Safeguarding water resources for society and ecosystems requires a comprehensive understanding of hydrological fluxes within the Critical Zone, Earth's living skin where the atmosphere, hydrosphere, biosphere, and lithosphere meet. For decades, tracer-aided mixing models have been used to track water flow paths through the Critical Zone, mapping the journey of water particles from atmospheric moisture to groundwater. Recent advances in novel tracer measurements and modeling methodologies offer new insights into hydrological partitioning within the Critical Zone, enabling improved quantification of water fluxes across scales ranging from microscopic to macroscopic. Advanced tracer-aided modeling approaches enable more rigorous testing of assumptions and improved quantification of uncertainties. In this review, we (a) summarize state-of-the-art tracer and modeling techniques, with an emphasis on stable water isotope tracers, (b) synthesize insights emerging from new approaches, and (c) highlight opportunities to apply these methods in interdisciplinary Critical Zone research.

Water transit time is now a standard measure in catchment hydrological and ecohydrological research. The last comprehensive review of transit time modeling approaches was published 15+ years ago. But since then the field has largely expanded with new data, theory and applications. Here, we review these new developments with focus on water-age-balance approaches and data-based approaches. We discuss and compare methods including StorAge-Selection functions, well/partially mixed compartments, water age tracking through spatially distributed models, direct transit time estimates from controlled experiments, young water fractions, and ensemble hydrograph separation. We unify some of the heterogeneity in the literature that has crept in with these many new approaches, in an attempt to clarify the key differences and similarities among them. Finally, we point to open questions in transit time research, including what we still need from theory, models, field work, and community practice.

Based on a literature overview, this paper summarizes the impact and legacy of the contributions of Wilfried Brutsaert and Jean-Yves Parlange (Cornell University) with respect to the current state-of-the-art understanding in hydraulic groundwater theory. Forming the basis of many applications in catchment hydrology, ranging from drought flow analysis to surface water-groundwater interactions, hydraulic groundwater theory simplifies the description of water flow in unconfined riparian and perched aquifers through assumptions attributed to Dupuit and Forchheimer. Boussinesq (1877) derived a general equation to study flow dynamics of unconfined aquifers in uniformly sloping hillslopes, resulting in a remarkably accurate and applicable family of results, though often challenging to solve due to its nonlinear form. Under certain conditions, the Boussinesq equation can be solved analytically allowing compact representation of soil and geomorphological controls on unconfined aquifer storage and release dynamics. The Boussinesq equation has been extended to account for flow divergence/convergence as well as for nonuniform bedrock slope (concave/convex). The extended Boussinesq equation has been favorably compared to numerical solutions of the three-dimensional Richards equation, confirming its validity under certain geometric conditions. Analytical solutions of the linearized original and extended Boussinesq equations led to the formulation of similarity indices for baseflow recession analysis, including scaling rules, to predict the moments of baseflow response. Validation of theoretical recession parameters on real-world streamflow data is complicated due to limited measurement accuracy, changing boundary conditions, and the strong coupling between the saturated aquifer with the overlying unsaturated zone. However, recent advances are shown to have mitigated several of these issues. The extended Boussinesq equation has been successfully applied to represent baseflow dynamics in catchment-scale hydrological models, and it is currently considered to represent lateral redistribution of groundwater in land surface schemes applied in global circulation models. From the review, it is clear that Wilfried Brutsaert and Jean-Yves Parlange stimulated a body of research that has led to several fundamental discoveries and practical applications with important contributions in hydrological modeling.