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F. De Domenico

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Flame front identification typically relies on chemiluminescence or planar laser-induced fluorescence (PLIF) diagnostics. Yet, existing approaches are often limited by line-of-sight integration, low signal-to-noise ratio, or limited applicability to hydrogen flames. This study introduces a novel OH PLIF-based method that isolates the flame front by subtracting fluorescence signals obtained from two excitation lines with distinct temperature dependencies. The method is validated using LIFSIM coupled with 1D freely propagating flame simulations and is experimentally demonstrated in a laminar premixed H2[jls-end-space/]-air Bunsen flame. The resulting flame front marker exhibits a well-defined peak located, on average, 0.56 flame thicknesses from the heat release rate (HRR) peak and an average width of 1.57 times the HRR width. These values are comparable to those obtained from OH∗ chemiluminescence and the OH PLIF gradient, while offering substantially higher SNR and providing spatial resolution. Beyond introducing a new flame-front marker, suitable for hydrogen flames, this work provides a numerical and experimental assessment of OH-based HRR markers, evaluating their performance for hydrogen flame diagnostics. ...
Hydrogen combustion is gaining attention for its potential to enable low-emission energy conversion in gas turbines. Since hydrogen is carbon-free, it produces no carbon-based pollutants and primarily forms water vapor. However, due to its higher adiabatic flame temperature with respect to hydrocarbons, hydrogen combustion is more prone to increased nitrogen oxides (NOx[jls-end-space/]) formation. Accurately predicting NOx formation remains a major challenge, particularly when scaling from laboratory experiments to industrial applications. While scaling laws are widely used in fluid dynamics, their application to NOx emissions is challenging due to the complex nature of NOx formation. This study develops a semi-empirical, physics-based correlation to estimate NOx emissions in swirl-stabilized, partially premixed lean hydrogen–air burners. The proposed correlation expresses the Emission Index of NOx (EINOx[jls-end-space/]) as a function of key operating and design parameters, including fuel mass flow rate, pressure, adiabatic flame temperature, equivalence ratio, residence time and swirl number. It builds upon Westenberg’s NOx formation rate equation, incorporating composition-dependent effects via equivalence ratio. The slow formation nature of NOx is accounted for via the combustor mean residence time. Additionally, the influence of swirl on the mixing process is modeled through a swirl-modified effective equivalence ratio, acknowledging that while partial premixing is a design choice, swirl intensity can either enhance or disrupt the degree of premixing before combustion. The model’s parameters were calibrated using experimental data from published literature. By providing a predictive tool for NOx scaling across different operating conditions, this model supports the development and design of experiments and devices for hydrogen–air combustion. ...
Introducing H 2 as fuel in gas turbines is a promising step towards decarbonizing the energy sector. However, the future availability of H 2 in large quantities remains uncertain. Consequently, designing fuel flexible (CH 4/H 2) combustion chambers for various fuel blends is necessary. The distinct combustion characteristics of H 2, such as high flame speeds and high adiabatic flame temperatures, pose challenges when designing systems that can operate in a stable manner and with low emissions across a wide range of fuel mixtures. This paper investigates the fuel-flexibility of an atmospheric laboratory scale, partially premixed swirl stabilized combustor. By deploying a non-rotating axial air jet (AAI) in the center-line of the swirling flow, the flashback risk for high H 2 content fuels is minimized. This study provides detailed insights into AAI's interaction with CH 4/H 2 fuel blends, analyzing the resulting flow field from Particle Image Velocimetry, emissions from exhaust gas analyser measurements, and flame structures from OH* chemiluminescence and OH Planar Laser Induced Fluorescence. The results show that AAI enables flame stabilization across the full range from 100% CH 4 to 100% H 2 in the same injector geometry. However, a high portion of the total airflow must be injected axially to stabilize H 2 flames. Increasing the level of AAI increases NO emissions and alters flame stabilization mechanisms. This is likely due to a decrease in mixing quality, resulting in the fuel staying close to the periphery of the mixing tube. Switching the fuel from 100% CH 4 to 100% H 2 leads to an increase in NO emission, despite lower adiabatic flame temperatures for the perfectly premixed case. This indicates that the mixing process and flame location within the combustion chamber are essential in controlling NO emissions. Moreover, the flow field transforms significantly from a swirl-stabilized flow field featuring an inner recirculation zone to one resembling the one of a jet flame. ...
Journal article (2025) - Jonathan Neeser, Francesca De Domenico
Resonance igniters are a promising alternative to conventional ignition devices for rocket engines using non-hypergolic propellants. This paper presents the development and analysis of a resonance igniter using gaseous oxygen and methane, supported by experimental measurements and numerical modelling. The effect of nozzle gap distance on acoustic resonance heating is investigated using oxygen and nitrogen as driving gases. Microphone data are used to determine the operating mode of the igniter; thermocouple data acquired on the outside of the resonator tip are used to evaluate heating performance across various nozzle pressure ratios and nozzle gap distances. A numerical model based on the open-source CFD software SU2 is developed and validated against resonance heating experimental data. This non-reacting flow model accurately captures the transition from the high-frequency Jet Screech Mode to the lower-frequency Jet Regurgitant Mode. Furthermore, it identifies the operational parameters leading to the highest rates of resonance heating observed in the experiments. Ignition attempts in non-premixed conditions, using gaseous oxygen and methane, show that the separate injection of methane in cross-flow into the combustion chamber causes severe disruption of resonance heating, preventing ignition. ...
The mixing of fuel and air is a key factor in determining NOx emissions during combustion. Lean-premixed burning strategies allow to control the flame temperature and therefore NOx emissions. However, for highly reactive fuels like hydrogen, the high flame speed makes full premixing dangerous due to the increased risk of flashback. In these cases, current combustor geometries are often operated in partially premixed modes with the fuel injected as close as possible to the combustion chamber. This highlights the need for effective mixing strategies to achieve a high degree of mixing over a short distance. This is even more critical in fuel-flexible combustion systems (e.g., combustors capable of burning both CH4 and H2), as the mixing process is heavily influenced by the varying properties of the fuel mixture. In such cases, a comprehensive understanding of the mixing process is required to minimize NOx emissions under all fuel blends conditions. This paper investigates the mixing of fuel jets into a swirling air cross-flow of a partially-premixed, swirl stabilized combustor using a combined experimental and numerical approach. The injector features an axial swirler and a mixing tube where the air and the fuel jets mix before entering the combustion chamber. The experiments are performed in cold flow conditions. A variable mixture of helium–air is used to represent different blends of CH4-H2 fuel, and the mixing process is visualized by seeding the fuel stream with DEHS droplets. Large-Eddy Simulations (LES) confirm the suitability of helium as a surrogate for H2 by demonstrating similar macro-mixing behavior for the two gases. This study examines the impact of varying fuel composition and momentum flux ratio (Jswirl) between the fuel jet and the swirling cross-flow on mixing performance. The results indicate that fuel with lower density achieve better mixing with the air at the mixing tube outlet. A numerical analysis of the radial transport terms reveals that higher H2 content in the fuel makes it less subject to outward convection which causes stratification close to the mixing tube outlet. Furthermore, the contribution of the molecular diffusion term increases with higher levels of H2, resulting in improved mixing. When increasing Jswirl (up to Jswirl = 10) increases the penetration of the fuel jet into the swirling flow. Above a critical value of Jswirl, the mixture homogeneity at the mixing tube outlet becomes insensitive to Jswirl for the investigated geometry. Overall, the fuel composition was found to have a greater influence on the level of mixing close to the mixing tube outlet than variations in Jswirl. ...
In this study, the macroscopic properties of kerosene-H2 blended flames are investigated in a multi-phase, multi-fuel combustor, focusing on the effects of increasing H2 blending fractions. The non-reacting flow field of the swirl-stabilized combustor is characterized using PIV, and macro-structures in the flow and spray-swirl interactions are analyzed. Kerosene atomizers are tested to estimate variations in spray quality across different fuel blends. The changes in the optical properties of the flames are recorded using broadband chemiluminescence imaging while the changes in the acoustic emissions are recorded using a microphone. Results show that H2 addition significantly alters the flame topology, transitioning from a lobed flame for pure kerosene to a single contiguous swirling flame for blended or pure H2 cases. The flame luminosity decreases, with the emission color shifting from bright yellow (pure kerosene case) to dull yellow (multi-fuel cases) to a red-blue hue (pure H2 case). These changes are attributed to variations in fuel distribution, heat release patterns, combustion mode, flame speed, and soot formation tendencies. The acoustic analysis reveals that a strong tonal behavior is observed under pure fuel conditions (prominent peaks at higher harmonics of 150 Hz) while broadband characteristics are exhibited under blended fuel conditions. The overall acoustic emissions in multi-fuel cases are reduced by ~80% compared to pure H2 and ~55% compared to pure kerosene. This study highlights the effects of high levels of H2 blending on flame dynamics and acoustic behavior in a multi-phase, multi-fuel combustor, offering valuable insights for the development of fuel-agnostic combustion systems. ...
Conference paper (2024) - Lorenzo Palanti, Lorenzo Mazzei, Cosimo Bianchini, Sarah Link, Kaushal Dave, F. De Domenico, A. Gangoli Rao
Due to climate change concerns, hydrogen is being considered for future aviation, but its commercial availability is limited, storage is bulky and its combustion with 100% concentration still poses numerous technical challenges. This leads to a certain interest in multi-fuel systems using both hydrogen and kerosene to facilitate the transition without completely redesigning the existing engines. Within the HOPE project, the present study focuses on an innovative multi-fuel combustion concept for aircraft propulsion, considering a laboratory-scale combustor hosted at TU Delft. Such a device, originally fueled with hydrogen and methane, is schematically composed of an axial swirler, four ducts for gaseous fuel injection, a mixing tube and a cylindrical combustion chamber. To avoid flashback, also an axial air injection duct is present that bypasses the swirler and directly reaches the air-fuel mixture in the mixing tube.
In this work, reactive CFD simulations are used to explore different spray injection configurations and assess the impact of kerosene on the flow field, the flame shape and the NO emissions of the modified system. In particular, three different injection positions are studied, featuring injection points on the backplane of the combustion chamber, inside the fuel/air mixing tube or on the axis of the burner. It is found that the most suitable position for kerosene injection is on the axis of the burner, so that the spray is surrounded by the swirling flow and undergoes a rapid mixing with the oxidising stream, limiting the maximum temperature reached by the mixture. Moreover, in this case, the addition of hydrogen leads to reduced NO emissions since it decreases the size of the hot spots generated by the combustion of kerosene. ...
Conference paper (2024) - Daniel Kierbel, Tanja Neuland, Paul Emile Roux, Pedro Nehter, Arvind Gangoli Rao, Francesca de Domenico, Maurice Hoogreef, Linder Van Biert, Feijia Yin, More authors...
HYLENA will investigate, develop and optimize an innovative, highly efficient integrated hydrogen powered, electrical aircraft propulsion concept for short and medium range. It will achieve significant climate impact reduction by being completely carbon neutral with radical increase of overall efficiency. The full synergistic use of: a) an electrical motor (as the main driver for propulsion), b) a contoured hydrogen fueled SOFC stacks (geometrically optimized for nacelle integration), c) a gas turbine (to thermodynamically integrate the SOFC), will act as an enabler for hydrogen aviation and will allow for efficient and compact engine concepts. This disruptive propulsion system will be called HYLENA concept. HYLENA aims to evaluate and demonstrate the feasibility of a “game changing” engine type which integrates Solid Oxide Fuel Cells (SOFC) into a turbomachine, in order to utilize the heat generated by the fuel cells on top of its electrical energy. The combination of e-motor, turbomachine and contoured SOFCs fueled with H2 will deliver high overall efficiency and performance versus state-of-the-art turbofan engines. Indeed, HYLENA Figures of Merit consist of minimizing CO2 emission; negligible NOX and an unmatched overall efficiency versus state-of-the-art turbofans which corresponds to an outstanding performance increase. It will also enable to extend the flight range for the same fuel tank size. The HYLENA project will deliver: 1. On SOFC cell level: Experimental investigations on SOFC cell technologies and identification of the most promising one(s) for aeronautical applications; 2. On SOFC stack level: Studies and tests to determine the most compact/light/manufacturable way of stack integration; 3. On thermodynamic level: Cycles simulations of the proposed novel HYLENA concept architecture and down selection of the most performing one; 4. On engine design level: Exploration, through resilient calculation and simulation, of the best engine design, sizing and overall components integration; 5. On overall engine efficiency level: Demonstration that HYLENA concept can reach very high efficiency levels with limited weight and complexity; 6. On demonstration level: A decision dossier for a potential ground test demonstrator to prove that the HYLENA concept works in practice during a second phase in the continuity of this project. ...
Conference paper (2023) - Lee Weller, Priyav Shah, Anthony Giles, Francesca De Domenico, Steve Morris, Benjamin A.O. Williams, Simone Hochgreb
Laser-Induced Grating Spectroscopy (LIGS) was applied in a high-pressure combustion facility. Instantaneous (sub-μs), spatially resolved (within 5 mm) measurements of temperature and molar fractions of water were obtained using thermal and electrostrictive LIGS signals. Temperatures up to 1800 K and water molar fractions between 0.01 and 0.12 were measured. A new analytic approach was developed to extract temperature from the frequencies of the measured signal within the flame brush region, where mixtures contain both burnt and unburnt gases. Mean product temperatures are shown to be 8% lower than the adiabatic temperatures for the nominal equivalence ratio, and 14% higher than measurements made with a thermocouple, uncorrected for radiation losses. This work represents the first application of LIGS to a high-pressure, turbulent swirling flame, opening up the potential for future uses in other real world applications. Challenges associated with the deployment of the technique are described, as are potential measures to overcome these difficulties. ...
Journal article (2023) - Jocelino Rodrigues, Lee Weller, Francesca De Domenico, Simone Hochgreb
A high-frequency (1.5 kHz) spontaneous Raman spectroscopy measurement technique is developed and applied to measure external fluctuations generated in the local concentration of an isothermal binary gas mixture of methane and air. Raman excitation is provided by a high-frequency laser at 527 nm in dual-pulsed mode. The Stokes Raman signal is collected using an EMCCD camera coupled to a high-frequency intensifier as a shutter. The emitted signal is collected over the 596–627 nm wavelength range, which allows for the simultaneous tracking of methane and nitrogen Stokes Q-branch mode signals. Calibration curves are initially obtained for each species (CH 4 and N 2) based on steady-state concentrations, and further corrected during use to detect local unsteady mixture fluctuations at gas pulsation frequencies up to 250 Hz. The main novelty is the demonstration of Raman spectroscopy for the simultaneous multispecies measurement of unsteady concentrations of gas-phase methane and air mixtures using a laser beam with a high-repetition rate, low energy per pulse, combined with a high-frequency intensifier and a single camera. ...
Lean-premixed swirl-stabilized combustion is a successful strategy to reduce pollutant emissions. However, these combustion systems are especially prone to thermoacoustic instabilities. The precessing vortex core (PVC) plays a significant role in suppressing or exciting those instabilities. Therefore, it is necessary to predict the PVC dynamics in different operating conditions. The introduction of alternative aviation fuels like hydrogen in fuel-flexible gas turbines might require changes in the combustor geometry. However, the influence of particular geometric parameters on the PVC dynamics in less conventional combustion chamber configurations is not yet clear. To contribute to the knowledge of PVC dynamics in different combustor geometries, this paper presents an experimental study of the PVC dynamics in isothermal conditions in a counter-rotating dual swirler configuration in different confinement ratios. Additionally, a non-rotating axial air jet can be injected on the center line of the primary swirler as a provision for increased flashback resistance in the reacting case with H 2. PVC frequencies and amplitudes are obtained by spectral proper orthogonal decomposition (SPOD) of time-resolved PIV measurements, and by time-resolved pressure measurements. The study shows that the frequency of the PVC scales with StPVC = 0.78, based on the diameter and the bulk velocity of the mixing tube. The PVC frequency is only determined by the conditions in the primary swirler and is fully independent of the amount of airflow going through the secondary counter-rotating swirler. Introducing an axial air jet on the center line decreases the PVC frequency significantly, which can be related to the change in effective swirl number. It is also shown that the smallest combustion chamber diameter results in the highest spectral energy for the PVC mode for all investigated points, hence the PVC motion is the strongest. Meanwhile, the biggest combustion chamber diameter shows the weakest pressure fluctuations. The results obtained in this study provide evidence that the periodic oscillations arising in the swirling flow field can be predicted and follow a Strouhal scaling independent of the geometry, even for more unconventional configurations. ...