The above-ground biomass of Spartina alterniflora salt marsh meadows is influenced by numerous interacting factors, among them elevation, tidal range and inundation duration. Bio-geomorphological models make use of either linear or quadratic equations, but it is important to be aware that the variables are area specific and hence not generic. In order to explore the vegetation growth pattern and its influencing factors along the Jiangsu coast, China, field surveys were conducted in two typical S. alterniflora marshes along the coast of Dafeng and Rudong. To combine the influence of elevation and the effect of tidal range, the inundation ratio (IR) is introduced as a novel parameter, which is the ratio between inundation duration and the duration of the whole tidal period concerned. The relationship between above-ground biomass and IR can be expressed by a quadratic equation. The optimal inundation ratio for S. alterniflora along the Jiangsu coast ranges from 0.21 to 0.26, which is much lower than, for example, that for the marsh of North Inlet (0.35), South Carolina, and the Virginia Coast Reserve (0.41), USA. Tidal range plays a significant role in that a larger tidal range leads to a smaller optimal IR, and that the landward and seaward limits are displaced toward higher ground elevations. In macrotidal regions the submergence depth is larger, which results in enhanced submergence and salinity stress for the entire marsh, causing it to shift toward higher elevations. Tidal range is an important factor influencing the growth pattern of S. alterniflora, but geomorphological factors such as topographic profiles, and the presence of cliffs and tidal creeks must also be taken into account.@en

The work presented here shows that the growth of supramolecular hydrogel fibers can be spatially directed at the nanoscale by catalytic negatively charged nanoparticles (NCNPs). The NCNPs with surfaces grafted with negatively charged polymer chains create a local proton gradient that facilitates an acid-catalyzed formation of hydrogelators in the vicinity of NCNPs, ultimately leading to the selective formation of gel fibers around NCNPs. The presence of NCNPs has a dominant effect on the properties of the resulting gels, including gelation time, mechanical properties, and network morphology. Interestingly, local fiber formation can selectively entrap and precipitate out NCNPs from a mixture of different nanoparticles. These findings show a new possibility to use directed molecular self-assembly to selectively trap target nano-objects, which may find applications in therapy, such as virus infection prevention, or engineering applications, like water treatment and nanoparticle separation.@en

The work presented here shows that the growth of supramolecular hydrogel fibers can be spatially directed at the nanoscale by catalytic negatively charged nanoparticles (NCNPs). The NCNPs with surfaces grafted with negatively charged polymer chains create a local proton gradient that facilitates an acid-catalyzed formation of hydrogelators in the vicinity of NCNPs, ultimately leading to the selective formation of gel fibers around NCNPs. The presence of NCNPs has a dominant effect on the properties of the resulting gels, including gelation time, mechanical properties, and network morphology. Interestingly, local fiber formation can selectively entrap and precipitate out NCNPs from a mixture of different nanoparticles. These findings show a new possibility to use directed molecular self-assembly to selectively trap target nano-objects, which may find applications in therapy, such as virus infection prevention, or engineering applications, like water treatment and nanoparticle separation.@en

Tidal flats, where significant land‐ocean interactions take place, are often abstracted as a cross‐shore bed profile with sediment zonation from the lower sand flat to the upper mud flat. However, in addition to cross‐shore tidal currents, the impact of the alongshore components on cross‐shore sediment transport, morphological evolution, and sediment grain‐size change remains unclear. Here we investigated sand‐mud tidal flat morphodynamics in the absence of waves by combining approaches of field observations, numerical modeling, and analytical interpretations, based on the example of the tidal flat on the central Jiangsu coast, China. The results show that the morphodynamic processes are complicated by the interactions of cross‐shore and alongshore tidal currents, cross‐shore flat morphology, and sediment zonation. With amplified phase lags of the alongshore tidal level at the boundaries, alongshore currents become dominant over cross‐shore tidal currents on the lower flat, while the upper flat is always dominated by the cross‐shore currents. Therefore, bed profiles and mud content on the upper flat were independent of the alongshore tidal current magnitude, being convex‐up and consisting of mud. In contrast, the strong alongshore currents can erode mud on the lower flat and promote landward sand transport from the subtidal area to the lower flat, forming a sand flat. The maximum tidal bed shear stress is almost spatially uniform across the muddy area but pronouncedly elevated where the bed sediment coarsens on the lower flat. The contributions of the alongshore tidal currents and sand‐mud sorting processes should be appropriately addressed in similar coastal environments.@en

Hollow silica nanoparticles were prepared through generating a silica layer in spherical polyelectrolyte nanogels (SPN), which consisted of a solid core of polystyrene (PS) and a shell of crosslinked poly(acrylic acid) (PAA), followed by removing the PS core via solvent dissolution. Small angle X-ray scattering (SAXS) in combination with TEM were employed to observe SPN, silica-polymer composite, and hollow silica nanoparticles. It was confirmed that SAXS is a powerful method to monitor the generation of silica layer in SPN. The density and thickness of generated silica layer in SPN were found to be tunable by controlling the crosslinking density of the templates. The porous structure and pH sensitivity of silica layer allowed the obtained hollow silica to be ideal carriers for controlled drug delivery.@en