As Polymer Electrolyte Membrane Fuel Cells (PEMFCs) emerge as a promising technology for transport decarbonization, the development of durability assessment protocols tailored to specific applications, such as maritime operations, is becoming relevant for the identification of stressors and lifetime enhancement. This study presents a preliminary experimental campaign aimed at introducing a methodology to assess the degradation of PEMFCs subjected to Accelerated Stress Test (AST). In particular, the methodology encompasses the utilization of electrochemical characterization and, in this work, the fuel cell operating profile has been chosen to mimic the operation of a small passenger vessel. The tests were carried out on two single Membrane Electrode Assemblies (MEAs) for 500 h. One membrane was subjected to the AST, and a second sample, tested under constant load operation, served as a reference. Periodic electrochemical characterization was conducted to assess performance degradation through polarization curves, electrochemical impedance spectroscopy, and cyclic voltammetry. The electrochemical analysis of degradation was conducted through a dual-method approach combining model-free and model-based methods for impedance analysis, as well as catalyst active area evaluation from voltammograms. Results show that the dynamic operation characteristic of the passenger ferry increases degradation compared to constant operation, evidenced by increased ohmic and interfacial resistances and losses in catalyst active area. This work provides a framework for developing application-specific durability protocols, enriched with multi-method diagnostic approaches to assess PEMFC degradation under realistic maritime conditions. Such methodologies support the development of durability enhancement strategies tailored to maritime applications, allowing a broader application of the technology in the sector.

This study investigates the integration of solid oxide fuel cells (SOFC) with proton exchange membrane fuel cells (PEMFC) to improve the system efficiency and minimise exergy losses from unused hydrogen. The paper offers new insights into the efficiency-power density trade-off of SOFC+PEMFC combined systems by simultaneously evaluating the systems’ efficiency trends and their overall volume and mass. The SOFC+PEMFC is thermodynamically analysed and compared for the first time against an SOFC stand-alone system with anode off-gas recirculation (AOGR), another approach to increase efficiency by maximising the direct conversion of fuel into power. Simulations are run to reveal the impact of varying stack operating parameters, fuel utilisation, cell voltage, and operating temperature on the system efficiency, shape of the system’s operational envelope, and overall volume and mass. An exergy analysis identifies major loss sources in the system and proposes pathways for improvement. The results demonstrate that integrating an SOFC with a PEMFC increases system efficiency to 55%, comparable to AOGR, while reducing the total system volume and mass by 20% and 23%, respectively. This study provides new insights into the potential use of SOFCs in volume and mass-limited applications such as long-distance transportation to reduce pollutant emissions.

This paper introduces a model predictive control (MPC) strategy for solid oxide fuel cell (SOFC) systems, introducing thermal stress-aware power modulation. The proposed MPC approach incorporates a temperature rate-of-change constraint to manage local temporal and spatial temperature gradients in the SOFC during transient power modulation. The study evaluates the sensitivity and effectiveness of the temperature rate-of-change constraint under four different constraint parameter sets, spanning a range from fast to slow power modulation. A one-dimensional spatially discretised SOFC model is employed in the simulations to assess the resulting local temperature gradients. The results of this paper indicate that the proposed MPC strategy enhances transient power tracking performance compared to the conventional approach of using an electrical current rate-of-change constraint with 1%–17%, without a significant increase in the local temporal and spatial temperature gradients in the SOFC.

Recent research in chemical plant operation shows increasing interest in dynamic process operation as part of designed operating strategy for reasons such as increased dependency on renewable energy, and process intensification. Conventional analyses of fixed bed reactors are developed for steady state optimization and may not be adequate for dynamic operation. In fact, the important metrics and targets in dynamic process design are not entirely clear. The first objective of this article is to provide a state-of-the-art survey categorize types of dynamic operation, and rank the available common modelling and analytical tools suitable for quantification of dynamic process variables. The article then examines a case study of 1D and 2D model differences in a methanol steam reforming reactor. The case study shows model prediction differences of up to 15% for conversion, and up to 50% for CO concentration at the outlet during extreme load changes. The study concludes that the complexity of analytical and numerical techniques for dynamic processes is notably higher compared to steady state analyses, but appropriate tools and procedures are currently lacking.

Low-Temperature Polymer Electrolyte Membrane Fuel Cells (LT-PEMFCs) have recently emerged as a promising solution for sustainable ship energy systems. However, enhancing durability is essential to enable their broader adoption in the maritime sector. Durability enhancement depends on a thorough understanding of degradation mechanisms and accurate prognostics, both of which are highly application-specific. The current literature lacks a comprehensive understanding of LT-PEMFC degradation under maritime operating conditions and its integration into reliable prognostic models. To address this gap, this review provides an overview of LT-PEMFC durability and prognostic models from the perspective of maritime applications. Through a comparative analysis of studies across various sectors, we identify and discuss maritime-specific degradation drivers, including ship load profiles, sodium chloride contamination, vibrations, and wave-induced inclinations. Building on this analysis, we critically evaluate existing prognostic models and their suitability for lifetime prediction in maritime applications. This review proposes durability enhancement strategies based on current knowledge and highlights key research gaps requiring further investigation. In addition, it outlines promising prognostic methodologies and identifies technical challenges for application to maritime LT-PEMFCs. In this way, this work lays the foundation for enhancing LT-PEMFC durability in maritime environments and supporting its broader adoption for zero-emission ships.

Solid oxide fuel cell systems are considered for the power plant of ships, because of their high efficiency, low pollutant emissions, and fuel flexibility. This research compares the volume, mass, fuel consumption, and emissions of different hybrid power plants for cruise ships using solid oxide fuel cells, fuelled with marine gas oil and liquefied natural gas. A component sizing model allocates the installed power over the selected power plant components and determines their size and weight. The components and energy management strategy are simulated with a cruise ship for five years of operation. A simple method is implemented to estimate the degradation and its effect on component operation. The combined component sizing and time-domain model highlights the importance of dynamic simulation for battery sizing. The results show that using solid oxide fuel cells for the auxiliary consumers can reduce greenhouse gas emissions by 21% and pollutants by 38% to 46% with only 17.5% installed power, which has limited consequences for the cost and size of the power plant. With 31% installed power, the ship can operate in low-emission zones while reducing greenhouse gas emissions by 33% and pollutants by 60% to 70%. Performing all cruise operations requires 51% installed fuel cell power and reduces greenhouse gas emissions by 49% and pollutants by 94% to 96%. In conclusion, the study affirms that solid oxide fuel cell systems, with proper sizing and energy management, can be used to reduce shipping emissions and reach IMO's 30% GHG emission reduction target for 2030.

Hydrogen economy is spreading across the maritime sector in response to increasingly stringent regulations for shipping emissions. The challenging on-board hydrogen logistics are often mitigated with hydrogen carriers such as methanol. Research on methanol reforming to hydrogen for fuel cell feed is conducted mostly in steady state, overlooking dynamic reactor operation and its effects on the power production system. Forced reactor operations induce fluctuations of CO content in the reformate potentially harmful to the PEM fuel cell, and drops in methanol conversion causing inefficient operation. In present research, simulations with a physical 2D unsteady model of a packed bed methanol steam reforming reactor resulted in methanol conversion drop durations of up to a minute. Additionally, temporary increases of CO content up to 112% were observed. Throughput ramp ups most notably impact the conversion, while ramp downs negatively affect selectivity. The investigation on reactor geometry concludes that larger tube diameters increase transient time and CO spikes, while they decrease with reactor length. Amplified unsteady effects are also observed with larger changes in input process variables. The results imply that heat transfer rate to the reactor are most often the detrimental factor for transient effects and durations in practice. Following this work, inclusion of realistic heating methods is recommended, instead of uniform tube temperatures used in present simulations. Heating system characteristics are necessary for realistic evaluation of the methanol reformer constraint on fuel cell feed demand in fully integrated systems.

Sustainability regulations urge the maritime sector to implement green technologies. The integration of polymer electrolyte membrane fuel cell (PEMFC) systems is a promising solution to cut emissions. However, their degradation in maritime environments is rarely addressed, while the environment differs significantly from land-based or automotive contexts and can greatly affect the type and extent of damage. Research in this field is especially relevant as ships often operate in isolated areas and require durable and reliable power propulsion systems. This work collects the insights from existing PEMFC durability research and analyzes degradation mechanisms specifically relevant for the maritime field. We consider air and fuel contamination, maritime load profiles, and vessel motions as potential causes. Insightful schematics summarize the content by linking these causes to damage indicators. Moreover, we identify various areas for further research including degradation from interconnected effects of maritime drive cycles, marine air salinity, hydrogen-carriers and their residues, long term maritime vibrations, and dynamic inclination. The overview of existing literature combines insights from electrochemistry and maritime research while the knowledge gaps help to prioritize future research. Together, these elements promote collaboration in this multidisciplinary field, advancing mitigation strategies and improving cell, stack, and ship design and operation. Such improvements encourage PEMFCs application in ships and support the move towards zero-emission shipping.

The maritime industry increasingly adopts hybrid fuel cell systems to reduce emissions and improve energy efficiency. This chapter examines the current state-of-the-art energy management strategies (EMS) for hybrid fuel cell applications in ships. It provides an in-depth analysis of various strategies, including rule-based, optimization-based, and learning-based approaches, highlighting their benefits, challenges, and real-world applications. The review begins with an overview of hybrid fuel cell systems, their configurations, and control strategies, followed by a detailed examination of EMS. Rule-based strategies are discussed in terms of their simplicity and effectiveness in dynamic marine environments. Optimization-based strategies are evaluated for their ability to enhance system and performance through advanced computational techniques. Learning-based strategies, particularly those leveraging machine learning and reinforcement learning, are explored for their potential to adapt to varying operational conditions. The chapter concludes by identifying the technical, economic, and regulatory challenges facing the adoption of these strategies and proposing future research directions.

HYLENA will investigate, develop and optimize an innovative, highly efficient integrated hydrogen powered, electrical aircraft propulsion concept for short and medium range. It will achieve significant climate impact reduction by being completely carbon neutral with radical increase of overall efficiency. The full synergistic use of: a) an electrical motor (as the main driver for propulsion), b) a contoured hydrogen fueled SOFC stacks (geometrically optimized for nacelle integration), c) a gas turbine (to thermodynamically integrate the SOFC), will act as an enabler for hydrogen aviation and will allow for efficient and compact engine concepts. This disruptive propulsion system will be called HYLENA concept. HYLENA aims to evaluate and demonstrate the feasibility of a “game changing” engine type which integrates Solid Oxide Fuel Cells (SOFC) into a turbomachine, in order to utilize the heat generated by the fuel cells on top of its electrical energy. The combination of e-motor, turbomachine and contoured SOFCs fueled with H2 will deliver high overall efficiency and performance versus state-of-the-art turbofan engines. Indeed, HYLENA Figures of Merit consist of minimizing CO2 emission; negligible NOX and an unmatched overall efficiency versus state-of-the-art turbofans which corresponds to an outstanding performance increase. It will also enable to extend the flight range for the same fuel tank size. The HYLENA project will deliver: 1. On SOFC cell level: Experimental investigations on SOFC cell technologies and identification of the most promising one(s) for aeronautical applications; 2. On SOFC stack level: Studies and tests to determine the most compact/light/manufacturable way of stack integration; 3. On thermodynamic level: Cycles simulations of the proposed novel HYLENA concept architecture and down selection of the most performing one; 4. On engine design level: Exploration, through resilient calculation and simulation, of the best engine design, sizing and overall components integration; 5. On overall engine efficiency level: Demonstration that HYLENA concept can reach very high efficiency levels with limited weight and complexity; 6. On demonstration level: A decision dossier for a potential ground test demonstrator to prove that the HYLENA concept works in practice during a second phase in the continuity of this project.

Solid Oxide Fuel Cell (SOFC) systems have the potential to reduce emissions from seagoing vessels. However, it is unknown whether ship motions influence the system's operation. In this research, a 1.5 kW SOFC module is operated on an inclination platform that emulates ship motions, to evaluate the influence of static and dynamic inclinations on the system's safety, operation, and lifetime. The test campaign consists of a static inclination test, a dynamic test, a degradation test, and a high acceleration test. There were no interruptions in the power supply during the different tests, and no detectable gas leakages or safety hazards. Although the SOFC does not fail in any test condition, dynamic inclinations result in forced oscillations in the fuel regulation, which propagate through the system by different feedback loops in the control architecture, leading to significant deviations in the operational parameters of the system. Additionally, for motion periods from 16 to 26 s, reoccurring exceedance of the fuel utilisation results in a gradual reduction of the power supply. Several enhancements are recommended to improve the design of SOFCs and marine fuel cell regulations to ensure their safe operation on ships.

An increasing demand in the marine industry to reduce emissions led to investigations into more efficient power conversion using fuels with sustainable production pathways. Solid Oxide Fuel Cells (SOFCs) are under consideration for long-range shipping, because of its high efficiency, low pollutant emissions, and fuel flexibility. SOFC systems also have great potential to cater for the heat demand in ships, but the heat integration is not often considered when assessing its feasibility. This study evaluates the electrical and heat efficiency of a 100 kW SOFC system for marine applications fuelled with methane, methanol, diesel, ammonia, or hydrogen. In addition, cathode off-gas recirculation (COGR) is investigated to tackle low oxygen utilisation and thus improve heat regeneration. The software Cycle Tempo is used to simulate the power plant, which uses a 1D model for the SOFCs. At nominal conditions, the highest net electrical efficiency (LHV) was found for methane (58.1%), followed by diesel (57.6%), and ammonia (55.1%). The highest heat efficiency was found for ammonia (27.4%), followed by hydrogen (25.6%). COGR resulted in similar electrical efficiencies, but increased the heat efficiency by 11.9% to 105.0% for the different fuels. The model was verified with a sensitivity analysis and validated by comparison with similar studies. It is concluded that COGR is a promising method to increase the heat efficiency of marine SOFC systems.