We use a hybrid superconductor-semiconductor transmon device to perform spectroscopy of a quantum dot Josephson junction tuned to be in a spin-1/2 ground state with an unpaired quasiparticle. Because of spin-orbit coupling, we resolve two flux-sensitive branches in the transmon spectrum, depending on the spin of the quasiparticle. A finite magnetic field shifts the two branches in energy, favoring one spin state and resulting in the anomalous Josephson effect. We demonstrate the excitation of the direct spin-flip transition using all-electrical control. Manipulation and control of the spin-flip transition enable the future implementation of charging energy protected Andreev spin qubits.

Inhomogeneous superconductors can host electronic excitations, known as Andreev bound states (ABSs), below the superconducting energy gap. With the advent of topological superconductivity, a new kind of zero-energy ABS with exotic qualities, known as a Majorana bound state (MBS), has been discovered. A special property of MBS wavefunctions is their non-locality, which, together with non-Abelian braiding, is the key to their promise in topological quantum computation. We focus on hybrid superconductor–semiconductor nanowires as a flexible and promising experimental platform to realize one-dimensional topological superconductivity and MBSs. We review the main properties of ABSs and MBSs, state-of-the-art techniques for their detection and theoretical progress beyond minimal models, including different types of robust zero modes that may emerge without a band-topological transition.

Superconductors containing magnetic impurities exhibit intriguing phenomena derived from the competition between Cooper pairing and Kondo screening. At the heart of this competition are the Yu-Shiba-Rusinov (Shiba) states which arise from the pair breaking effects a magnetic impurity has on a superconducting host. Hybrid superconductor-molecular junctions offer unique access to these states but the added complexity in fabricating such devices has kept their exploration to a minimum. Here, we report on the successful integration of a model spin 1/2 impurity, in the form of a neutral and stable all organic radical molecule, in proximity-induced superconducting break junctions. Our measurements reveal excitations which are characteristic of a spin-induced Shiba state due to the radical's unpaired spin strongly coupled to a superconductor. By virtue of a variable molecule-electrode coupling, we access both the singlet and doublet ground states of the hybrid system which give rise to the doublet and singlet Shiba excited states, respectively. Our results show that Shiba states are a robust feature of the interaction between a paramagnetic impurity and a proximity-induced superconductor where the excited state is mediated by correlated electron-hole (Andreev) pairs instead of Cooper pairs.