During a solar eclipse, sunlight incident on the Earth is reduced due to the (partial) shadow of the Moon. Atmospheric trace gas concentrations which are influenced by the amount of available sunlight, such as nitrogen dioxide (NO2), may be affected due to the disrupted photolysis processes. Large-scale observations of the increased NO2 concentrations caused by the solar eclipse would improve our understanding of the sensitivity of NO2 in the atmosphere to short-term variations in sunlight. Spaceborne measurements can provide valuable information about the large-scale spatial distribution of NO2, which is provided daily by the TROPOMI instrument aboard the Sentinel-5 Precursor satellite by measuring and retrieving locally reflected sunlight. However, the TROPOMI NO2 retrieval is unable to derive reliable concentrations during a solar eclipse, as solar eclipses are not taken into account in its retrieval algorithm. In this research, we have adjusted the NO2 retrieval of TROPOMI such that it can handle solar eclipses and study the large-scale response of NO2 during two solar eclipses over Europe in 2021 and 2022. We found a large-scale increase of NO2 in the adjusted measurements, which linearly correlated with the degree of obscuration. We compared the measured NO2 increase with the values from the atmospheric chemistry model TM5 including an applied eclipse implementation and we found a close agreement in most areas that are not highly polluted. Our measurements and model predict a NO2 increase of 60%±12% and 70%±7% for an obscuration fraction of 1, respectively. More advanced chemistry modelling work is needed to explain the measurements in highly populated areas. We conclude that our results demonstrate that the TROPOMI algorithm is capable of correctly measuring NO2 after an adjustment of the NO2 retrieval. We have shown that it is possible to adjust an atmospheric trace gas retrieval for the influence of a solar eclipse. Moreover, we are the first to provide evidence for an increase in NO2 during a solar eclipse using space-based measurement techniques and to quantify this increase on a large scale with the same instrument. Our measurements can be used to test atmospheric chemistry models, possibly improving their sensitivity to solar eclipses but also artificial shadows on the Earth induced by sunlight-intercepting geoengineering approaches.

This project is a consulting project for Community Cloud Forest Conservation (CCFC) on how to obtain and communicate to relevant stakeholders an understanding of the impact of land use change and climate change on the hydrological balance of the cloud forest ecosystem in the Sierra Yalijux. The outcomes of the project will be used by CCFC and partners in four areas: Rural water committee capacity building with municipal and village leadership groups, environmental education with the ministry of education, reforestation, and conservation carbon/water credit prioritization with the national forestry institute, and to create thesis topics for bachelors level students with Universidad Rafael Landívar and Universidad de San Carlos. In order to achieve this goal, we divided our efforts in four areas: First, a description of the situation and a review of literature to identify gaps in scientific and practical understanding of local cloud forest hydrology (Chapter 2). Second, an analysis of the situation at a regional scale using publicly available historical data such as remote sensing data and data from the national meteorological authority (Chapter 3). Third, identifying important hydrological processes in the Cloud Forest micro-climate (Chapter 4) and prototyping and testing measurement setups (Chapter 5). Fourth, making suggestions on how to apply the results to the intended impact areas that CCFC has (Chapter 6). Our recommendations to CCFC for capacity building with water committees are based on a literature re view, we found that the presence of Cloud Forest is expected to increase base flow in springs due to its ability to capture additional hydrological inputs in the dry season, increase moisture recycling after heavy rain events, and store water in the soil. We recommend working with water committees to outline the recharge zones of their springs, run some simple calculations on water availability based on precipitation, and develop manage ment plans for the area. Our recommendations for further research are based on the research approaches we describe at the regional scale and the prototyping of field methodologies that we tested. A more permanent setup for data collection is being developed jointly with the Universidad de San Carlos at CCFC’s nature preserve.