Context. The detection and characterization of exorings (rings around exoplanets) will help us to better understand the origin and evolution of planetary rings in the Solar System and beyond. However, exorings are still elusive, and new and clever methods for identifying them need to be developed and tested. Aims. We explore the potential of polarimetry as a tool for discovering and characterizing exorings. Methods. For this purpose, we improved the general publicly available photometric code Pryngles by adding the results of radiative transfer calculations with an adding-doubling algorithm that fully includes polarization. With this improved code, we computed the total and polarized fluxes and the degree of polarization of model gas giant planets with or without rings. Additionally, we demonstrate the versatility of our code by predicting the polarimetric signal of the puffed-up planet HIP 41378 f as if it had an exoring. Results. Spatially unresolved dusty rings can significantly modify the flux and polarization signals of the light that is reflected by a gas giant exoplanet along its orbit. Rings are expected to have a low polarization signal, but they will decrease the degree of polarization of reflected light when they cast a shadow on the planet and/or block part of the planet. The most diagnostic feature of a ring occurs around the ring-plane crossings when sharp changes in the flux and degree of polarization curves are predicted by our model. When we applied our methods to HIP 41378 f, we found that if it is surrounded by a ring, noticeable changes in the degree of polarization of reflected light will arise. Although the reflected light on the planet cannot yet be directly imaged, the addition of polarimetry to future observations would aid in the characterization of the system.

Context. Terrestrial-type exoplanets in or near stellar habitable zones appear to be ubiquitous. It is, however, unknown which of these planets have temperate, Earth-like climates or for example, extreme Venus-like climates. Aims. Technical tools to distinguish different kinds of terrestrial-type planets are crucial for determining whether a planet could be habitable or incompatible with life as we know it. We aim to investigate the potential of spectropolarimetry for distinguishing exo-Earths from exo-Venuses. Methods. We present numerically computed fluxes and degrees of linear polarization of starlight that is reflected by exoplanets with atmospheres in evolutionary states ranging from similar to the current Earth to similar to the current Venus, with cloud compositions ranging from pure water to 75% sulfuric acid solution, for wavelengths between 0.3 and 2.5 μm. We also present flux and polarization signals of such planets in stable but spatially unresolved orbits around the star Alpha Centauri A. Results. The degree of polarization of the reflected starlight shows larger variations with the planetary phase angle and wavelength than the total flux. Across the visible, the largest degree of polarization is reached for an Earth-like atmosphere with water clouds due to Rayleigh scattering above the clouds and the rainbow feature at phase angles near 40. At near-infrared wavelengths, the planet with a Venus-like CO2 atmosphere and thin water cloud shows the most prominent polarization features due to Rayleigh-like scattering by the small cloud droplets. A planet in a stable orbit around Alpha Centauri A would leave temporal variations on the order of 10-13 W m s-1 in the total reflected flux and 10-11 in the total degree of polarization as the planet orbits the star and assuming a spatially unresolved star-planet system. Star-planet contrasts are on the order of 10-10 and vary proportionally with planetary flux. Conclusions. Current polarimeters appear to be incapable to distinguish between the possible evolutionary phases of spatially unresolved terrestrial exoplanets, as a sensitivity close to 10-10 would be required to discern the planetary signal given the background of unpolarized starlight. A telescope or instrument capable of achieving planet-star contrasts lower than 10-9 should be able to observe the large variation of the planets resolved degree of polarization as a function of its phase angle and thus be able to discern an exo-Earth from an exo-Venus based on their clouds unique polarization signatures.

In the JWST, Extremely Large Telescopes, and LUVOIR era, we expect to characterize a number of potentially habitable Earth-like exoplanets. However, the characterization of these worlds depends crucially on the accuracy of theoretical models. Validating these models against observations of planets with known properties will be key for the future characterization of terrestrial exoplanets. Due to its sensitivity to the micro- and macro-physical properties of an atmosphere, polarimetry will be an important tool that, in tandem with traditional flux-only observations, will enhance the capabilities of characterizing Earth-like planets. In this paper we benchmark two different polarization-enabled radiative-transfer codes against each other and against unique linear spectropolarimetric observations of the earthshine that cover wavelengths from ∼0.4 to ∼2.3 μm. We find that while the results from the two codes generally agree with each other, there is a phase dependency between the compared models. Additionally, with our current assumptions, the models from both codes underestimate the level of polarization of the earthshine. We also report an interesting discrepancy between our models and the observed 1.27 μm O₂ feature in the earthshine, and provide an analysis of potential methods for matching this feature. Our results suggest that only having access to the 1.27 μm O₂ feature coupled with a lack of observations of the O₂ A and B bands could result in a mischaracterization of an Earth-like atmosphere. Providing these assessments is vital to aid the community in the search for life beyond the solar system.

NASA is engaged in planning for a Habitable Worlds Observatory (HabWorlds), a coronagraphic space mission to detect rocky planets in habitable zones and establish their habitability. Surface liquid water is central to the definition of planetary habitability. Photometric and polarimetric phase curves of starlight reflected by an exoplanet can reveal ocean glint, rainbows, and other phenomena caused by scattering by clouds or atmospheric gas. Direct imaging missions are optimized for planets near quadrature, but HabWorlds’ coronagraph may obscure the phase angles where such optical features are strongest. The range of accessible phase angles for a given exoplanet will depend on the planet’s orbital inclination and/or the coronagraph’s inner working angle (IWA). We use a recently created catalog relevant to HabWorlds of 164 stars to estimate the number of exo-Earths that could be searched for ocean glint, rainbows, and polarization effects due to Rayleigh scattering. We find that the polarimetric Rayleigh scattering peak is accessible in most of the exo-Earth planetary systems. The rainbow due to water clouds at phase angles of ∼20^◦ − 60^◦ would be accessible with HabWorlds for a planet with an Earth equivalent instellation in ∼46 systems, while the ocean glint signature at phase angles of ∼130^◦ − 170^◦ would be accessible in ∼16 systems, assuming an IWA = 62 mas (3λ/D). Improving the IWA = 41 mas (2λ/D) increases accessibility to rainbows and glints by factors of approximately 2 and 3, respectively. By observing these scattering features, HabWorlds could detect a surface ocean and water cycle, key indicators of habitability.

Does life exist outside our Solar System A first step towards searching for life outside our Solar System is detecting life on Earth by using remote sensing applications. One powerful and unambiguous biosignature is the circular polarization resulting from the homochirality of biotic molecules and systems. We aim to investigate the possibility of identifying and characterizing life on Earth by using airborne spectropolarimetric observations from a hot air balloon during our field campaign in Switzerland, May 2022. In this proceeding we present the optical-setup and the data obtained from aerial circular spectropolarimetric measurements of farmland, forests, lakes and urban sites. We make use of the well-calibrated FlyPol instrument that measures the fractionally induced circular polarization (V/I) of (reflected) light with a sensitivity of < 10-4. The instrument operates in the visible spectrum, ranging from 400 to 900 nm. We demonstrate the possibility to distinguish biotic from abiotic features using circular polarization spectra and additional broadband linear polarization information. We review the performance of our optical-setup and discuss potential improvements. This sets the requirements on how to perform future airborne spectropolarimetric measurements of the Earth's surface features from several elevations.

NASA's EPOXI mission used the Deep Impact spacecraft to observe the disk-integrated Earth as an analog to terrestial exoplanets' appearance. The mission took five 24 hr observations in 2008-2009 at various phase angles (57. 7-86. 4) and ranges (0.11-0.34 au), of which three equatorial (E1, E4, E5) and two polar (P1, North and P2, South). The visible data taken by the HRIV instrument ranges from 0.3 to 1.0 μm, taken trough seven spectral filters that have spectral widths of about 100 nm, and which are centered about 100 nm apart, from 350 to 950 nm. The disk-integrated, 24 hr averaged signal is used in a phase angle analysis. A Lambertian-reflecting, spherical planet model is used to estimate geometric albedo for every observation and wavelength. The geometric albedos range from 0.143 (E1, 950 nm) to 0.353 (P2, 350 nm) and show wavelength dependence. The equatorial observations have similar values, while the polar observations have higher values due to the ice in view. Therefore, equatorial observations can be predicted for other phase angles, but (Earth-like) polar views (with ice) would be underestimated.

Planet-wide stationary gravity waves have been observed with the thermal camera on the Akatsuki spacecraft. These waves have been attributed to the underlying surface topography and have successfully been reproduced using the Institut Pierre Simon Laplace (IPSL) Venus Mesoscale Model (VMM). Here, we use numerical radiative transfer computations of the total and polarized fluxes of the sunlight that is reflected by Venus under the conditions of these gravity waves to show that the waves could also be observed in polarimetric observations. To model the waves, we use the density perturbations computed by the IPSL VMM. We show the computed wave signatures in the polarization for nadir-viewing geometries observed by a spacecraft in orbit around Venus and as they could be observed using an Earth-based telescope. We find that the strength of the signatures of the atmospheric density waves in the degree of polarization of the reflected sunlight depends not only on the density variations themselves, but also on the wavelength and the cloud top altitude. Observations of such wave signatures on the dayside of the planet would give insight into the occurrence of the waves and possibly into the conditions that govern their onset and development. The computed change in degree of polarization due to these atmospheric density waves is about 1000 ppm at a wavelength of 300 nm. This signal is large enough for an accurate polarimeter to detect.

One of the most exciting scientific challenges is to detect Earth-like planets in the habitable zones of other stars in the galaxy and search for evidence of life. During the past 20 years the detection of exoplanets, orbiting stars beyond our own, has moved from science fiction to science fact. From the first handful of gas giants, found through radial velocity studies, detection techniques have increased in sensitivity, finding smaller planets and diverse multi-planet systems. Through enhanced ground-based spectroscopic observations, transit detection techniques and the enormous productivity of the Kepler space mission, the number of confirmed planets has increased to more than 2000. Several space missions, including TESS (NASA), now operational, and PLATO (ESA), will extend the parameter space for exoplanet discovery towards the regime of rocky Earth-like planets and take the census of such bodies in the neighbourhood of the Solar System. The ability to observe and characterise dozens of potentially rocky Earth-like planets now lies within the realm of possibility due to rapid advances in key space and imaging technologies and active studies of potential missions have been underway for a number of years. The latest of these is the Large UV Optical IR space telescope (LUVOIR), one of four flagship mission studies commissioned by NASA in support of the 2020 US Decadal Survey. LUVOIR, if selected, will be of interest to a wide scientific community and will be the only telescope capable of searching for and characterizing a sufficient number of exo-Earths to provide a meaningful answer to the question “Are we alone?”. This contribution is a White Paper that has been submitted in response to the ESA Voyage 2050 Call.

We present the performance characterization of the Life Signature Detection polarimeter (LSDpol), a prototype instrument designed to identify life on Earth and derive the integrated signal of Earth-as-an-exoplanet through global polarization measurements from the Airbus Bartolomeo platform on the International Space Station (ISS). LSDpol is optimized for the measurement of an unambiguous biomarker exhibited by chlorophyll and other bio-pigments: homochirality. The instrument is very sensitive to small signals in circular polarization induced by this preference in handedness found in biological molecules. LSDpol has the capability of measuring full Stokes parameters as a function of wavelength while containing no moving parts and a compact design suitable for SmallSats. The point-and-shoot configuration of this instrument uses a patterned liquid crystal spatial polarization modulator at the slit followed by a quarter wave retarder and a liquid crystal polarization grating. This combination decouples the faint circular and strong linear polarization signals through spatial modulation making it insensitive to cross-talk. In this paper we present detailed simulations and results from the performance characterization of LSDpol. We discuss the current design and the impact of instrumental artefacts such as distortions, flat field, and retardation errors in the quarter-waveplate based on simulations of the spatial modulation. Our study looks at the instruments’ capabilities in the laboratory and outdoors. Abiotic data from artificial vegetation and concrete are used as a control against the chlorophyll measurements of interest. Preliminary results from beetles, leaves and grass demonstrate the current capabilities of LSDpol. This versatile instrument concept will be ideally suited for remote sensing of homochirality, enabling vegetation health monitoring on Earth and detection of possible biotic signatures on icy moons.

The polarization state of starlight reflected by a planetary atmosphere uniquely reveals coverage, particle size, and composition of aerosols as well as changing cloud patterns. It is not possible to obtain a comparable level of detail from flux-only observations. It is therefore a powerful tool to better understand the crucial role played by clouds and aerosols in the chemistry, dynamics, and radiative balance of a planet. Furthermore, polarization observations can probe the atmosphere of planets independently of the orbital geometry (hence it applies to both transiting and non-transiting exoplanets). A high-resolution spectropolarimeter with a broad wavelength coverage, particularly if attached to a large space telescope, would enable simultaneous study of the polarimetric planetary properties of the continuum and to look for and characterize the polarimetric signal due to scattering from single molecules, providing detailed information about the composition and vertical structure of the atmosphere.

Context. Homochirality is a generic and unique property of life on Earth and is considered a universal and agnostic biosignature. Homochirality induces fractional circular polarization in the incident light that it reflects. Because this circularly polarized light can be sensed remotely, it can be one of the most compelling candidate biosignatures in life detection missions. While there are also other sources of circular polarization, these result in spectrally flat signals with lower magnitude. Additionally, circular polarization can be a valuable tool in Earth remote sensing because the circular polarization signal directly relates to vegetation physiology. Aims. While high-quality circular polarization measurements can be obtained in the laboratory and under semi-static conditions in the field, there has been a significant gap to more realistic remote sensing conditions. Methods. In this study, we present sensitive circular spectropolarimetric measurements of various landscape elements taken from a fast-moving helicopter. Results. We demonstrate that during flight, within mere seconds of measurements, we can differentiate (S∕ N > 5) between grass fields, forests, and abiotic urban areas. Importantly, we show that with only nonzero circular polarization as a discriminant, photosynthetic organisms can even be measured in lakes. Conclusions. Circular spectropolarimetry can be a powerful technique to detect life beyond Earth, and we emphasize the potential of utilizing circular spectropolarimetry as a remote sensing tool to characterize and monitor in detail the vegetation physiology and terrain features of Earth itself.

We present LOUPE, the Lunar Observatory for Unresolved Polarimetry of the Earth, a compact snapshot spectropolarimeter designed to observe the Earth from the Moon as if it were an exoplanet. Viewing the Earth as it would be seen by a faraway observer will offer novel insight into the spectropolarimetric signatures of planets harboring life, as well as a chance to refine algorithms for the retrieval of exoplanetary properties such as the presence of liquid water, clouds, vegetation, and more. LOUPE boasts a novel solid-state design based on patterned liquid crystal optics built atop the cosine HyperScout®, a flight-proven hyperspectral imager. Uniquely to LOUPE, a microlens array creates a two- dimensional grid of unresolved Earth-images on the detector, resulting in an array of "pale (blue) dots"filtered spectrally along one direction, with polarization modulation applied in the perpendicular direction. The clever use of custom-patterned liquid crystals as a passive modulator thus replaces the need for classical dispersion elements and polarization modulation optics. This pioneering approach enables LOUPE to simultaneously obtain spectral and Stokes measurements for the entire Earth, whilst the position of the Earth-dots also has the benefit of providing input for angle-dependent spectral and polarization calibration. Here we discuss our detailed design process and the challenges involved in creating a unique, space-qualified spectropolarimeter with no moving parts and no bulky optics, whilst maintaining flexibility for different usage scenarios: rovers, landers, orbiters, and more. We present a performance trade-off and optical design informed by ray tracing with polarization effects, to prepare for the demodulation of simulated Earth observation data.