The Pearl River estuary is an ecologically dynamic region located in southern China that experiences strong gradients in its biogeochemical properties. This study examined the seasonality of nutrient dynamics, identified related environmental responses, and evaluated how river discharge regulated nutrient sink and source. The field investigation showed significant differences of dissolved nutrients with seasons and three zones of the estuary regarding the estuarine characteristics. Spatially, nutrients exhibited a clear decreasing trend along the salinity gradient; temporally, their levels were obviously higher in summer than other seasons. The aquatic environment was overall eutrophic, as a result of increased fluxes of nitrogen and silicate. This estuary was thus highly sensitive to nutrient enrichment and related pollution of eutrophication. River discharge, oceanic current, and atmospheric deposition distinctly influenced the nutrient status. These factors accordingly may influence phytoplankton that are of importance in coastal ecosystems. Phytoplankton (in terms of chlorophyll) was potentially phosphate limited, which then more frequently resulted in nutrient pollution and blooms. Additionally, the nutrient sources were implied according to the cause–effect chains between nutrients, hydrology, and chlorophyll, identified by the PCA-generated quantification. Nitrogen was constrained by marine-riverine waters and their mutual increase-decline trend, and a new source was supplemented along the transport from river to sea, while a different source of terrestrial emission from coastal cities contributed to phosphate greatly.@en

As a tide propagates into the estuary, river discharge affects tidal damping, primarily via a friction term, attenuating tidal motion by increasing the quadratic velocity in the numerator, while reducing the effective friction by increasing the water depth in the denominator. For the first time, we demonstrate a third effect of river discharge that may lead to the weakening of the channel convergence (i.e. landward reduction of channel width and/or depth). In this study, monthly averaged tidal water levels (2003-2014) at six gauging stations along the Yangtze River estuary are used to understand the seasonal behaviour of tidal damping and residual water level slope. Observations show that there is a critical value of river discharge, beyond which the tidal damping is reduced with increasing river discharge. This phenomenon is clearly observed in the upstream part of the Yangtze River estuary (between the Maanshan and Wuhu reaches), which suggests an important cumulative effect of residual water level on tide-river dynamics. To understand the underlying mechanism, an analytical model has been used to quantify the seasonal behaviour of tide-river dynamics and the corresponding residual water level slope under various external forcing conditions. It is shown that a critical position along the estuary is where there is maximum tidal damping (approximately corresponding to a maximum residual water level slope), upstream of which tidal damping is reduced in the landward direction. Moreover, contrary to the common assumption that larger river discharge leads to heavier damping, we demonstrate that beyond a critical value tidal damping is slightly reduced with increasing river discharge, owing to the cumulative effect of the residual water level on the effective friction and channel convergence. Our contribution describes the seasonal patterns of tide-river dynamics in detail, which will, hopefully, enhance our understanding of the nonlinear tide-river interplay and guide effective and sustainable water management in the Yangtze River estuary and other estuaries with substantial freshwater discharge.@en

Based on a monthly field survey in 2011 of the Pearl River Estuary, the dynamics of polycyclic aromatic hydrocarbons (PAHs) in surface sediments (depth < 5 cm) were explored. The seasonal variations in PAH level and composition were investigated in this study, as well as their environmental behaviors, the role of particles, and source apportionment. The concentration of the sum of 16 priority PAHs (defined as ∑16PAHs) ranged from 0.32 to 1.10 μg/g, while that of the sum of 62 PAHs (defined as ∑tPAHs) varied from 0.83 to 2.75 μg/g. The levels of both the ∑16PAHs and ∑tPAHs peaked in February, although the minimum levels appeared in different months—December and August, respectively. The seasonal difference in the ∑tPAHs was significant (flood season, 7.69 μg/g; dry season, 10.51 μg/g). The 5-ring PAH compound (e.g., perylene) was the most abundant and was responsible for 35% of the total, which implied a terrestrial input source via the Pearl River. Sediment particles were predominantly composed of clayed sand, and sediment PAHs showed a greater tendency to be adsorbed onto the large-sized particles rather than the fine fractions. Total organic carbon (TOC) could considerably facilitate the sediment PAHs. Principal component analysis revealed that vehicle emission sources, petroleum sources, and combustion sources were the major anthropogenic contamination sources. The diagnostic ratios of various individual PAHs were also explored. These findings are particularly useful for understanding the geochemistry of organic pollutants in the complex estuarine environment.@en

When different tidal constituents propagate along an estuary, they interact because of the presence of nonlinear terms in the hydrodynamic equations. In particular, due to the quadratic velocity in the friction term, the effective friction experienced by both the predominant and the minor tidal constituents is enhanced. We explore the underlying mechanism with a simple conceptual model by utilizing Chebyshev polynomials, enabling the effect of the velocities of the tidal constituents to be summed in the friction term and, hence, the linearized hydrodynamic equations to be solved analytically in a closed form. An analytical model is adopted for each single tidal constituent with a correction factor to adjust the linearized friction term, accounting for the mutual interactions between the different tidal constituents by means of an iterative procedure. The proposed method is applied to the Guadiana (southern Portugal-Spain border) and Guadalquivir (Spain) estuaries for different tidal constituents (M2, S2, N2, O1, K1) imposed independently at the estuary mouth. The analytical results appear to agree very well with the observed tidal amplitudes and phases of the different tidal constituents. The proposed method could be applicable to other alluvial estuaries with a small tidal amplitude-to-depth ratio and negligible river discharge.@en