AK

A. Kosari

22 records found

Atmospheric corrosion of iron under a single droplet

A new systematic multi-electrochemical approach

Utilizing a dedicated micro-sized three-electrode cell, this study systematically investigates early-stage electrochemical properties and corrosion behavior of pure iron under single droplets. Various volumes and NaCl concentrations were considered during the evaporation-driven s ...
The corrosion inhibiting effect of lithium carbonate has been studied over the pH range relevant for atmospheric corrosion conditions at the polymer/metal interface. It is demonstrated that lithium carbonate offers optimum corrosion protection under moderately alkaline conditions ...
We study microstructure, mechanical, and corrosion properties of Zr1-xCrxBy coatings deposited by hybrid high-power impulse/DC magnetron co-sputtering (CrB2-HiPIMS/ZrB2-DCMS). Cr/(Zr + Cr) ratio, x, increases from 0.13 to 0.9 ...
The formation process of a lithium-based conversion layer on AA2024-T3 and its corrosion protective behavior are studied using electrochemical noise (EN). Wavelet transform, as well as noise resistance analysis, have been employed to interpret the EN data. The EN data confirmed f ...
Electroless nickel (Ni) immersion gold (Au), commonly referred to by the acronym ENIG, is the most common protective coating applied on the exposed copper (Cu) traces of printed circuit boards (PCBs). In this work, we elucidate the local corrosion mechanism of the ENIG-Cu system ...
Liquid-phase transmission electron microscopy (LP-TEM) has provided corrosion scientists with a unique opportunity to directly correlate nanoscopic morphological and compositional evolutions to the corresponding electrochemical response of corroding thin TEM specimens. Electroche ...
For many decades, corrosion and corrosion inhibition of high-strength aluminium alloys have been studied indirectly and through traditional and separately performed electrochemical, spectroscopic and microscopic techniques. These approaches employed to date commonly lack sufficie ...
Cerium-based compounds have been studied for decades as non-toxic candidates for the protection of aerospace aluminium alloys (AAs) like AA2024-T3. However, the complex heterogeneous microstructure of these alloys has hindered a thorough understanding of the subsequent stages of ...
Lithium leaching coatings have recently been developed as eco-friendly active corrosion protection technology for aerospace aluminium alloys (AAs) by the formation of a conversion layer at coating defects. While general conversion layer formation characteristics were studied and ...
Lithium salts have been proposed as promising environmentally friendly alternatives to carcinogenic hexavalent chromium-based inhibitors for the corrosion protection of aerospace aluminium alloys (AAs). Incorporated into organic coatings, lithium salts are released at damaged loc ...
The soil corrosion of widely applied galvanized steel structures, such as power transmission towers, must be considered to prevent harm to their structural integrity and to mitigate the high costs associated with early failure. A full two-level factorial design was used to evalua ...
Aluminum alloy (AA) 3003 is widely used as fin and tube material in heat exchangers. In these heat exchangers, the tube and fin material are brazed together by means of an AA4xxx alloy. In this study, the effect of a simulated brazing step on the microstructure and corrosion beha ...
This work focuses on the cross-sectional characterization of the protective conversion layer formed on AA2024-T3 by lithium-leaching from a polyurethane coating in a corrosive environment. The layer shows a multi-layered arrangement comprising nanoscopic local phases. Transmissio ...
Nanoscopic characterization of heterogeneous intermetallic particles (IMPs) which microstructurally and compositionally evolve during local corrosion is crucial in unravelling the mechanisms and sequence of initial and local corrosion events. Herein, we study site-specific initia ...
Identifying corrosion initiation events in metals and alloys demands techniques that can provide temporal and spatial resolution simultaneously. Transmission electron microscopy (TEM) enables one to obtain microstructural and chemical descriptors of materials at atomic/nanoscopic ...
Dealloying is involved in materials science responsible for fabrication of nanoscale structures beneficially but for corrosion degradations detrimentally. Detailed understanding related to the latter is critical for designing corrosion-resistance alloys and dedicated inhibition s ...
In this study, we report on a combined microscopic, analytical and electrochemical characterization of the nanoscopic passive layer on a tungsten‑molybdenum-containing super duplex stainless steel. We used scanning transmission electron microscopy/energy dispersive X-ray spectros ...
Two types of austenite morphologies, equiaxed and Widmanstätten, were produced through different phase transformation routes to evaluate the critical factors affecting the intergranular corrosion susceptibility in a 2205 duplex stainless steel. These distinct austenite morphologi ...
In this work, response surface method (RSM) is employed to design electrochemical experiments for assessment of a green organic molecule, namely Clopidogrel from cardiovascular drugs class, as a corrosion inhibitor for mild steel in sulfuric acid solution. Mathematical models bas ...