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T.J. Heimovaara

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Backward erosion piping (BEP), a form of internal soil erosion, often threatens the safety of dykes built on alluvial deposits. To reduce the risk of dyke failure due to piping, reliable and cost-effective mitigation measures are essential. For the first time, this paper proposes the use of nature-inspired low-permeability barriers to mitigate BEP. The potential of this novel solution is demonstrated in a series of laboratory physical tests. Low-permeability barriers are created by mixing sand either with aluminium-organic matter flocs, or clay. The results show that both kinds of barriers can significantly inhibit pipe progression and intercept the erosion channels. The hydraulic gradients required for pipes to reach the barrier are significantly higher than the critical gradient measured in the absence of barriers, ranging from 2·2 to 7·4 times greater than those in sand alone. The associated mitigating mechanisms include the dissipation of flow energy, resistance to internal erosion due to pore space clogging and prevention of sand fluidisation. The mitigating effect is affected by the reduction of hydraulic conductivity, the depths and the heterogeneity of barriers. The findings of this experimental work provide guidance for the design of low-permeability barriers in practice and contribute to the development of numerical models for BEP. ...
Review (2025) - Nasim Janatian, Urmas Raudsepp, Parya Broomandi, Kate Fickas, Kalle Olli, Timo Heimovaara, Aarne Mannik, Rivo Uiboupin, Nima Pahlevan
Optical satellite observations have been recently introduced as the backbone of several harmful algal bloom monitoring frameworks for regional or continental-scale decision-making. Documented in prior peer-reviewed publications, these satellite-based decision support systems are not directly comparable, making a synthesis effort inevitable for future improvements. This review highlights select, widely used harmul cyanobacteria bloom (cyanoHABs) monitoring services, including the Cyanobacteria Assessment Network (CyAN), Cyanobacterial Bloom Indicator (CyaBI), CyanoTRACKER, EOLakeWatch, and CyanoKhoj, by focusing on their effectiveness in freshwater and inland waters. We selected these systems for their widespread use, documented effectiveness, and diverse approaches to cyanoHABs monitoring. These services provide early warnings and actionable insights, enabling effective responses to protect water quality, ecosystem health, and public safety. It considers the broader remote-sensing-based monitoring landscape, noting the capabilities and impacts of these services. Our assessments underscore the transformative impact of services like CyAN, which provide robust early warnings using the Cyanobacteria Index (CI). CyanoTRACKER and EOLakeWatch improve community engagement and data collection, increasing monitoring effectiveness. CyanoKhoj leverages high-resolution monitoring through GEE, offering valuable insights. The quality of cyanoHABs products depends on satellite imagery and processing level, noting that most processors leverage Top of Atmosphere or Rayleigh-corrected reflectance products to arrive at cyanoHABs products. Challenges in cyanoHABs monitoring also include variability in ecosystems and accurate biomass estimations. Despite challenges, services like CyAN, CyanoTRACKER, EOLakeWatch, and CyanoKhoj have made significant strides in communicating and managing cyanoHABs risks. This review identifies key future research directions: (1) improving algorithmic approaches and accuracy, (2) defining a universal threshold for bloom formation, (3) utilizing emerging technologies and democratizing data and information, and (4) addressing satellite technique trade-offs in cyanoHABs analysis. By focusing on these areas and leveraging machine learning, future advancements promise more accurate and comprehensive monitoring to protect aquatic ecosystems and public health. ...
Journal article (2025) - L. Wang, T. J. Heimovaara
The emission potential, which represents the total leachable mass in landfill waste body, is hard to measure directly. Therefore we propose to quantify it by assimilating available measurements. The leachate production rate is influenced by the total water storage in the waste body, while both total chloride mass and total water storage in the waste body influence the chloride concentration in the leachate. Thus assimilating leachate volume and chloride concentration simultaneously will help quantify the uncertainties in emission potential. This study investigated the feasibility of using a particle filter in a concentration-volume coupled travel time distribution model to estimate the emission potential. Leachate production rates and chloride concentrations were assimilated simultaneously by a weakly coupled data assimilation method. The time lag issue in the travel time distribution model was solved by adding a daily model error to cover layer states. The proposed method was tested in synthetic experiments first to investigate the performance. The results show that the uncertainties in chloride mass and waste body total water storage were quantified and reduced. The predictions of chloride concentrations were also improved. ...
Journal article (2025) - L. Wang, T. J. Heimovaara
Accurate estimation of water storage in municipal solid waste landfills is critical for assessing leachate-generation risk yet remains challenging due to pronounced heterogeneity. Here we apply Bayesian Evidential Learning (BEL) to directly relate Electrical Resistivity Tomography (ERT) data to total water storage (TWS), bypassing explicit inversion. A semi-parametric forward model generates 100,000 synthetic TWS–ERT pairs spanning stochastic saturation fields and petrophysical uncertainty. A Bayesian neural network captures data-dependent predictive uncertainty, while stratified resampling and adaptive weighting mitigate class imbalance across the TWS range. The framework yields well-calibrated posterior estimates and consistent agreement with independent water-balance benchmarks from four field transects. The BEL–ERT workflow provides a rapid, open-source alternative for landfill monitoring and highlights the potential of uncertainty-aware learning from synthetic ensembles to quantify water storage in heterogeneous near-surface systems. ...
Journal article (2025) - T. J. Heimovaara, L. Wang
Sanitary engineered landfills require extensive aftercare to safeguard human health and the environment. This involves monitoring emissions like leachate and gas, maintaining cover layers, and managing leachate and gas collection systems. Researchers have explored methods to conclude or extend aftercare. Quantifying emission potential, a key concept integrating various processes influencing emissions, is essential for managing and predicting landfill impacts. In this study we developed a stochastic travel time model based on water life expectancies. The model is used to predict leachate production rates and leachate chloride concentrations from landfill waste bodies. Unknown parameters are quantified by matching model output to measured time series using Bayesian inference. Once parameter distributions have been obtained, we are able to describe the measured long-term leachate dynamics. By analyzing the parameters and evolution of model states, we obtain a deeper understanding of the water and mass balance of the waste bodies. We demonstrate that the model can be used to quantify the chloride emission potential and the estimated values of total chloride mass match data quantified by sampling from the waste body. The results confirm that emissions with leachate are dominated by preferential flow infiltrating from the cover layer. Similar results have been obtained by applying the model to datasets from four different waste bodies, demonstrating that the approach is generally applicable for conservative solutes. Understanding of the water balance of the landfill together with conservative solute leaching is a necessary first step for further evaluating emission of reactive species. ...
Journal article (2025) - Edith J.S. Eder, Alemeh Karami, Timo J. Heimovaara, Mariëtte Wolthers, Boris Jansen
Flocculation, as the formation of insoluble organo-metallic complexes, has been studied considerably in the field of soil science, as it emerges e.g. from podzolization where a soil layer with reduced permeability is created; but also in the field of water treatment, as a means to remove natural organic matter (NOM). It is based on the process where positively charged metal species – Aluminium (Al), Iron (Fe) and Zirconium (Zr) in this study – react with the negatively charged surface of dissolved organic matter (DOM) and precipitate to form flocs. Since pH affects the surface charge of the organic matter (OM) particles and the form in which the coagulants are present in solution, controlling physico-chemical parameters, such as the pH, would significantly improve the flocculation process and help to enhance the efficiency of water purification strategies and soil permeability reduction from a geo-engineering perspective. It was shown that (1) there are ideal intervals in terms of metal to Carbon ratio (Me/C), in which the coagulants should be added to cover the surface of the DOM particles and these vary with metal type and pH; (2) at pH = 1, the OM forms flocs only with protons when mixed with Al, while with Fe some, and with Zr all, metal is associated with the solid phase; (3) Zr generally forms larger flocs than Al and Fe, even at acidic pH = 1, but also at higher concentrations; and (4) as the Me/C increases, the floc size does as well. ...
Journal article (2024) - J.M. van den Brink, H. Scharff, B. Steinert, S. Melchior, M. Hrachowitz, J. Heimovaara, J. Gebert
This study quantifies the field hydraulic performance of a dual-functionality landfill cover, combining microbial methane oxidation with water diversion using a capillary barrier. The investigated 500 m2 test field, constructed on a landfill in the Netherlands, consisted of a cover soil optimised for methane oxidation, underlain by a sandy capillary layer and a gravelly capillary block. Outflows from these layers were measured between 2009 and 2023. Average precipitation was 848 mm/a, evapotranspiration, diverted infiltration and breakthrough amounted to 504 (59.4 %), 282 (33.3 %) and 62 (7.3 %) mm/a, respectively. On average, the capillary barrier diverted 82 % of the inflow into the capillary layer. Breakthrough occurred mainly from October to March when evapotranspiration was low and the maximum water storage capacity of the cover soil was reached. During this period, inflow into the capillary barrier exceeded its diversion capacity, caused by the relatively high hydraulic conductivity of the cover soil due to its optimisation for gas transport. The diversion capacity declined drastically in the year after construction and increased again afterwards. This was attributed to suffusion of sand from the capillary layer into the capillary block and subsequent washout to greater depths or the influence of iron precipitates at the bottom of the capillary layer. The effect of a more finely grained methane oxidation layer on the hydraulic and methane oxidation performance should be investigated further. These measures could further improve the combined performance of the dual functionality landfill cover system under the given conditions of a temperate climate. ...
Canal dikes in low-lying polders, as well as in other regions worldwide, are critical infrastructure for flood protection and water management. The subsurface water conditions can cause dike failures during excessive rainfall and prolonged periods of drought. There is a lack of multi-year monitoring of subsurface water conditions in canal dikes and an insufficient understanding of their geohydrological behavior. This study provides and analyses a novel multiyear data set of soil moisture and hydraulic heads (from February 2020 until March 2023) from a monitoring network covering various canal dikes with different characteristics in the western Netherlands. The data, including two extremely dry summers, highlight the impact of meteorological variations on the subsurface water conditions. Non-hydrostatic hydraulic head levels were observed during droughts that can be detrimental to dike stability and that are often not accounted for in safety assessments for drought situations. The effectiveness of various meteorological drought indicators applied to subsurface water conditions was evaluated: the precipitation deficit is the most reliable measure and outperforms the standardized drought indicators (SPEI and SPI). The drought recovery of dikes was analyzed to understand seasonal transitions and the sequence of different failure mechanisms, during dry and wet situations. This analysis also reveals differences between meteorological, soil moisture, and groundwater droughts, highlighting soil's storage capacity after drought and the limitations of meteorological drought indicators as proxies for soil moisture and groundwater. The insights from this study enhance assessments, inspection procedures and the identification of weak spots of dikes and other earthworks of infrastructure. ...
Journal article (2024) - Aoxi Zhang, Vanessa Magnanimo, Hongyang Cheng, Timo J. Heimovaara, Anne-Catherine Dieudonné
Bio-mediated methods, such as microbially induced carbonate precipitation, are promising techniques for soil stabilisation. However, uncertainty about the spatial distribution of the minerals formed and the mechanical improvements impedes bio-mediated methods from being translated widely into practice. To bolster confidence in bio-treatment, non-destructive characterisation is desired. Seismic methods offer the possibility to monitor the effectiveness and mechanical efficiency of bio-treatment both in the laboratory and in the field. To aid the interpretation of shear wave velocity measurements, this study uses the discrete element method to examine the small-strain stiffness of bio-cemented sands. Bio-cemented specimens with different characteristics, including properties of the host sand (void ratio, uniformity of particle size distribution) and properties of the precipitated minerals (distribution pattern, content, Young’s modulus), are modelled and subjected to static probing. The mechanisms affecting the small-strain properties of cemented soils are investigated from microscopic observations. The results identify two mechanisms controlling the mechanical reinforcement associated with bio-cementation, namely the number of effective bonds and the ability of a single bond to improve stiffness. The results show that the dominant mechanism varies with the properties of the host sand. These results support the use of seismic measurements to assess the mechanical efficiency and effectiveness of bio-mediated treatment. ...
Nitrogen undergoes multiple biogeochemical transformations during waste degradation, which depend on speciation, prevailing geochemical boundary conditions, and waste surface properties. This study developed a waste biodegradation model with high flexibility in accommodating reaction pathways to assess different process dynamics. The model was applied to landfill simulator reactors operating anaerobically. Model results show that dilution with adsorption matches the experimental dissolved NH4+ concentration (C/N=25) at the early experimental stages. Also, NH4+ binding decreases
due to competition with Ca2+, and the model better captures the dissolved NH4+ behavior when CaSO4 is present in solution. Mass removal due to sampling and posterior dilution are the main mechanisms to reduce NH4+ concentration in the leachate. The model highlights the role of nitrogen sorption as the main
mechanism for nitrogen accumulation in the solid phase of municipal solid waste. ...
Conference paper (2023) - Timo Heimovaara, Julia Gebert, Twan Kanen, Nathali Meza
In-situ stabilization of waste bodies can be achieved by the infiltration of water or recirculation of leachate into the landfill, which is thought to enhance the microbial degradation of waste organics by (re-)moisturizing dry zones and flushing out metabolic products of organic matter decay. The success of in-situ stabilization should reflect in initially accelerated and thereafter reduced rates of anaerobic waste organic matter decay rates. This paper compares the methane generation that was modelled using the Afvalzorg multiphase model without the added effect of leachate recirculation with actually extracted methane in the landfill and gas generation on sampled wastes following five years of leachate recirculation on a Dutch landfill. Laboratory incubations revealed a methane potential between 0.03 kg CH4/t dw and 15.8 kg CH4/t dw for 365 days. Clear trends with respect to depth, moisture content, total organic carbon or share in hard plastics did not emerge as overall waste heterogeneity was high and likely obfuscated the correlation analysis. The results showed a recovery efficiency of 30.4% for 2021, with 0.07 kg CH4/t dw for the recovered methane and 0.23 kg CH4/t dw for the predicted methane in compartment 3. The average methane potential measured in the laboratory was almost twice as high as the remaining methane potential predicted for the period of 2021-2093. The discrepancy could be due to (i) enhanced waste degradability as a result of five years of recirculation, (ii) enhancing effects of material perturbation during sampling and/or (iii) impeded on-site methane generation and gas and water transport limitations due to presence of plastics. Overall, the laboratory incubations demonstrate a significant potential for waste biodegradation still residing in the waste. ...

Changes in pore water metal bioavailability

Journal article (2022) - Arjan J. Wijdeveld, Cor A. Schipper, T.J. Heimovaara
Abstract: The use of sediments as soils is an area of interest for Beneficial Use of dredged sediments. In this study the impact of the transition from sediments to soils is researched by looking at the seasonal and long year (10 year) change in pore water metal chemistry of sediments which are considered clean (class A) according to the Dutch soil directive. This study is based on a combination of geohydrological, geochemical and ecotoxicological risk models and validated against measured pore water concentrations for metals over an dry/wet period. The pore water metal concentrations are compared against standards and expressed as at Risk Characterization Ratio’s (RCR) values. The RCR values are high (> 1) during the first 3 years after the application of sediments as soil, especially at the end of the summer. The multi substances Potentially Affected Fraction (ms-PAF) shows a similar trend as the RCR values, although it takes 5 years before the combined calculated potential ecotoxicity is below the legal 40% threshold level. Translated to land use, it is advised to restrict land use for farming on soils where these clean (class A) sediments are applied for a five-year transition period. Article Highlights: Beneficial Use of sediments should take into account the different conditions when used as soils.Use of sediments as soils lead to a predicable seasonal and multiple year trend in metal concentrations in pore water.The predicted results in metal pore water concentrations are translated into an advice for temporal land use. ...
Journal article (2022) - Anniek J. Kortleve, José M. Mogollón, Timo J. Heimovaara, Julia Gebert
Urbanization influences soil carbon (C) stocks and flows, which, in turn, affect soil-derived ecosystem services. This paper explores soil C storage in urban greenspaces in the Dutch city of The Hague along a transect from the suburban seaside towards the city centre, reflecting a toposequence from dune to peaty inland soils. C storage and C mineralisation potential were evaluated in relation to soil type and greenspace categories. Several soil-quality characteristics were measured, including dissolved organic C, pH, electrical conductivity, nitrogen, phosphorus, sulphur, calcium carbonate, and the water-holding capacity of the soil to evaluate what drives soil C storage in the urban context. The total SOC storage of the upper 30 cm of the greenspaces in The Hague (20.8 km2 with 37% greenspace) was estimated at 78.4 kt, which was significantly higher than assumed given their soil types. Degradability of soil organic matter in laboratory batch tests varied between 0.2 and 3 mg C gSOC−1 day−1. Degradability was highest in the seaside dune soils; however, extrapolated to the topsoil using the bulk density, topsoil C mineralization was higher in the urban forest. Soils beneath shrubs appeared to be hotspots for C storage, accounting for only 13% of the aerial cover but reflecting 24% of the total C storage. Land ownership, land use, greenspaces size, litter management and soil type did not result in significantly different C stocks, suggesting that processes driving urban soil C storage are controlled by different factors, namely land cover and the urbanization extent. ...
Journal article (2022) - Jianchao Zhou, S. Laumann, T. J. Heimovaara
This study presents a novel geotechnical engineering approach that utilizes naturally occurring processes to reduce soil permeability in-situ. This approach is inspired by a soil stratification process (Podzolization), where a low permeability layer is formed by metal-organic matter precipitates. In a field experiment, a direct aluminum-organic matter (Al-OM) floc injection was applied to create a continuous vertical flow barrier in a dike. Direct injection uses the shear-dependent size of Al-OM flocs. High-shear conditions (i.e., during injection) lead to the breakage of Al-OM flocs and thus allow their transportation in soils. When the injection stops and low-shear conditions prevail, the Al-OM flocs re-grow in size and block the pores, which ultimately reduces soil permeability. Two different Al-OM floc concentrations were applied in the field. Results show that a continuous flow barrier is only formed at lower concentrations; at higher concentrations a scattered permeability reduction was achieved. This demonstrates the viability of this approach in reducing soil permeability in-situ and shows that the spatial distribution of the flocs depends on input concentration. ...
Journal article (2022) - F. Zander, A. Groengroeft, A. Eschenbach, T. J. Heimovaara, J. Gebert
Anaerobic sediment organic matter decay generates methane, delays sediment consolidation, reduces sediment density, viscosity and shear strength, all impacting the sediment rheological parameters and the navigable depth. This study quantifies the share of anaerobically and aerobically degradable sediment organic matter (SOM) in a depth profile and along a transect through the tidal river Elbe in the section of the Port of Hamburg. From exponential organic matter decay functions, organic matter decay rates (mg C gTOC−1 d−1) were derived and clustered with a k-Means Cluster Analysis. The reactivity of different (kinetic) organic matter pools along the river transect were characterized based on their biodegradation rates. A fast, medium, slowly and non-degradable pool (pools 1–4) were identified based on the measured organic matter lability. SOM lability decreased from upstream to downstream, evidenced by the decreasing amount of the easily degradable pool 1 material from upstream to downstream. The size of the slowly degradable pool 3, assumed to be associated with SOM bound to the mineral particles, did not show any spatial gradient and is therefore suggested to represent a baseline share of hardly accessible SOM in the investigation area (about 12%−16% of TOC). Total degradability thus appears to be governed by the amount of SOM present in addition to this basis (pool 3), which in turn follows a source gradient and an age gradient from upstream to downstream. The recalcitrant pool 4 was the largest at any part of the harbour, for any depth, and for both, anaerobic and aerobic conditions (about 75%−85% of TOC). This indicates that the sediment in the investigation area, including the uppermost fluidic and freshly settled layers, mostly comprises stabilised organic matter and contributes largely to storage of organic carbon. Differently sized anaerobic SOM pools with depth were observed as well as seasonal changes of the easily degradable SOM pool 1. The degradability was larger in upper sediment layers, it was also larger under aerobic conditions (by about 10% of TOC) but the differences between aerobic and anaerobic decay decreased from upstream to downstream. ...
Journal article (2022) - Nathali Meza, Hans Lammen, Carmen Cruz, Timo Heimovaara, Julia Gebert
In-situ aeration of landfills accelerates biodegradation of waste organic matter and hence advances waste stabilization. The spatial outreach of aeration greatly affects stabilization efficiency. This study analyzed the spatial variability of gas composition and flow in 230 wells spread over four compartments of a Dutch landfill which is under in situ aeration since 2017, as well as the carbon extraction efficiency, tem-perature, and settlement. Flow rates and gas composition in the extraction wells varied strongly. The highest variability was observed in the compartment with the highest water tables with submerged filter screens for most wells, with low flow rates, and elevated ratios of CH4 to CO2, indicating predominance of anaerobic processes (compartment 11Z). The compartment with the most uniform distribution of gas flow rates, composition and lower ratios of CH4 to CO2, suggesting a significant share of aerobic carbon mineralization, also showed higher temperatures, a carbon extraction efficiency, and larger cumulative settlement, all indicative of enhanced microbial activity (compartment 11N). In this compartment, the amount of extracted carbon exceeded the carbon generation predicted from landfill gas modeling by the factor of 2 over the hitherto four years aeration. The effect of water tables on gas flow and the correlation between the flow, and the ratio of CH4 to CO2 appeared weak, indicating that also other factors than water tables influence gas concentration and flow. Future work includes stable isotope probing to analyze the significance of microbial respiration and microbial CH4 oxidation for the composition of the final extracted gas mixture. ...

Relevance for the reliability assessment of dikes

Journal article (2021) - J. Chavez Olalla, T. G. Winkels, D. J.M. Ngan-Tillard, T. J. Heimovaara
The geometric variability of soil layers is a large source of uncertainty in the reliability assessment of dikes. Because direct samples of the subsurface soils are often insufficient to capture the complexity of the subsurface, geophysical methods provide a powerful source of complementary information. A combined approach to estimate the geometry of soil layers is presented. The approach combines local point data, i.e. data obtained from a CPT or a borehole log, and geophysical tomography in a universal cokriging framework. The approach uses the contact points between soil layers obtained from local point data and the orientations of the layers derived from geophysical tomography. To reduce subjectivity in the interpretation of tomographic images, an automated edge detection technique was used. The combined approach was applied to characterise two test sites where the presence of paleochannels locally change the geometry of soil layers. The results show that a combined approach enables the reduction of sampling efforts with an improved estimation of geometric variability. ...
Journal article (2020) - André G. van Turnhout, Hans Oonk, Heijo Scharff, Timo J. Heimovaara
In order to reduce the environmental and financial burden for future generations, approaches are needed to shorten aftercare of landfills. Aeration of the waste-body is a promising approach, however, the poor understanding of transport of gas and water through a waste-body makes it difficult to design an effective aeration strategy. The aim of this study is to develop a tool to determine the optimal aeration strategy for landfills. This study presents a comparison of aeration strategies based on the air distribution they generate with a 3-D multiphase model. The implemented theory is based on parameter values obtained from (laboratory) experiments performed under conditions which are similar to those in a full scale landfill. Calibration with field scale gas extraction data from the Dutch pilot site Wieringermeer shows that the model gives a good description of the average gas flow under extraction. Scenario analyses for the case study landfill indicate that injection strategies reach a larger volume fraction of waste with a higher air flow compared with extraction strategies, especially at the bottom of the landfill. Extraction, however, supplies oxygen more homogeneously through-out the waste. An import design criterion is also the distance between the wells. Too large distances lead to ineffective treatment because too large volumes of waste/leachate remain untreated. In addition to the comparison of aeration strategies, an optimal aeration strategy for the pilot site is presented. A combination of (alternating) injection and extraction wells which are maximum 20m apart seems to be the optimal strategy. ...
Journal article (2020) - Florian Zander, Timo Heimovaara, Julia Gebert
Purpose: The microbial turnover of sediment organic matter (OM) in ports and waterways impacts water quality, sonic depth finding and presumably also rheological properties as well as greenhouse gas emissions, especially if organic carbon is released as methane. As a consequence, sediment management practices as a whole are affected. This study aimed to discern spatial OM degradability patterns in the Port of Hamburg and investigated correlations with standard analytical properties as a basis for future predictive modelling. Materials and methods: Sediments in the Port of Hamburg were repeatedly sampled at nine locations along an east-west transect using a 1-m corer. In a stratified sampling approach, layers of suspended particulate matter (SPM), fluid mud (FM), pre-consolidated sediment (PS) and consolidated sediment (CS) were identified and individually analysed for long-term aerobic and anaerobic degradation of organic matter, DNA concentration, stable carbon isotope signature, density fractions and standard solids and pore water properties. Results and discussion: The investigation area was characterised by a distinct gradient with a 10-fold higher OM degradability in upstream areas and lower degradability in downstream areas. Concomitantly, upstream locations showed higher DNA concentrations and more negative δ13C values. The share of bulk sediment in the heavy density fraction as well as the proportion and absolute amount of organic carbon were significantly larger at downstream locations. A depth and hence age-related gradient was found at individual locations, showing higher degradability of the upper, younger material, concomitant with higher DNA concentration, and lower OM turnover in the deeper, older and more consolidated material. Deeper layers were also characterised by higher concentrations of pore water ammonium, indicative of anaerobic nitrogen mineralisation. Conclusions: Organic matter lability is inversely linked to its stabilisation in organo-mineral complexes. The observed degradability gradient is likely due to the different OM quality in relation to its origin. Downstream OM enters the system with the tidal flood current from the direction of the North Sea whereas upstream locations receive OM originating from the catchment, containing more autochthonous, plankton-derived and more easily degradable components. At individual sampling points, depth-related degradability gradients reflect an age gradient, with easily degradable material in top layers and increasing stabilisation of OM in organo-mineral compounds with depth. ...
Journal article (2019) - Héloïse A.A. Thouement, Tomasz Kuder, Timo J. Heimovaara, Boris M. van Breukelen
Back-diffusion of chlorinated ethenes (CEs) from low-permeability layers (LPLs) causes contaminant persistence long after the primary spill zones have disappeared. Naturally occurring degradation in LPLs lowers remediation time frames, but its assessment through sediment sampling is prohibitive in conventional remediation projects. Scenario simulations were performed with a reactive transport model (PHT3D in FloPy) accounting for isotope effects associated with degradation, sorption, and diffusion, to evaluate the potential of CSIA data from aquifers in assessing degradation in aquitards. The model simulated a trichloroethylene (TCE) DNAPL and its pollution plume within an aquifer-aquitard-aquifer system. Sequential reductive dechlorination to ethene and sorption were uniform in the aquitard and did not occur in the aquifer. After 10 years of loading the aquitard through diffusion from the plume, subsequent source removal triggered release of TCE by back-diffusion. In the upper aquifer, during the loading phase, δ13C-TCE was slightly enriched (up to 2‰) due to diffusion effects stimulated by degradation in the aquitard. In the upper aquifer, during the release phase, (i) source removal triggered a huge δ13C increase especially for higher CEs, (ii) moreover, downstream decreasing isotope ratios (caused by downgradient later onset of the release phase) with temporal increasing isotope ratios reflect aquitard degradation (as opposed to downstream increasing and temporally constant isotope ratios in reactive aquifers), and (iii) the carbon isotope mass balance (CIMB) enriched up to 4‰ as lower CEs (more depleted, less sorbing) have been transported deeper into the aquitard. Thus, enriched CIMB does not indicate oxidative transformation in this system. The CIMB enrichment enhanced with more sorption and lower aquitard thickness. Thin aquitards are quicker flushed from lower CEs leading to faster CIMB enrichment over time. CIMB enrichment is smaller or nearly absent when daughter products accumulate. Aquifer CSIA patterns indicative of aquitard degradation were similar in case of linear decreasing rate constants but contrasted with previous simulations assuming a thin bioactive zone. The Rayleigh equation systematically underestimates the extent of TCE degradation in aquifer samples especially during the loading phase and for conditions leading to long remediation time frames (low groundwater flow velocity, thicker aquitards, strong sorption in the aquitard). The Rayleigh equation provides a good and useful picture on aquitard degradation during the release phase throughout the sensitivity analysis. This modelling study provides a framework on how aquifer CSIA data can inform on the occurrence of aquitard degradation and its pitfalls. ...