The use of fibers to address tensile cracking in alkali-activated concrete (AAC) is a topic of ongoing research. The addition of fibers enhances the tensile and flexural characteristics of all types of concrete including AAC. However, the mixing process, the setting time, and the workability are compromised due to the presence of fibers in the hardened matrix. There are different material categories of fibers such as steel, synthetic, carbon, and organic fibers that can impart different characteristics depending on the intended usage of concrete. The present chapter reviews the different types, orientations, dosages, and geometric properties of fibers included in AAC. along with the effects of fiber addition on the mix design, mixing and curing procedure of concrete, as well as the fresh and hardened characteristics of fiber-reinforced alkali-activated concrete (FRAAC). The use of statistical models to predict the mechanical characteristics of FRAAC is also discussed. Finally, the chapter presents the advantages, disadvantages, and safety precautions for this material followed by recommendations for practical usage.

Because building materials are intended to provide durable and safe structures, they are subject to strict regulations designed to ensure that they do not pose a hazard during their use. But they must also not be harmful to humans or the environment at the end of their life cycle, regardless of whether they are reused, recycled, or disposed of in a landfill. The requirements that building materials/products must meet vary around the world, but all countries have at least some minimum requirements, whether through regulations, mandatory standards, certification procedures, and/or monitoring at construction sites. In Europe, regulations and standards are based on what is known as the “materials-based” approach, meaning that standards define not only the technical requirements, but also the materials from which products are made. Other parts of the world use the so-called “performance-based approach”, meaning that products must have a certain performance regardless of the materials from which they are made. The “materials-based” approach could present some obstacles or barriers for alkali activated products when it comes to providing the documentation needed to bring such products to the market, as there are no EN standards for alkali-activated products so far. The aim of this chapter is to provide information on the legislation for building materials in general but with a focus on alkali activated materials (AAM) around the world and to provide guidance on how to approach the subject.

This chapter serves as a concise introduction to the State-of-the-Art Report on the Mechanical Properties of Alkali-Activated Materials (AAMs) in construction. It emphasizes the important role of mechanical properties in shaping AAM research and highlights key areas of exploration, including the impact of raw materials on mixture design, fresh properties, and a broad range of mechanical characteristics. Additionally, it outlines the structure of the book, guiding readers through its extensive coverage of theoretical foundations, practical insights, and emerging standards for AAMs. Overall, it sets the stage for understanding how AAMs can significantly advance sustainable construction practices.

The increasing demand for sustainable development in engineering practice has triggered researchers to explore solutions to reduce the CO₂ footprint caused by Portland cement (PC) production. Alkali-activated concrete (AAC), made by alkali activation of industrial by-products, poses to be a sustainable alternative to traditional Portland cement concrete. Despite vast studies on its material properties, there is still insufficient knowledge on the structural performance of reinforced AAC members, which impedes its widespread application. Bond between concrete and embedded reinforcement is critical for the structural behaviour of reinforced members, including crack propagation (crack opening and crack spacing), load carrying capacity, deformational capacity and seismic resistance. In this chapter, a critical review on the bond behaviour between AAC and reinforcement is given. A vast variety of tests have been used for studying the AAC-reinforcement bond. Similar to traditional PC concrete, different setup configurations and specimen geometries affect not only the measured bond strength, but also the nature of the bond response. Therefore, in this review different bond tests are discussed, focusing on application of both conventional steel and fibre reinforced polymer (FRP) as reinforcement. Given that AAC is a wide class of materials with largely varying mechanical properties, this study systematically classifies bond results based on different types of precursors used. Furthermore, numerical methods to predict AAC flexural response as well as the applicability of existing PC concrete design codes are summarized. It is concluded that AAC beams show comparable short-term bond behaviour with traditional PC concrete of the same strength class. Although the design codes for traditional concrete turn out to be usually applicable for the AAC-reinforcement bond, opposite trends were also reported. Finally, whereas the short-term behaviour has been widely investigated for AAC bond, systematic studies dealing with its long-term behaviour are lacking. Time dependent effects must be considered when developing reliable guidelines and recommendations for future structural design of AAC.

The introduction of alkali-activated concrete (AAC) technology to the construction industry represents a significant step toward a sustainable development and a cleaner environment by reducing environmental pollution. Currently, its application is relatively limited compared to traditional Portland cement based concrete (PCC). However, AAC has a remarkable potential for future growth and innovation despite several associated challenges and limitations. The current Chapter highlights recent progress in AAC mix design and its mechanical properties, paving the way for a broader application. The universally recognized international standards and codes for AAC, its mix design and evaluation of its long-term performance are still emerging. Unlike conventional PCC, AAC encompasses a wide class of materials with wide varying chemical composition and reaction mechanisms, depending on the choice of constituent materials (precursors and alkali activators). The mechanical properties, while diverse, reflect the flexibility of the material in response to different compositions and curing conditions. Though, non-uniformity makes consistent AAC usage challenging on the scale of PCC. Nevertheless, ongoing research and development efforts by RILEM TC 294-MPA are dedicated to tackling these challenges and enhancing the efficacy and widespread adoption of AAC technology.

Self-healing concrete, with its ability to autonomously repair damages, holds promise in enhancing its structural durability and resilience. Research on self-healing concrete in the past decade has advanced in understanding the mechanisms behind healing, exploring various healing agents, and assessing their effectiveness in concrete structures. However, the full potential of self-healing concrete remains untapped unless its effects are effectively integrated into the design practices of reinforced concrete structures. Realizing this challenge, this paper synthesizes the current research progress and discusses the possibilities to consider self-healing into design codes. The focus was placed on two specific benefits of applying self-healing concrete: one centered on durability and the other on mechanical performance. Specifically, the effect of self-healing on impeding chloride penetration into cracked reinforced concrete was discussed first. Modifications of parameters in existing predictive models based on different types of healing approaches were recommended. Furthermore, the possible impact of the self-healing capacity in mitigating the stiffness reduction of concrete was also discussed. Equations that can describe the stiffness regained due to healing action are presented. In each part of the case study, limitations and challenges still hindering standardization and wider application in the construction field are discussed.

Under the directives of the RILEM Technical Committee 294-MPA, this publication reports on the findings of an interlaboratory study that tested fiber-reinforced GGBFS-based alkali-activated concrete (FRAAC), with participants from Belgium, India and Slovenia. The research also elaborates prediction models for the tensile splitting strength of GGBFS-based FRAAC. This research endeavoured between 2020 and 2024 to find a globally reproducible FRAAC mix that could attain the required mechanical strength and workability criteria. The primary goal of the interlaboratory study was to generate FRAAC without the use of superplasticizers in order to maintain an S4 class consistency slump and achieve the desired 28-days cube compressive strength of 40 MPa. Steel and PVA fibers were determined to be incorporated to the GGBFS-based AAC mix at 0.3 and 0.1% volume fractions, respectively, through iterative interlaboratory investigations. Experimental program was conducted to examine the compressive and tensile splitting strength of these FRAAC combinations at different curing ages, ranging from 1 to 720 days. The findings indicate that while there were a few interlaboratory variations in the mechanical properties, the FRAAC produced was uniform across all participants. The desired compressive strength of 40 MPa was attained by GGBFS-based FRAAC with both steel and PVA fibers at 28 days. Although FRAAC containing steel fibers exhibited the higher early compressive strength, FRAAC prepared with steel and FRAAC prepared with PVA both demonstrated a 720-days compressive strength of about 61 MPa. The FRAAC mixes with steel fiber additions exhibited a tensile splitting strength that was approximately 30% higher than the mix with PVA fibers. Nonetheless, at all ages, the tensile splitting strength of both FRAAC mixes was clearly higher than 2 MPa. These results support reliable and consistent experimental findings, which allude towards FRAAC as a sustainable substitute for conventional Portland cement concrete.

This report presents a meticulous synthesis of collaborative interlaboratory research conducted within the purview of the RILEM Technical Committee 294-MPA, with two expert groups named RRT1 and RRT2, and encompassing ten participants from Belgium, China, Finland, India, Italy, Japan, the Netherlands, and the United Kingdom. The RRT1 expert group mainly focused on the ground granulated blast furnace slag-based alkali-activated concrete (GGBFS-based AAC) mix design and mechanical properties. In turn, the RRT2 expert group focused on the fresh properties of GGBFS-based AAC. The investigation, conducted between 2020 and 2024, aimed to establish globally reproducible mix design and mixing protocols for GGBFS-based AAC. Developed by the RRT1 and RRT2 expert groups, these protocols have emerged through iterative experiments followed by a comprehensive interlaboratory study. The outcomes highlight the reliable production of GGBFS-based AAC across participants, with minor deviations in fresh and mechanical properties that are largely consistent with those observed in Portland cement concrete (PCC). The primary objective of the developed GGBFS-based AAC mix design was to achieve a defined consistence class S4, while targeting a compressive strength threshold of approximately 50 MPa at 28 days. This objective was effectively realized, with the average compressive strength values reaching 56 MPa at 28 days and 64 MPa at 720 days. While the average splitting tensile strength stabilized at 3.2 MPa over the 720 day period. These findings underscore the growing importance of AAC within the construction sector, particularly due to its reproducible and reliable experimental results, as the industry increasingly shifts toward more sustainable alternatives to traditional cement-based materials.

The production of cement and concrete contributes significantly to global greenhouse gas emissions. Alkali‐activated concretes (AACs) are a family of existing alternative construction materials that could reduce the current environmental impact of Portland cement (PC) production and utilisation. Successful applications of AACs can be found in Europe and the former USSR since the 1950s and more recently in Australia, China and North America, proving their potential as construction materials. However, their utilisation is limited presently by the lack of normative and construction guidelines. Raw materials’ non‐uniform global availability and variable intrinsic properties, coupled with the lack of specific testing methods, raise questions regarding reproducibility and reliability. The mechanical and chemical behaviour of AACs has been investigated extensively over the past decades, strengthening its potential as a sustainable substitute for traditional PC‐based concrete. Although a wide amount of studies demonstrated that AACs could meet and even exceed the performance requirements provided by European design standards, a classification of these broad spectra of materials, as well as new analytical models linking the chemistry of the system components to the mechanical behaviour of the material, still need further development. This report gives an overview of the potential of alkali‐activated systems technology, focusing on the limitations and challenges still hindering their standardisation and wider application in the construction field.

The fib Model Codes aim at integrating in a single document the relevant knowledge for the structural design with concrete. Fibre reinforced concrete is already integrated in fib Model Code 2010 (fib MC2010) as a general category of materials. The group of flowable concrete consists of clusters of different types of concrete among others Self-Compacting Concrete, Ultra High Performance Concrete and Strain-Hardening Cementitious Composites. Being highly flowable is the distinguishing characteristic, flowable concrete might contain or not contain fibres. Although the fibre contribution on the structural level can be assessed on short-term, the structural behaviour also depends on the behaviour of the fibres and the matrix in which they are embedded. fib Task Group 4.3 worked on identifying and characterising different types of flowable concrete and discusses in a fib bulletin the most relevant aspects with regard to mix design, manufacturing, material performance and structural behaviour of flowable concrete which can allow innovative applications to be developed and realised. This paper discusses recent developments with regard to flowable concrete in a broader perspective and addresses the progress with regard to standardisation.

This paper investigates the development of the alkalinity and its impact on carbon steel reinforcement embedded in alkali-activated fly ashes (AAFA) and alkali-activated fly ashes with ten percentage mass (wt%) of blast furnace slag (AAFAS)-based materials (geopolymer–GP). The pH analysis of eluates indicates a remarkable decrease of alkalinity in AAFA and AAFAS in the first hours of the geopolymerization process. Phenolphthalein solution and pore solution tests on concretes also show a sharp decrease of alkalinity with increased Ca content in the binder due to carbonation. Micro X-ray computer tomography (µXCT) and electrochemical techniques indicate that the changed pH in the GP systems was accompanied by a decrease in the corrosion rates of steel reinforcement when compared to ordinary Portland cement (OPC) systems. In contrast to calcite and vaterite, which were detected in OPC and AAFAS after a carbonation process, only sodium carbonate natron was determined at lower levels in AAFA by X-ray diffraction (XRD).