The composition of the atmosphere over the Aegean Sea (AS) during an 'Etesian' outbreak under the influence of biomass burning (BB) activity is investigated. Simulations with the fully coupled WRF-Chem model during the Aegean-GAME campaign (29/8-9/9/2011) are used to examine the BB effect over the region. Two distinct Etesian flow patterns characterized by different transport conditions are analysed. The influence of the off-line calculated BB emissions on the atmospheric chemical composition over the AS under these conditions is estimated. In addition, sensitivity runs are used to examine the influence of the biogenic emissions calculated on-line and the realistic representation of the stratosphere-troposphere exchange processes are investigated through the time-varying chemical boundary conditions from the MOZART global chemical transport model. The horizontal and vertical distributions of gaseous and aerosol species are simulated under long-range transport conditions and interpreted in relation to the evolution of the Planetary Boundary Layer (PBL). In the case of a weaker synoptic system (medium-range transport conditions), even a small variability of meteorological parameters in limited areas become critical for the spatial distribution of gases and aerosols. The BB activity increases O3, PM2.5 and organic matter concentrations up to 5.5 ppb, 5.8 μg m-3 and 3.3 μg m-3, respectively. The spatial extent of the simulated BB plumes is further examined by comparison with airborne measurements of hydrogen cyanide (HCN). The estimated effect of biogenic emissions on O3 and PM2.5 concentrations is either positive or negative (±6 ppb for O3 and up to ± 1 μg m-3 for PM2.5) depending on the emission algorithm employed. The realistic representation of the chemical boundary conditions reproduces an observed layer rich in O3 above 4 km, but also increases O3 concentrations inside the PBL by up to 40%.@en

Differential mobility analyzers (DMAs) are widely used to determine the size of aerosol particles, and to probe their size-dependent physicochemical properties when two are employed in tandem. A limitation of tandem DMA (TDMA) systems is their long measuring cycle when the properties of more than one monodisperse population of particles need to be probed. In this work, we propose a simple modification of the classical cylindrical DMA by including three monodisperse-particle outlets in its central electrode (namely, the 3MO-DMA), with the objective of using it as the first DMA in TDMA systems for reducing their measuring cycle. The performance of the 3MO-DMA at different flow conditions was evaluated using laboratory-generated aerosol particles, and compared with theoretical predictions. The theory predicted accurately (i.e., within 3%) the geometric mean diameters of the three distinct populations, as well as the resolutions of the first and the third outlet, under all experimental conditions. For the second outlet, the resolution was 10% to 74% lower than that predicted theoretically depending on the sheath-to-aerosol flow ratio. Nevertheless, the geometric standard deviation of the monodisperse aerosol from all the outlets was less than 1.09, which is sufficient for using the 3MO-DMA designed and tested in this work as a first DMA to produce a monodisperse aerosol flow containing three distinct particle populations in TDMA systems.@en

This study examines how new particle formation (NPF) in the eastern Mediterranean in summer affects CCN (cloud condensation nuclei) concentrations and cloud droplet formation. For this, the concentration and size distribution of submicron aerosol particles, along with the concentration of trace gases and meteorological variables, were studied over the central (Santorini) and southern Aegean Sea (Finokalia, Crete) from 15 to 28 July 2013, a period that includes Etesian events and moderate northern surface winds. Particle nucleation bursts were recorded during the Etesian flow at both stations, with those observed at Santorini reaching up to 1.5 × 104 particles cm-3; the fraction of nucleation-mode particles over Crete was relatively diminished, but a higher number of Aitken-mode particles were observed as a result of aging. Aerosol and photochemical pollutants covaried throughout the measurement period; lower concentrations were observed during the period of Etesian flow (e.g., 43-70 ppbv for ozone and 1.5-5.7 μg m-3 for sulfate) but were substantially enhanced during the period of moderate surface winds (i.e., increase of up to 32 for ozone and 140 % for sulfate). We find that NPF can double CCN number (at 0.1% supersaturation), but the resulting strong competition for water vapor in cloudy updrafts decreases maximum supersaturation by 14 % and augments the potential droplet number only by 12 %. Therefore, although NPF events may strongly elevate CCN numbers, the relative impacts on cloud droplet number (compared to pre-event levels) is eventually limited by water vapor availability and depends on the prevailing cloud formation dynamics and the aerosol levels associated with the background of the region.@en

The Differential Mobility Analyzer (DMA) is currently the most effective instrument for sizing sub-micrometer aerosol particles. An important requirement to ensure good performance in terms of sizing accuracy and resolution is that the flow field remains laminar and undisturbed along its classification zone. To achieve that, a flow straightener (or flow laminarizer) is employed at the sheath flow inlet, located at the top of the classification column. In this study, we assess the performance of a custom-made DMA using different sheath flow straighteners made out of plastic fabric materials or built by 3D printing. Our tests show that 3D-printed flow straighteners can achieve comparable, and in some cases better, results to those used in commercial DMAs (e.g., fine nylon meshes; Dacron®). Considering the great flexibility and ease in manufacturing offered by 3D printing, our findings show that this technology provides a promising alternative for building enhanced flow straightening systems.@en

Recent advanced in the fields of nanotechnology and atmospheric sciences underline the increasing need for sizing sub-10-nm aerosol particles in a simple yet efficient way. In this article, we develop, experimentally test and model the performance of a High-Pass Electrical Mobility Filter (HP-EMF) that can be used for sizing nanoparticles suspended in gaseous media. Experimental measurements of the penetration of nanoparticles having diameters down to ca 1nm through the HP-EMF are compared with predictions by an analytic, a semi-empirical and a numerical model. The results show that the HPEMF effectively filters nanoparticles below a threshold diameter with an extremely high level of sizing performance, while it is easier to use compared to existing nanoparticle sizing techniques through design simplifications. What is more, the HP-EMF is an inexpensive and compact tool, making it an enabling technology for a variety of applications ranging from nanomaterial synthesis to distributed monitoring of atmospheric nanoparticles.@en

Hygroscopic Tandem Differential Mobility Analyzers (HTDMAs) are widely used to measure the water uptake characteristics of aerosol particles. As has been shown experimentally in the past, potential differences in the relative humidity (RH) between the aerosol and the sheath flow of the second Differential Mobility Analyzer (DMA) can lead to erroneous estimates of the apparent hygroscopic behavior of the sampled particles. A prompt phase transition, for example, may become smeared and be erroneously interpreted as non-prompt. Using a particle-tracking model, here we simulate the trajectories and the state of the particles classified in a DMA with non-uniform RH and temperature profiles. Our simulations corroborate earlier observations proving that such an experimental artifact can induce particle growth within the second DMA. Given the importance of maintaining uniform RH and temperature inside the second DMA of HTDMA systems and the limitations of existing RH and temperature sensors, we further provide suggestions for their operation.@en

Particle number size distribution measurements were conducted during the summer of 2012 at City-Centre Urban Background (Patras-C), Urban Background (ICE-HT in Patras, DEM in Athens, EPT in Thessaloniki), and Regional Background stations (FIN in Crete). At the City-Centre Urban Background station, the average number distribution had a geometric mean diameter peak approximately at 60 nm and the highest number concentration, whereas at the Regional Background station and the Urban Background stations it displayed a major peak approximately at 100 nm, with the Regional Background station exhibiting the lowest number concentration. The particle number size distribution at each site was divided into size fractions and, based on their diurnal variation and previous studies, we concluded that the main sources for the City-Centre Urban Background station are traffic and the regional background concentration, for the Urban Background stations fresh traffic, aged traffic, cooking and the regional background concentration, and for the Regional Background station local activities (tourism, cooking) and regional background concentration. The median number concentration that is attributed to regional background concentration for the City-Centre Urban Background, the Urban Background and the Regional Background stations are respectively 13, 29 and 45% of the total number concentration. Nucleation events were identified at DEM station, where the newly formed particles accounted for 4% of the total particle concentration for the measurement period in the size range 10–20 nm, EPT, where they accounted for 12%, and FIN, where they accounted for 1%, respectively. New Particle Formation events contribution during summer to Condensation Cloud Nuclei were therefore insignificant in the Eastern Mediterranean. Modal analysis was performed on the number distributions and the results were classified in clusters. At the City-Centre Urban Background station, the cluster-source that dominated number concentration and frequency is related to fresh and aged traffic emissions, at the Urban Background stations aged traffic emissions, while at the Regional Background station number and frequency were dominated by the regional background concentration. Based on cluster analysis, 18% of the median number distribution was due to long range transport at the City-Centre Urban Background site, 37% at the Urban Background sites, and 59% at the Regional Background site. The Flexible Particle Dispersion Model (FLEXPART) was used in order to acquire geographic origin clusters and we concluded that the Etesian flow increases the median regional background number concentration in the Mediterranean basin by a factor of 2.5–4.@en

The Alphasense optical particle counter (OPC) provides a low-cost and lightweight solution for measurements of the size and number concentration of airborne particulate matter (PM). The micro fan with which it is originally equipped cannot, however, achieve a high enough pressure differential for maintaining an adequate flow rate when connected to sampling/pretreatment aerosol lines, limiting its use for air quality monitoring. Here, we propose a simple modification on the sample flow system that enables the connection of the Alphasense OPC with sampling/pretreatment lines (e.g., dryers) commonly employed on ground observational sites, as well as its use onboard Unmanned Aerial Systems (UASs). Tests of the modified OPC using monodisperse polystyrene spherical (PS) particles having sizes between 0.8 and 2.5 μm show that both the sizing and counting performance of the modified instrument is in agreement with that of a calibrated reference OPC at concentrations from ca. 50 to 800 #/ml, which are typically encountered in the atmosphere in that size range. For particle number concentrations below or above this range, we observed a concentration-dependent counting efficiency, which can be corrected using a polynomial function derived from our measurements. Tests conducted under reduced pressure and temperature conditions demonstrate the capability of the modified OPC for accurately (i.e., within 13% deviation from the reference measurements) determining the size and number concentration of the sampled particles. The tests reported in this work show that the proposed modification can qualify the Alphasense OPC for use in both ground and aerial observations without affecting its performance, and at the same time maintaining its strongly desired characteristics (i.e., cost effectiveness and high portability).@en

Modern electrochemical gas sensors hold great potential for improving practices in air quality (AQ) monitoring as their low cost, ease of operation and compact design can enable dense observational networks and mobile measurements. Despite that, however, numerous studies have shown that the performance of these sensors depends on a number of factors (e.g. environmental conditions, sensor quality, maintenance and calibration), thereby adding significant uncertainties in the reported measurements and large discrepancies from those recorded by reference-grade instruments. In this work we investigate the performance of electrochemical sensors, provided by two manufacturers (namely Alphasense and Winsen), for measuring the concentrations of CO, NO2, O3 and SO2. To achieve that we carried out collocated yearlong measurements with reference-grade instruments at a traffic AQ monitoring station in Nicosia, Cyprus, where temperatures ranged from ca. 0 ∘C in the winter to almost 45 ∘C in the summer. The CO sensors exhibit the best performance among all the ones we tested, having minimal mean relative error (MRE) compared to reference instruments (ca. −5 %), although a significant difference in their response was observed before and after the summer period. At the other end of the spectrum, the SO2 sensors reported concentration values that were at least 1 order of magnitude higher than the respective reference measurements (with MREs being more than 1000 % for Alphasense and almost 400 % for Winsen throughout the entire measurement period), which can be justified by the fact that the concentrations of SO2 at our measuring site were below their limit of detection. In general, variabilities in the environmental conditions (i.e. temperature and relative humidity) appear to significantly affect the performance of the sensors. When compared with reference instruments, the CO and NO2 electrochemical sensors provide measurements that exhibit increasing errors and decreasing correlations as temperature increases (from below 10 to above 30 ∘C) and RH decreases (from >75 % to below 30 %). Interestingly, the performance of the sensors was affected irreversibly during the hot summer period, exhibiting different responses before and after that, resulting in a signal deterioration that was more than twice that reported by the manufacturers. With the exception of the Alphasense NO2 sensor, all low-cost sensors (LCSs) exhibited measurement uncertainties that were much higher, even at the beginning of our measurement period, compared to those required for qualifying the sensors for indicative air quality measurements according to the respective European Commission (EC) Directive. Overall, our results show that the response of all LCSs is strongly affected by the environmental conditions, warranting further investigations on how they are manufactured, calibrated and employed in the field.@en

This study investigates the concentration, cloud condensation nuclei (CCN) activity and hygroscopic properties of particles influenced by biomass burning in the eastern Mediterranean and their impacts on cloud droplet formation. Air masses sampled were subject to a range of atmospheric processing (several hours up to 3 days). Values of the hygroscopicity parameter, κ, were derived from CCN measurements and a Hygroscopic Tandem Differential Mobility Analyzer (HTDMA). An Aerosol Chemical Speciation Monitor (ACSM) was also used to determine the chemical composition and mass concentration of non-refractory components of the submicron aerosol fraction. During fire events, the increased organic content (and lower inorganic fraction) of the aerosol decreases the values of κ, for all particle sizes. Particle sizes smaller than 80 nm exhibited considerable chemical dispersion (where hygroscopicity varied up to 100% for particles of same size); larger particles, however, exhibited considerably less dispersion owing to the effects of condensational growth and cloud processing. ACSM measurements indicate that the bulk composition reflects the hygroscopicity and chemical nature of the largest particles (having a diameter of ∼ 100 nm at dry conditions) sampled. Based on positive matrix factorization (PMF) analysis of the organic ACSM spectra, CCN concentrations follow a similar trend as the biomass-burning organic aerosol (BBOA) component, with the former being enhanced between 65 and 150% (for supersaturations ranging between 0.2 and 0.7%) with the arrival of the smoke plumes. Using multilinear regression of the PMF factors (BBOA, OOA-BB and OOA) and the observed hygroscopicity parameter, the inferred hygroscopicity of the oxygenated organic aerosol components is determined. We find that the transformation of freshly emitted biomass burning (BBOA) to more oxidized organic aerosol (OOA-BB) can result in a 2-fold increase of the inferred organic hygroscopicity; about 10% of the total aerosol hygroscopicity is related to the two biomass-burning components (BBOA and OOA-BB), which in turn contribute almost 35% to the fine-particle organic water of the aerosol. Observation-derived calculations of the cloud droplet concentrations that develop for typical boundary layer cloud conditions suggest that biomass burning increases droplet number, on average by 8.5%. The strongly sublinear response of clouds to biomass-burning (BB) influences is a result of strong competition of CCN for water vapor, which results in very low maximum supersaturation (0.08% on average). Attributing droplet number variations to the total aerosol number and the chemical composition variations shows that the importance of chemical composition increases with distance, contributing up to 25% of the total droplet variability. Therefore, although BB may strongly elevate CCN numbers, the impact on droplet number is limited by water vapor availability and depends on the aerosol particle concentration levels associated with the background.@en

We report measurements of the size, concentration, and hygroscopicity of ultrafine particles (UFPs) emitted during thermal spraying of ceramic coatings in an industrial setting. High concentrations (i.e., higher than 106 cm−3) of fractal-like UFPs were measured inside the spraying booths of the facility. The emitted UFPs were found to take up small amounts of water when exposed to elevated relative humidity (RH = 87%) within a Hygroscopic Tandem Differential Mobility Analyzer (HTDMA) system. The hygroscopicity of the sampled particles was distinguishably lower compared to those of the atmospheric background aerosol particles present in the breathing air. UFPs smaller than 90 nm that are produced by the thermal spraying process, exhibit hygroscopic factors less than unity in a systematic way. This behavior indicates that the particles were irregularly shaped at dry conditions, and that they underwent a shape change (i.e., restructuring) upon humidification inside the HTDMA. The fractal-like structure of process-emitted UFPs was further corroborated by Transmission Electron Microscopy (TEM) conducted on samples collected at dry conditions on site.@en

A sharp-cut cyclone with an aerodynamic cut-off diameter of 1 μm, when operated at a flow rate of 1 L min−1, was built by 3D-printing and tested against a metallic (aluminum) counterpart having the same design and dimensions. The penetration efficiency of both cyclones was experimentally determined using quasi-monodisperse aerosol particles having aerodynamic diameters from ca. 100 nm to 2 μm. The aerodynamic cut-off diameter for both cyclones was very similar and in accordance with the expected design value. The penetration efficiency curve of the 3D-printed cyclone was less steep compared to that of its metallic counterpart. This difference is most likely attributed to the higher surface roughness of the inner parts of the 3D-printed cyclone - as also indicated by the greater pressure drop it exhibits compared to the aluminum cyclone when operated at the same flow rate - and not by higher deviations from its design dimensions resulting from the tolerances of the 3D printer. Despite that, the substantially low cost, speed, and ease of manufacturing, make the 3D-printed cyclone a highly promising solution for applications in aerosol metrology.@en

Air quality monitoring using airborne platforms is rapidly gaining ground as unmanned aerial vehicles (UAVs) are becoming easier, less expensive, and safer to operate on a routine basis. To facilitate measurements of key atmospheric properties, however, efforts are still required in developing/testing miniaturized instruments for use onboard UAVs. Here, we test two commercially available cost-effective/lightweight optical particle counters (OPCs; Alphasense Model N2) capable of measuring the size distributions of airborne particles having diameters from 380 nm to 17 μm. Tests were made against a reference and recently calibrated OPC (Grimm Model 1.109) using monodisperse polystyrene spheres. All instruments were placed in a chamber in which the temperature and pressure varied in the ranges of –5 to 23°C and 0.7 to 1.0 atm, respectively; conditions typically encountered during UAV flights. Agreement in the particle number concentrations measured by the Alphasense and the Grimm OPCs was within 40%, under all experimental conditions used in this work, when particles having sizes >1 μm were employed during the tests. Deviations higher than 50%, however, were observed when the instruments were tested with 1.0- and 0.8-μm polysterene spheres. The particle sizes reported by both Alphasense OPCs were within ± 5% with respect to the nominal polysterene spheres’ size under all operating pressures and temperatures down to 5°C. At lower temperatures, the sizing accuracy of one of the two Alphasense OPCs degraded significantly. While our findings support that the Alphasense OPCs can be used at low temperature/pressure conditions, they should be carefully tested prior the measurements to ensure good performance.@en

Portable instruments that can measure the number concentration and size of airborne nanoparticles are very useful for assessing their impacts on human health and climate, mainly because they can enable personal monitoring when carried by individuals, and/or 2- or 3-dimensional mappings when employed onboard mobile platforms. Partector 2 (P2), which is a lightweight and portable instrument manufactured by Naneos Particle Solutions GmbH (Windisch, Switzerland), can determine the concentration (up to 106 #/cm3) and average diameter of aerosol particles having sizes from 10 to 300 nm, making it an excellent candidate for such measurements. Although its performance has been investigated at standard conditions (i.e., ground level pressure and room temperatures), it has not been assessed under reduced pressure and temperature conditions that are typically encountered at higher altitudes; e.g., when employed outdoors in mountainous environments and/or onboard Unmanned Aerial Systems; UASs. Here we assess the counting and sizing capabilities of P2 at temperatures from ca. 22 down to 4 °C, and pressures from 1013 down to 710 hPa that correspond to altitudes from sea level to ca. 3 km. Our results show that the performance of the instrument is not substantially affected when operated at these conditions, remaining within the accuracy thresholds of ±30% reported by the manufacturer. P2, therefore, qualifies for outdoor use at higher altitudes, and can be employed in such environments to determine the number concentration and mean size of sub-300 nm aerosol particles, complementing existing portable optical particle counters that are already employed onboard aerial systems.@en