NH₃/H₂O based systems are promising for thermal energy storage and thermal energy conversion. These systems are used for absorption energy storage and Kalina cycles. This paper investigates the condensation of high-concentration NH₃/H₂O in vertically downward plate heat exchangers. A combined method is proposed by discussing the applicability of equilibrium and non-equilibrium models. Both models are necessary for zeotropic mixtures with large temperature glide. The non-equilibrium model applies where the temperature glide is non-linear or the vapor is in non-equilibrium with the liquid. The equilibrium model becomes applicable with decreasing vapor qualities. Heat transfer correlations are proposed according to the equilibrium model, which interpret convective condensation and gravity-controlled condensation. The additional heat transfer resistance is calculated considering mass transfer. The non-equilibrium model is further developed quantifying the heat and mass transfer of vapor and neglecting the mass transfer resistance of the liquid. The non-equilibrium model transforms into the equilibrium model as the concentration gradient of vapor approaches zero. Additionally, a frictional pressure drop model for separated flow conditions is proposed and quantifies the two-phase shear force.

The performance of a magnetocaloric heat pump (MCHP) consisting of active magnetocaloric regenerators (AMR) of 12 layers of MnFePSi magnetocaloric materials (MCM) with a linear distribution of Curie temperatures was investigated using a 1D numerical model. The model predicted the heating power and coefficient of performance (COP) of the AMR for a fixed temperature span of 27 K, between 281 K and 308 K, and variable flow rate and AMR cycle frequency. A maximum applied magnetic field strength of 1.4 T was used. A well-insulated house with a maximum heating power demand of 3 kW (under quasi steady state conditions) was considered. Ambient temperature in The Netherlands was taken as a reference for the estimation of the seasonal heating power demand. Without optimizing the design of the AMR, the model predicts a maximum single-AMR heating power equal to 43.5 W when the AMR operates at 3 Hz and 3 L min^-1, and a maximum COP equal to 5.8 when it operates at 1.5 Hz and 1 L min^-1 Considering the maximum heating power of a single AMR, approximately 69 AMRs are needed to provide the design heating power demand of the house. It was found that it is possible to achieve an AMR seasonal COP of 5.6 by continuously adjusting the flow rate and frequency of operation of the MCHP along with the ON/OFF switching of some groups of AMRs in order to adjust the heating power of the MCHP to the heating power demand of the house.

High concentration NH₃/H₂O is suitable for Kalina cycles used for the recovery of low grade heat. Plate heat exchangers (PHEs) are compact and reduce the charge of working fluid. This paper investigates the condensation of NH₃/H₂O with NH₃ mass concentrations of 80%-96%. The vapor and liquid concentrations are close to equilibrium state, which are different from normal absorbers. The apparent heat transfer coefficients (HTCs) and frictional pressure drop are presented, covering the mass fluxes of 32–86 kgm⁻²s⁻¹, the averaged vapor qualities of 0.08–0.65 and the saturated pressure of 610 to 780 kPa. Larger mass fluxes noticeably increase the apparent HTCs and frictional pressure drop. At the mass concentrations of 96%, 91% and 88%, higher vapor qualities increase the apparent HTCs for large mass fluxes. The apparent HTCs decrease slightly with vapor qualities for 80% mass concentration. The experimental results are compared with those of pure NH₃. The flow patterns of high concentration NH₃/H₂O are considered as full film flow and partial film flow, which are the same as for NH₃. The mass transfer resistance deteriorates the heat transfer especially for partial film flow, which happens at small liquid mass fluxes. The mass transfer resistance has negligible influences on frictional pressure drop.

The development of affordable magnetocaloric materials (MCM) with a giant magnetocaloric effect (MCE) has brought magnetocaloric heat pumps a step closer to commercialization. The narrow temperature range in which these materials exhibit a large MCE demands the use of several materials with Curie temperatures covering the temperature span of the heat pump in a so-called layered active magnetocaloric regenerator (AMR). How to place these materials in the AMR in terms of distribution of Curie temperatures and thickness of each layer is still a topic of study. In this research we used a one dimensional numerical model to unveil potential benefits of either using a distribution of Curie temperatures that follows a sigmoidal shape or using thicker layers at the cold and hot ends of the AMR along with a linear distribution of Curie temperatures. We found that these AMRs are less sensitive to changes in the hot and cold reservoir temperatures compared to an AMR that uses just a linear distribution of Curie temperatures with uniform layer length, but only the one with thicker ends produces similar heating capacities and second law efficiencies. The heating capacity of the simulated AMR with a sigmoidal distribution of Curie temperatures varies only 5.6 % in a high utilization scenario, flow rate 37.5 g/s and a frequency of 0.75 Hz, when the hot side temperature changes from 308 K to 312 K and the temperature span is 18 K while the corresponding change is 8.7 % for the AMR with thicker end layers, and 37.9 % for the one with a linear distribution of Curie temperatures. For the considered geometry and operating conditions, the maximum heating capacities with temperature span 27 K in the high utilization scenario are 28.6 W, 23.0 W, and 28.5 W, whereas the corresponding second law efficiencies are 33.2%, 27.3 %, and 32.7% for the AMRs with linear distribution of Curie temperatures, sigmoid distribution, and linear distribution with thicker ends respectively.

Heat pumps can drastically reduce energy requirements in industry. Operating a compression resorption heat pump with an NH₃-CO₂-H₂O mixture has been identified as a promising option that can have an increased performance compared to only NH₃-H₂O. In this paper an important process of the heat pump cycle is investigated: The absorption process. A mini-channel heat exchanger with 116 tubes of inside diameter of 0.5 mm is used for this purpose. For the NH₃-H₂O experiments overall heat transfer coefficients of 2.7–6 kW/(m²K) were reached for mixture mass flows of 0.71–2.5 kg/h. For the NH₃-CO₂-H₂O mixture pumping instabilities limited the operating range which resulted in higher pressures and higher mixture mass flows compared to NH₃-H₂O. The overall heat transfer coefficients were lower in the case of the added CO₂, with the maximum of 3 kW/(m²K) corresponding to a mixture mass flow of 4.2 kg/h. However, an increase in heat transfer of approximately 5% was reached with the added CO₂ which is beneficial for heat pump applications. Additionally, limited research has been conducted on absorption in upward versus downward flow and, therefore, these two configurations have also been tested in the mini-channel heat exchanger. Even though the pumping instabilities vanished with absorption in upward flow it was confirmed that absorption in downward flow with the mixture on the tube side is the most beneficial configuration for absorption of ammonia in NH₃-CO₂-H₂O or NH₃-H₂O in a mini-channel heat exchanger. The performance increased by approximately 10% with absorption in downward flow.

Heat pumps can efficiently upgrade waste heat from the industry and in that way reduce emissions. One of the main reasons why heat pumps are not applied to a greater extent in industry are large payback periods. Compression–resorption heat pumps (CRHP) enhanced by wet compression are considered a very promising option that can have higher coefficient of performance compared to traditional technologies when the heat source and/or sink have a large temperature glide. In this study the thermodynamic and economic performance of two potential industrial cases are examined for CRHP operating with NH₃–H₂O and NH₃–CO₂–H₂O. A detailed thermodynamic model of the compressor is used to evaluate the isentropic efficiency for each case. The results are used to calculate the simple payback period, when a boiler is replaced by a CRHP, as a function of the predicted gas and electricity prices in the Netherlands from 2020 to 2035. The results indicate that adding CO₂ to the NH₃–H₂O mixture increases the cycle COP when the temperature glide of the heat sink is 40 K while the opposite occurs when the glide is 80 K. The highest COPs and lowest payback times are obtained when the outlet vapor quality is around 0.50 for both the binary and ternary mixtures. Larger glides require higher outlet qualities. However, it is clear that even for high temperature glides the payback period can be within acceptable limits, especially if the cost of CO₂ emissions is taken into account.

This paper develops predicting models for NH₃ condensation in plate heat exchangers based on the experiments of flow patterns, heat transfer coefficients and frictional pressure drop previously reported by the authors. The aim is to provide design methods of compact plate condensers used in NH₃ systems, which are not available in open literature. The experimental data are firstly compared with selected correlations, showing a poor agreement. A heat transfer model is developed based on flow patterns, which represents the transition from convective condensation to gravity-controlled condensation. The physical interpretation of the two-phase multiplier approach and the deviation from Nusselt's theory are discussed. A transition criterion of condensation mechanisms is proposed based on the wetting characteristics. Since the flow patterns indicate separated flow, the Lockhart and Martinelli model is selected and is modified to predict the frictional pressure drop. The model is the sum of the liquid pressure drop, vapor pressure drop and interface pressure drop. The contributions of vapor pressure drop and interface pressure drop are discussed and quantified. The proposed heat transfer and frictional pressure drop models show good predictive performances. NH₃ flow has large two-phase slip because of the large density ratio. Plate heat exchangers have corrugated channels and tend to break up the liquid film. The models identify the distinct flow characteristics based on flow patterns.

This paper investigates NH₃ condensation in a plate heat exchanger by visualizing the flow patterns and measuring heat transfer coefficients and frictional pressure drop. Visualization experiments were conducted between 20 and 100 kgm⁻²s⁻¹. Full film flow takes place at large mass fluxes and intermediate mass fluxes of low vapor qualities, while partial film flow occurs at small mass fluxes and intermediate mass fluxes at high vapor qualities. The heat transfer and frictional pressure drop experiments cover the mass fluxes of 21~78 kgm⁻²s⁻¹, the averaged vapor qualities of 0.05~0.65 and the saturated pressure of 630 to 930 kPa. Vapor qualities have significant influences on heat transfer and frictional pressure drop. In the tested ranges, the effect of mass fluxes is noticeable on frictional pressure drop, but is moderate on heat transfer. The impact of saturated pressure is small. The heat transfer reflects the change of flow patterns. The frictional pressure drop shows the characteristics of separated flow.

Compression-resorption heat pumps (CRHP) utilizing wet compression are a very promising option to upgrade waste heat from industry. CRHPs have the potential to have higher coefficient of performance (COP) than the traditionally used vapour-compression heat pumps (VCHP). However, commercial solutions utilizing wet compression are not available yet. Also, wet compression is a feasible option only if the efficiency of the compressor is sufficiently high, 0.7 or higher, as identified by several authors. In this study, we develop and validate a model of a twin screw compressor that is suitable for wet compression. The model is adapted to calculate the entropy production generation in order to identify where the major irreversibilities are located in the compressor. The effects of clearance size, rotational speed, ammonia concentrations, compressor inlet vapor quality as well as under- and over compression are analysed. The results show that the clearance size and the rotational speed have the largest effects on the entropy production. Additionally, increased ammonia concentration and decreased vapor quality lead to decreased losses. The results indicate that it should be feasible to reach the targeted performance if the clearances size is limited to 50 μm, the rotational speed maintained above 10,000 rpm, the ammonia concentration kept in the range of 30–40 wt.%, and the inlet vapor quality in the range 0.5–0.7.

Unfavorable transport properties have always been pointed out as the key factors that hinder the application of ammonia/ionic liquids (NH ₃ /ILs) in absorption cycles, while heat and mass transfer of these new fluids in components have been rarely reported. In this study, a corrugated plate heat exchanger is selected as the geometry for exploring the absorption of NH ₃ in the proposed NH ₃ /ILs working fluids. The process is studied making use of a semi-empirical framework: experimental data is needed to determine unknown information of heat and mass transfer, and a numerical model is developed making use of frequently applied theories. In addition, relevant transport properties of the NH ₃ /ILs working fluids are modeled based on collected experimental data. The proposed model is used to study the heat and mass transfer performance during the absorption of NH ₃ vapor into NH ₃ /ILs fluids. Distribution of local parameters and overall heat and mass transfer characteristics are obtained. The performance of absorption of NH ₃ into different working fluids is investigated as well. The overall heat transfer coefficient is found around 1.4 kW/(m ² ·K) for the most promising working fluid NH ₃ /[emim][SCN].

Negative transport properties have always been pointed out as the key factors that hinder the application of ammonia/ionic liquids (NH3/ILs) in the absorption cycles, while heat and mass transfer of these new fluids in components have been rarely reported. The authors selected corrugated plate heat exchangers as the geometry to explore the absorption of the proposed working fluids. In this paper, a modeling method and a continuous absorption-desorption setup are introduced. Absorption process is modeled with the two-resistance theory by introducing a gas-liquid interface. Analytical heat transfer results and mass transfer from penetration theory are applied. With the model, distribution of local parameters and overall heat and mass transfer characteristics of an absorber in a cooling application are obtained. The overall heat transfer coefficient of an absorber for a refrigeration application is around 1350 W/(m²K) for the studied NH3/IL working fluids. An experimental setup is developed for further model improvement.

Solar-based poly-generation systems with thermally driven sorption heat pump / chillers use the condensation heat of ORC to cover heating and cooling loads of buildings. In the present study the performance of such systems when used in buildings in the Netherlands and Greece is investigated taking both exergy efficiency and economic aspects into account. The alternative of using PV-panels and electrically driven vapour compression heat pumps / chillers is also investigated. The performance of the systems is compared to the performance of conventional heating and cooling systems. Higher exergy efficiencies can be attained with the ORC sorption systems only for unacceptably long payback times. Optimum systems will have low exergy efficiency (8 %) compared to the exergy efficiency of conventional systems (16 %) and still long payback times (longer than 19 years). PV - panel vapour compression heat pump / chiller systems have generally acceptable payback times smaller than 10 years.