The clinker in cement largely determines the environmental footprint of concrete. Therefore, concrete recycling should focus on retrieving high-quality cementitious fractions to replace clinker. This requires a shift from current traditional recycling techniques towards innovative recycling methods, enabling recovery of not only clean secondary aggregates, but also residual cementitious fines (RCF), potentially eliminating the carbon dioxide emissions associated with them. The production and upcycling of RCF offer new implementation routes that were previously deemed unfeasible. However, the properties of RCF may vary based on their origin, affecting their replacement and upcycling potential. Consequently, assessing the original concrete quality, with a focus on the binder type, before demolition is important. A handheld x-ray fluorescence technique appears promising for this purpose. To achieve effective separation of clean secondary aggregates from the original cementitious content, innovative crushing and separation techniques are needed. Additionally, electrostatic separation shows significant research potential for further optimizing RCF.@en

The environmental footprint of concrete is largely influenced by the binder. It is therefore of high interest to investigate the potential reuse of the binder retrieved by modern separation techniques. However, studies found that the recycled cement fraction (RCF) still contained a certain amount of siliceous concrete aggregates, which forms an obstacle in the upcycling of RCF. In this study, the potential of electrostatic separation as a method to separate cementitious binder (hydrated and unhydrated) and sand (silica) is evaluated. Different cementitious powders and silica (sand) were prepared, resulting in a total of 9 powders and 8 mixtures. The mixtures consisted of a combination of silica and one of the cementitious powders (50/50 wt%) with a particle size of the components <125 μm. The potential of the studied technique was evaluated through charging measurements and x-ray fluorescence (XRF). Silica was assumed to contain no CaO and the detected CaO was therefore assigned to the cementitious powders. Results showed that silica and silica-rich fly ash (FA) particles became negatively charged, blast furnace slag (BFS) particles remained largely charge neutral and all other cementitious particles obtained a positive charge. Through electrostatic separation an enrichment of the cementitious binder fraction for all mixtures was obtained at the negative electrode. FA-Silica achieved the highest enrichment (89.9%), CEM III/B-Silica the lowest (4.7%) and the hydrates were enriched ranging from 28.0 to 31.8%.@en

Given the rising popularity of foam concrete (FC) for both structural and insulating purposes, evaluating the feasibility of recycling after its lifespan is crucial in the context of the growing emphasis on sustainable building practices. One approach to recycling FC incorporating microencapsulated phase change material (MPCM) involves utilizing recycled foam concrete powder (RFCP) as an additive in cement composites. This article aims to investigate the impact of RFCP without and with MPCM when employed as a partial replacement for cement in mortars. Furthermore, the study verifies various processing methods such as crushing, grinding, and heat treatment for RFCP. The results reveal that introducing RFCP, regardless of the MPCM presence and processing method, significantly affects the properties of both cement and mortar. The presence of MPCM in RFCP negatively influences the flowability of fresh mortars, delays the setting time, and reduces the hydration heat within the first 48 h. However, the presence of MPCM does not significantly affect mortars' strength and water absorption but simultaneously it increases shrinkage and decreases thermal conductivity. Grinding RFCP mitigates the adverse effects of MPCM, while thermal processing removes MPCM from RFCP, albeit with an associated increase in water demand. A noteworthy finding is that mortars having 20 % RFCP, with or without MPCM, exhibit compressive strengths exceeding 16 MPa and 42.5 MPa after 2 and 28 days, respectively. These results meet the requirements outlined in EN-196-1 for cement of class 42.5, highlighting the potential to produce CEM II/A-F 42.5 using RFCP with MPCM.

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Given the ongoing global urbanization and the rise of heat, flooding, and drought in cities, the integration of climate adaptive measures based on “ecosystem functions and services” becomes imperative in design. This study details the implementation process of a microclimate design model in the design and retrofitting of the housing project Ecohof Noorderveer in Wormerveer, the Netherlands. The model, which quantifies local urban heat and mitigating measures through ecosystem functionalities, was incorporated into the program of requirements. The design process followed a research-by-design trajectory, involving iterative creative collaboration among all stakeholders, including future residents, the municipality, the water board, and the architect. The research employed the CFIR method to compare anticipated implementation outcomes with actual results. The findings suggest that introducing the microclimate design model into the program of requirements proved beneficial for the implementation process in the early design stage. The research-by-design approach was also deemed helpful, contingent on careful involvement of all participants in the knowledge-sharing process. This implementation method demonstrates significant potential for scaling up to standard urban development projects.@en

Research into bioreceptive materials is gaining increased interest. However, while advances are being made on the material side of bioreceptivity, the underlying ecology of urban mosses is still underexposed. This research aimed to determine how the local environment affects the species composition of urban epilithic moss communities and assess which moss species are most suitable for the colonisation of pristine (bioreceptive) concrete surfaces, leading to recommendations for moss species selection to designers and engineers of bioreceptive structures. We conducted a field survey of 137 moss communities on concrete in the Dutch cities of Amsterdam, Rotterdam and The Hague. A total of 26 different species were found, of which the acrocarp species Tortula muralis, Grimmia pulvinata, Ptychostomum capillare, and Orthotrichum diaphanum and the pleurocarp species Brachythecium rutabulum, Hypnum cupressiforme, and Rhynchostegium confertum acted as most common pioneers and also formed a part of the climax community. We found some positive associations between acrocarp species but negative associations between acrocarp and pleurocarp species. Local environmental factors only played a small role in the community composition at a species level; however, when comparing acrocarp and pleurocarp species, the former preferred more exposed sites, whereas the latter preferred more shaded habitats. As such, we recommend that bioreceptive concrete structures use acrocarp pioneers for exposed locations and pleurocarp pioneers for more shaded locations.

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The technical (service) lifespan of concrete is a crucial element in the construction sector, where the quality of the concrete mix and execution technology plays a decisive role in the performance throughout the entire functional life of structures. This presentation explores the importance of a well-designed concrete mix and how it contributes to the sustainability (overall environmental impact) and longevity of structures. We will examine the influence of reducing the environmental impact of concrete, resistance to environmental exposure conditions, and maintenance needs of concrete structures. By providing insights into the relationships between mix composition and lifespan performance, we emphasize the necessity of careful material selection and precise execution technology as the foundation for sustainable construction practices. The presentation will offer practical recommendations for improving the technical lifespan and reducing the environmental impact of concrete by focusing on the quality of the concrete mix and execution technology.@en

This study compares Enzyme-Induced Calcium Carbonate Precipitation (EICP) and Microbially Induced Calcium Carbonate Precipitation (MICP) for repairing external cracks in cement-based materials. Cracks in cement-base members can compromise structural integrity and increase maintenance costs. Thus, cement-base specimens with controlled cracks were treated using EICPs and MICP, with organic and non-organic additives to enhance calcium carbonate formation. Results show that both methods were effective in sealing cracks smaller than 0.35 mm. While incorporated additives improved the overall precipitation effectiveness, influence the crystallite size and altern the morphology of precipitated calcium carbonate. MICP generated more consistent crystal structures, while EICPs resulted in diverse crystal shapes influenced by enzyme sources and additives. Both methods offer promising, sustainable solutions for crack repair, with EICP providing greater flexibility and easier preparation. Presented research gives the comprehensive insights into the field of crack repair via bio-based methods reveals its potential in this area.

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This study investigates the structural behaviour and self-healing performance of hybrid reinforced concrete (RC) beams, enhanced with a 1.5-cm-thick self-healing cover composed of bacteria-embedded strain hardening cementitious composite (SHCC), for its potential in crack width control and crack healing. The research focuses on the performance under both flexural and shear loading, examining aspects such as load-bearing capacity, surface crack pattern, crack propagation between layers, and healing effectiveness. Results demonstrate the successful activation of the healing function, alongside improvements in structural performance. Under flexural loading, hybrid beams exhibited greater load-bearing capacity and significantly improved crack control ability. The maximum crack width of the hybrid beams exceeded 0.3 mm at 124.7 kN load, whereas in the control beam the largest crack exceeded 0.3 mm at only 59.8 kN load. Under shear loading, while the influence of the cover on structural capacity was minimal, it notably improved post-peak ductility and energy dissipation. Interface delamination was not observed in both cases. The results of the current study demonstrate the potential of delivering the self-healing mechanism precisely where it is most needed, which presents a scalable and economically viable strategy for integrating self-healing technology into standard construction practices.

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Implementing nature in cities has great potential to improve urban liveability by providing ecosystem services, which can help mitigate heat stress, improve air quality, attenuate noise, and reduce rainwater run-off. However, widespread adoption of urban nature and green building typologies is still limited due to their costs, environmental impact, and space constraints. Bioreceptive concrete can form the basis of a new green building typology, where the concrete mixture is adjusted to allow for biological growth, specifically mosses, to occur on its surface.

This literature review aims to give an overview of the current state of the art on bioreceptive concrete as a material in general and specifically the (potential) ecosystem services provided by the mosses growing on this bioreceptive concrete.

This review shows that bioreceptivity can be achieved in concrete in several ways, including minor adjustments to standard concrete recipes. While quantitative data on the ecosystem services provided by mosses in an urban context is still limited, potential gains appear significant. The main challenges lie in the durable long-term development of mosses on the bioreceptive concrete and the valuation through quantification of the ecosystem services they provide. However, moss-receptive concrete shows promise as a new green building typology if these challenges are bridged. @en

In the current study, experiments were carried out to investigate the structural performance of reinforced concrete (RC) beams with a self-healing cover zone. The cover zone consists of a 1.5-cm-thick layer of bacteria-embedded strain hardening cementitious composite (SHCC) for a combination of crack width control and crack healing. The aim is to bring together two emerging technologies (i.e., self-healing and strain-hardening) that show great potential for realizing highly efficient concrete structures. RC beam without the self-healing cover was also prepared as the control specimen for comparison purposes. The experimental program includes loading the beams to failure in four-point bending configuration and sawing the beams to segments for crack pattern analysis and crack healing. Results show that the beams with self-healing cover exhibited a 45-60% improvement in structural capacity. The crack patterns of the hybrid beams were also largely modified. While the reference beam formed only a few major cracks, the hybrid beams formed around 40 fine cracks in the constant bending moment region with an average crack width smaller than 0.2 mm even at maximum load. By having an improved cracking behavior and an enhanced self-healing capacity, it is expected that the beams with a self-healing cover will possess an extended service life at the expense of minimal additional cost.@en

This study presents an early-stage design exploration of NRG-Foam, an innovative insulation material composed of cementitious foam doped with microencapsulated phase change materials (MPCMs). The study comprises the static part that utilizes life cycle assessment and life cycle costing assessment for getting insight into the impacts of the NRG-Foam production process and the dynamic part that identifies the trade-offs between performance characteristics of NRG-Foam using multi-objective optimization. The production of MPCMs was found to be a major contributor to environmental impacts while the addition of small amounts of reduced graphene oxide amplifies the impacts even further. The hot spot analysis pinpointed high electricity consumption as the main driver of environmental impacts. A multi-objective optimization analysis revealed trade-offs between performance characteristics, emphasizing the necessity of compromises during material development. The selection of the MPCM type was shown to be determinative of the final properties of NRG-Foam.

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The current study investigates short-term and long-term crack-healing behaviour of mortars embedded with bacteria-based poly-lactic acid (PLA) capsules under both ideal and realistic environmental conditions. Two sets of specimens were prepared and subjected to different healing regimes, with the first set kept in a mist room for varying short durations (i.e., 1 week, 2 weeks, 3 weeks and 8 weeks) and the second set placed in an unsheltered outdoor environment for a long-term healing process (i.e., 1 year). Alteration of microstructure because of self-healing was characterized by backscattered electron (BSE) imaging and energy dispersive X-ray spectroscopy (EDS) via crack cross-sections. Results show that visible crack healing enabled by bacteria began after 2 weeks in a humid environment. The healing products initially precipitated at crack mouths and gradually moved deeper into cracks, with the precipitated calcium carbonate crystals growing larger over time. After 8 weeks, healing products can be found even a few millimetres deep inside cracks. Observations of crack healing in a realistic environment revealed significant differences compared to healing under controlled conditions. While no healing products can be found at crack mouths, a substantial healing process was observed throughout the entire crack depth. It is likely that the environmental actions such as rainfall and/or freeze and thaw cycles may have worn away the healing products at crack mouths and thus led to a deeper ingress of oxygen into cracks, which promoted the activation of healing agents and associated calcium carbonate precipitation deep inside a crack.

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Earthen construction is re-gaining popularity as an ecological and economical alternative to contemporary building materials. While building with earth offers several benefits, its performance due to water ingress is a concern for its widespread application. This limitation is often solved by adding chemical stabilisers such as Portland cement and hydraulic lime. Chemical stabilisers are a subject of widespread debate as they increase the cost and embodied energy of the structure, and reduce the desirable characteristics of raw or unstabilised earth. This along with perceived environmental performance, renewability, and proven effectiveness in traditional earthen construction has led to a growing interest in biological or organic stabilisers. Although the strengthening mechanism of biological stabilisers is widely covered in scientific studies, discussion regarding the water-resistance is limited. This review aggregates the research from the field of earthen construction and geotechnical engineering and extends it to explain the possible mechanism responsible for the water-resistance behaviour of biologically stabilised earthen materials. This study includes a wide range of traditional and industrial biological stabilisers derived from animals (cow-dung, casein, chitosan), plants (starch, guar gum, cactus mucilage, lignin, tannin) seaweeds (alginate, agar, carrageen) and microbes (xanthan gum, gellan gum). A conceptual model of water-ingress in unstabilised earthen blocks is proposed and the response of biological stabiliser to water ingress and related physico-chemical and physical factors is discussed using the model at microscale (stabiliser interaction with clay, sand) and macroscale (hydraulic conductivity of block). Properties of stabilisers such as hydrophobicity, stability under wet conditions or interaction with cations have a dominant effect on the overall response to water ingress. Key gaps have been identified in the existing knowledge that are necessary to investigate in order to understand the water-resistance behaviour comprehensively. The study concludes with a brief assessment of biological stabilisers based on their performance and feasibility to use in contemporary earthen construction.@en

The water-resistance of cow-dung has made it a widely used stabiliser in traditional earthen structures in several Asian and African countries. Multiple studies have shown an improvement in water-resistance with the addition of cow-dung, but none provides insight into this behaviour. The present study investigates the water-resistance behaviour of cow-dung stabilised earthen blocks through an extensive experimental programme to identify and characterise the components of cow-dung responsible for its water-resistance. Fresh cow-dung was collected and separated into fibres (>63 μm), medium-sized microbial aggregates (1-63 μm) and small-sized microbial aggregates (0.5-7 μm). Each component was mixed with soil and samples were prepared at different water contents (optimum water content corresponding to the highest dry density and water content higher than optimum) and compacted with 2.5 MPa force to prepare compressed blocks. The water-resistance of these blocks was evaluated through the immersion and modified drip/rain test. It was found that the small-sized microbial aggregates are almost entirely responsible for water-resistance behaviour of cow-dung stabilised earthen blocks. Small-sized microbial aggregates were further characterised by gas chromatography, mercury intrusion porosimetry, N2- BET surface area, zeta potential measurement and electron microscopy. The results indicate that the small-sized microbial aggregates are composed of clay-sized negatively charged particles that are rich in fatty acids. The hydrophobicity of these particles is hypothesised to be responsible for water-resistance behaviour. These insights are further used to produce stabilised blocks that performed at least 30 times better than the unstabilised blocks in both water-resistance tests. The study concludes with practical recommendations for the use of wet cow-dung over dry cow-dung and a reduction of fibre content to increase the water-resistance of earthen blocks. @en

In this study, the applicability of two bacteria-based healing agents (e.g., poly-lactic acid and polyhydroxyalkanoate) in blast furnace slag cement (BFSC) mortar has been assessed. An experimental campaign on the functional properties, self-healing capacity, freezing–thawing and carbonation resistance has been conducted in comparison with plain mortar (Ctrl). Due to the relatively low alkalinity of the mixture, the addition of poly-lactic acid healing agents (PLA) caused coarsening of the micro-structure, decrease of strength and did not improve the self-healing capacity of the material. Among other consequences, the mass loss due to the freezing–thawing of PLA specimens was about 5% higher than that of the Ctrl specimens. On the contrary, no detrimental effect of the mortar functional properties was measured when polyhydroxyalkanoate healing agents (AKD) were added. The self-healing capacity of AKD specimens was higher than that of the Ctrl specimens, reaching a maximum healed crack width of 559 µm after 168 days of self-healing, while it was 439 µm for the Ctrl specimens and 385 µm for PLA specimens. The air void content of the AKD mixture was 0.9% higher than that of the Ctrl, increasing its resistance against freezing–thawing cycles. This study aims to confirm the potential applicability of AKD particles as self-healing agents in low-alkaline cementitious mixtures. @en

Asphalt pavement consists of aggregates resulting in a waste material at end of its life. The aggregates can be reused as basic material for asphalt or cementitious binding agents. In both scenarios, the recycled aggregates should provide a good bond with the binder to achieve strength. This study focuses on reusing recycled asphalt aggregates (RAA) in mortar. The major weakness of RAA is the thin oily film originating from the asphalt residue, weakening the bond with cement. The pyrolysis method is accessed in an attempt to overcome this weakness. Three scenarios were investigated; the use of virgin aggregates (VA), RAA, and pyrolysis recycled asphalt aggregate (PRAA) as constituent in mortar. All variables were set a constant except for the aggregate type, the VA mortar function as controlling element. This research is methodologically based on experimental data conducted in the laboratory, while aggregate samples were taken from the field. To analyze the influence of pyrolysis to the aggregate-to-cement bond behaviour, qualitative and quantitative data were collected. The quantitative data were the mechanical properties, the mortar tensile, and compression strength. The qualitative data were obtained from scanning electron microscope readings to visually observe the aggregate surface roughness and voids, including the aggregates cross-section and pre-existing micro-cracks in the aggregate-to-cement interface. Supporting data were the aggregates‘ abrasion rate and absorption. The RAA resulted in a significant mortar strength decrease. This conclusion was supported by the findings of pre-existing cracks in the interfacial transition zone. The pyrolysis method improved the compression strength but negligibly affected the tensile behavior. The compression and tensile strength increased as a function of time for both RAA and PRAA, and a strength convergence was reached at 28 days. The PRAA is considered an option for reuse in mortar, supporting nature conservation.

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The urban heat island, is a serious threat for the urban well-being, and can be determined by the local energy balance. The surface energy balance, with respect to incoming radiative energy and subsequent partitioning into reflected energy (albedo), absorbed energy and further partitioning of latter into convectional heat (QH), radiative heat (QR) and latent heat (QE) by using commonly applied urban materials and vegetation types, was therefore experimentally quantified in this study. In agreement with previous studies it was found that materials convert most of absorbed energy into convectional heat (>92%) while vegetation channels a substantial part of absorbed radiative energy into latent heat (27–50%). It is for the first time experimentally demonstrated that significant differences in thermal behaviour between different types of urban vegetation surfaces occur. Of the investigated vegetation types ivy and moss showed respectively the highest (0.10) and lowest (0.07) albedo, but sedum and moss channelled respectively lowest (27%) and highest (50%) percentage of the absorbed radiative energy into latent heat production. Of the four investigated plant types, moss appeared most effective in preventing UHI, converting only 50% of incoming radiative energy into convectional heat, while sedum was least effective converting 73% of incoming radiative energy into convectional heat. These quantitative measurements show that strategic use of specific types of urban vegetation surfaces, instead of commonly applied building materials, can be an effective measure for mitigation of UHI leading to improved climate resilient cities.@en

The possible beneficial impact of self-healing on chloride transport through cracks has been assessed for two bacteria-based self-healing mortar mixtures in comparison with Ordinary Portland cement mortar. Intact self-healing specimens featured lower chloride transport coefficients thanks to a denser microstructure and to the formation of a layer of calcium carbonate on their surface. However, self-healing of cracks of cracked mortar specimens did not significantly reduce chloride penetration during 28 days of chloride exposure compared to cracked and non-healed specimens. On the other hand, this study demonstrated that self-healing of 150–200 µm wide cracks reduced chloride ingress during shorter term (14 days) chloride exposure in comparison to cracked but non-healed specimens. The results of this study suggest that self-healing of cracks through calcium carbonate formation results in water blockage (sealing) of cracks but that the limited amount of limestone formed creates an imperfect barrier against diffusion of chloride ions through the apparent porous limestone. The short-term positive effect of self-healing with respect to reduced chloride ingress could be beneficial in applications where chloride exposure is limited or non-permanent such as concrete structures irregularly exposed to deicing salts or located in the splash zone in marine environments.

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Since self-healing of cementitious materials can theoretically improve the service-life of concrete structures, it has gathered significant attention from both researchers and industry during the last two decades. Many researchers have proposed different methods to assess and quantify the self-healing capacity (i.e. the ability of cementitious materials to heal cracks) that is generated in concrete autogenously as well as autonomously. Even though many methodologies can be found in the literature, a way to accurately quantify the healing products produced by any self-healing mechanism has not been yet achieved. In this study, a methodology is proposed to observe and to quantify in-time formation of healing products based on active thin sections. Thin sections of Portland cement paste have been prepared with no epoxy impregnation to facilitate reactions between the cement matrix and the surrounding environment. Artificial cracks (260 μm wide) were induced at 28 days of age and the crystal growth was continuously monitored up to 28 days of self-healing. Through image analysis of the micrographs, it was calculated that the autogenous self-healing capacity of paste (triggered by portlandite carbonation in uncontrolled indoor conditions) was around 55% after 28 days of self-healing. Healing products were further characterised through Environmental Scanning Electron Microscope analysis. Based on the results obtained in this study, the proposed methodology seems to be promising to compare the self-healing mechanisms triggered by different healing agents.

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In this paper, the elevated temperature on a concrete-galvalume composite beam's flexural strength based on the numerical and experimental methods is investigated. The strategy is to perform modeling and simulation of the flexural test based on finite element method (FEM) at room temperature and validate its results to experimental data at the same temperature. When the numerical model was proven valid, the model was utilized to simulate the effect of elevated temperatures on the composite element. The study concludes that the flexural strength of the beam decreases at higher temperature. Additionally, it was shown that cracking moments is susceptible to temperature fluctuation and the failure modes are sensitive concerning the elevated temperature.

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