In-depth understanding of the synergetic effect between the various incorporating constituents in asphalt binders (e.g., polymers, fillers) is needed to design durable paving materials with desired properties. In this research, the focus was first on the effect of the reactivity of fillers on the evolution of adhesive strength between stone aggregates and epoxy modified asphalt mastics during the epoxy polymerization. Uniaxial tensile tests were performed on different combinations of fillers and binders with and without the epoxy-based polymer, and at different modification levels. Based on the results of the tensile tests, the increase of the adhesive strength of mastic with aggregates was generally lower when reactive filler particles (i.e., hydrated lime) were added than of epoxy binders with non-reactive filler. In other words, the non-reactive fillers did not influence the adhesion process and were thus selected for the next step studies on aging. The chemo-mechanical changes of epoxy modified asphalt mastics were analysed after pressure aging vessel and oven-conditioning after various aging times by means of Fourier transform infrared spectroscopy and dynamic shear rheometer. Less sulfoxides formed and higher modulus levels were measured with increasing the epoxy polymer in mastics over oven- and PAV-aging conditions. Due to the pressure difference, the rate of modulus increases and phase angle decrease was higher when the materials were conditioned in PAV than in oven.

Aging during construction and in-service substantially changes the chemical composition and physical properties of bitumen thereof influences the performance of asphalt pavements. The modification of bitumen by crumb rubber modifier (CRM) significantly increases the complexity of the aging mechanism and is expected to improve the aging resistance of bitumen. This study aims to investigate the effects of laboratory short-term and long-term aging on the chemistry and rheology of crumb rubber modified bitumen (CRMB). Neat bitumen and CRMB with four different CRM contents were studied. Fourier transform infrared spectroscopy and dynamic shear rheometer were employed to measure the change in the chemical composition and rheological properties of binders at different aging states. Bitumen hardening, which was rheologically revealed by the frequency sweep and multiple creep recovery test results, was also reflected in the growth of carbonyl and sulfoxide functional groups. In addition, the aliphaticity and aromaticity indices of binders before and after aging were also investigated. CRMB binders showed improved aging resistance compared to neat bitumen as reflected by the decreased carbonyl and sulfoxide indices as well as the lower change in rheological parameters. Higher resistance against aging was achieved when increasing the CRM content. The results also highlight the correlation between chemistry and rheology of bitumen. Among six selected mechanical parameters of binder, the non-recoverable creep compliance and percent recovery show better correlations with the combined chemical aging index (sum of carbonyl and sulfoxide indices) than the parameters derived from the linear viscoelastic region.

Recently warm mix asphalt (WMA) technologies have been introduced to rubberized asphalt mixtures to decrease the required construction temperatures and to alleviate the hazardous gas emissions. Rubberized asphalt pavements combining with WMA have the potential to improve the long-term pavement performance. This study aims to investigate the fatigue performance of crumb rubber modified bitumen (CRMB) containing warm-mix additives using different characterization methods. The effects of crumb rubber modifier (CRM) content (5%, 10%, 15% and 22% by weight of base bitumen) and warm-mix additives on the binder fatigue performance were investigated. Various laboratory tests, including frequency sweep tests, time sweep (TS) tests and linear amplitude sweep (LAS) tests, were conducted on the long-term aged binders to obtain indicators of fatigue performance. Results show that there is a good correlation between the measured fatigue life determined by TS tests using the dissipated energy concept and the predicted fatigue life determined by LAS tests using the simplified viscoelastic continuum damage (S-VECD) theory. However, the traditional Superpave fatigue parameter and the G-R parameter cannot characterize accurate enough the fatigue performance of modified binders. CRMB binders exhibit superior fatigue performance compared to the neat bitumen. The effects of warm-mix additives on the fatigue performance are different for neat bitumen compared to CRMB binder. Based on the findings in this study, rubberized asphalt mixture combining with WMA additives is expected to have a promising long-term fatigue performance.

Many research on mechanistic testing have come to likely conclusion that different test setup results in different performance. The aim of this paper is to analyse the stiffness modulus resulting from three different test setups, namely; Monotonic Uniaxial Tension Test (MUTT), Monotonic Uniaxial Compression Test (MUCT), and Indirect Tensile Test (ITT). They are monotonic tests. This paper will elaborate if there is any significant difference among the result of the first three tests. Master curves of stiffness modulus as a function of strain rate at reference temperature of 15 C were developed. The results show that there is no significance difference between the modulus resulting from the three tests performed at high strain rates. It's also shown that at low strain rate, the elastic modulus resulting from compression tests is in between indirect and uniaxial tension test's elastic modulus.

The chemical irreversible hardening of epoxy modified bitumen is affected by various physical factors and the successful application of this technology is directly linked with full understanding of chemo-rheological material characteristics. This study proposes a model to describe the material viscosity evolution during hardening of epoxy modified bitumen. The findings from numerical analyses performed to assess the mechanical response of epoxy modified bituminous binders are presented. Information of the chemical interaction of epoxy within a bituminous matrix was collected and all the influential factors have been determined. The proposed chemo-rheological model accounting for the polymerization of the epoxy in the bitumen was formulated and the sensitivity of material parameters, such as activation energy, reaction order and extent of hardening reaction until the gel point of epoxy modified binders, was demonstrated. Results of the analyses suggest that lower levels of activation energy increase the degree of hardening and the rate of viscosity development. By decreasing the hardening reaction until the gel point the achieved viscosity of epoxy modified bitumen was increased showing the importance of gel reaction extent on material viscosity evolution. The numerical studies have shown also that the polymerization rate in the epoxy modified bitumen is highly dependent on the temperature under various (non-) isothermal conditions. Also, the polymerization rate should be considered through all the material curing processes to avoid unwanted variations in the mechanical properties.

Remarkable variances were observed in permanent deformation curves of a dense asphalt mixture captured in triaxial repeated load permanent deformation (TRLPD) tests. In order to explore the causes of such variances, each permanent deformation curve was characterized firstly by an indicator (B) of the permanent deformation rate at a steady state stage. Meanwhile, a linear relationship was found between the values of indicator B and the resilient moduli of specimens after 1000 load repetitions. Secondly, a profound discussion on the potential relationship between resilient moduli and air voids content was performed. The discussion showed that air voids content appears to have no contributions to the observed variances. Nevertheless, three failure modes, tension failure, shear failure and shear failure with barreling, were observed in the X-ray Computed Tomography (CT) images of failed specimens subjected to triaxial compressive stresses. Furthermore, a significant correlation between failure modes and the resilient moduli was found by means of one-way analysis of variance (ANOVA). Moreover, it was found that the internal weak zones observed in the CT images of intact specimens dominate the behavior of the permanent deformation of asphalt mixture and the internal structure is the essential cause of such variances in the case of this study. This exploration highlights the influence of the internal structure on the mechanical performance of asphalt materials and thus recommends that considerable attention should be paid on the internal structure other than the volumetric properties when selecting test specimens.

Noise produced from the tyre-road surface interface is one of the most important contributions to the overall traffic noise and there is an increasing requirement for predicting the tyre-road noise levels prior to road construction in the Netherlands. In practice, a model with a simple structure as well as a high accuracy is applicable in road engineering. Also, material properties are preferred to be used as input variables of the prediction model, which will facilitate the pavement design. Based on these considerations, models are developed for evaluating the tyre-road noise from the asphalt mixture compositions and road surface characteristics. They are statistical models developed from the measurements on thin layer surfacings in the Netherlands. Different regression methods, model types and input variable combinations are taken into account. The selection of the model is due to the fitness of the prediction and validation by using measurement data from in service road sections. Two models, which evaluate the tyre-road noise level from the surface characteristics and from material properties, respectively, are finally selected. By using these models, only a small number of input variables are required and reliable predictions can be provided. The models achieved in this study can be used for predicting the tyre-road noise generation in road engineering and investigating the influence of surface characteristics and material properties on tyre- road noise levels.