This paper investigates the effects of three ageing factors (chemical, humidity, and temperature) and their interactions on the physical properties and degradation of silicone sealant used in microelectronic applications. The thermal degradation of silicone sealants was investigated by exposing samples to temperatures in the range of 150 up to 175 °C. Also, a set of samples were aged at 40 °C in a salt spray set-up with 100 % humidity in a salty atmosphere. Results showed detectable changes in the FTIR spectra of aged specimen as compared with the as-received sample. In all accelerated testing conditions, peak intensities decreased with ageing time, inferring that that the surface characteristics of the sealant is affected by ageing. Shear test results showed that with increasing the ageing time, the maximum shear stress in most cases has decreased in all ageing conditions. Also, it appears that samples with longer ageing times have experienced more elongation before failure. Results also show that salt spraying of specimens is associated with a decrease in the mechanical properties of the sealant, indicating the deleterious implications of ionic contaminations for the mechanical properties of samples.

This paper investigates the microstructure and electrochemical properties of Polyaniline-Modified (FeCoNiCrMn)₃O₄, a high-entropy oxide, with a focus on its potential as an anode material in lithium-ion batteries. The high-entropy oxide (FeCoNiCrMn)₃O₄, featuring a spinel structure, was synthesized via a two-step process: mechanical milling of constituent oxides followed by a calcination treatment at 900 °C. To investigate the structure of the synthesized powder, scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDS), and X-ray diffraction (XRD) were employed. The results demonstrate the successful synthesis of a single-phase spinel structure with a homogeneous distribution of elements, exhibiting perfect uniformity. A Polyaniline (PANI) coating layer was subsequently applied to the HEO particles using a polymerization method. The presence of the PANI layer was confirmed using Fourier Transform Infrared Spectroscopy (FTIR). Results from impedance analysis revealed a substantial decrease in the Z-value of the PANI-modified sample compared to the pure HEO, indicating that the modified anode exhibits enhanced electrical conductivity. It is evident that the PANI coating layer has a significantly positive attribution to the electrochemical performance of the anode material by enhancing its structural stability and inhibiting excessive solid electrolyte interphase (SEI) growth during cycling. The correlations between the HEO structure and the PANI layer with the electrochemical performance of the anode material are discussed.

This paper investigates the photocatalytic characteristics of Ag nanowire (AgNW)/TiO2 and AgNW/TiO2/graphene oxide (GO) nanocomposites. Samples were synthesized by the direct coating of TiO2 particles on the surface of silver nanowires. As-prepared AgNW/TiO2 and AgNW/TiO2/GO nanocomposites were characterized by electron microscopy, X-ray diffraction, UV/visible absorption spectroscopy, and infrared spectroscopy. Transmission electron microscope (TEM) images confirmed the successful deposition of TiO2 nanoparticles on the surface of AgNWs. The photocatalytic activity of synthesized nanocomposites was evaluated using Rhodamine B (RhB) in an aqueous solution as the model organic dye. Results showed that synthesized AgNW/TiO2/GO nanocomposite has superior photocatalytic activities when it comes to the decomposition of RhB.

This paper investigates the synthesis and characterization of photoactive TiO₂/CuO nanocomposites for the simultaneous antibacterial applications and photocatalytic removal of Amoxicilline from wastewaters. Effective removal of biological and organic contaminants from water resources has become a global challenge due to contaminants' complexity and extensive use. TiO₂/CuO heterojunctions with different CuO loadings were synthesized using a straightforward precipitation method. Electron microscopy, energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), Fourier transformed infrared (FTIR), ultraviolet–visible (UV-VIS) analyses were used to characterize synthesized samples. Antibacterial activities of samples were investigated against Staphylococcus aureus. Also, the applicability of synthesized powders in the photocatalytic removal of Amoxicilline from wastewater was methodically investigated. Results showed that the photocatalytic activity of synthesized TiO₂/CuO nanocomposites is highly dependent on the CuO loadings of samples. CuO loading can also increase the light absorption within the visible light region, making TiO₂/CuO samples applicable in the visible light region. Results also showed that CuO loading greatly enhances the antibacterial characteristics of samples.

This paper aims to investigate the synthesis, structure, and optical properties of SiO₂ @YAG:Ce core–shell optical nanoparticles for solid state lighting applications. YAG:Ce phosphor is a key part in white light emitting diodes (LEDs), with its main functionality being the generation of yellow light. Generated yellow light from phosphor will be combined with blue light, emitted from chip, resulting in the generation of white light. Generated light in LEDs will often be scattered by SiO₂ nanoparticles. SiO₂ nanoparticles are often distributed within the optical window, aiming for a more homogeneous light output. The main idea in this research is to combine these functionalities in one core–shell particle, with its core being SiO₂ and its shell being phosphor. In this study core–shell nanoparticles with different Ce³⁺ concentrations were synthesized by a sol–gel method. Synthesized nanoparticles were characterized by X-ray diffraction (XRD), small angle X-ray scattering (SAXS) analysis, high resolution transmission electron macroscopy (HRTEM), Fourier transform infrared (FTIR), and photoluminescence spectroscopy. Luminescence characteristics of SiO₂ @YAG:Ce core–shell particles were compared with that of SiO₂ /YAG:Ce mixture composite, which is now used in commercial LEDs. Obtained results showed that core–shell nanoparticles have comparatively much better optical properties, compared to SiO₂ /YAG:Ce mixture composite and can therefore be potentially used in LEDs.

In this paper, degradation mechanisms of optical materials, used in the light emitting diode (LED)-based products, are reviewed. The LED lighting is one of the fastest technology shifts in human history. Lighting accounts for almost 20% of the global electrical energy use, inferring that replacement of traditional lighting sources with LEDs with higher efficiencies will have major positive implications for the global energy consumption. Organic optical materials are key components in LEDs in the sense that they control the functionality of the device and they have decisive effects on the durability and reliability of LEDs. This paper aims at describing the influences of chemical structure and service conditions on the degradation mechanisms of organic optical materials in LEDs which lead to the lumen depreciation, discolouration, and colour shift of the LED light output. The contributions of different degradation mechanisms of optical and package materials in LED-based products to the lumen depreciation and colour shift are methodically reviewed.

This paper investigates the root cause of the formation of surface cracks on hot-rolled C-Mn constructional steel heavy plates. Cracks are rather evenly distributed over the surface in the form of colonies of cracks. Samples were cut from the heavy plate. The microstructure of samples in the as-cast and hot-rolled states were studied using optical and electron microscopes as well as energy dispersive X-ray spectroscopy (EDS). Results show that cracks are heavily oxidized. De-carburized areas are also seen alongside cracks. The crack tip is in the form of a deer-horn, indicating that crack branching has taken place during deformation. The crack initiation sites are V-shaped grooves on the surface of as-cast slabs. Correlations between microstructures, processing parameters, and crack formation are discussed.

This paper aims at studying microstructure and mechanical properties of spark plasma sintered (SPSed) Stellite®-6 cobalt-based superalloy. SPS is a sintering technique, based on a relatively fast resistance heating using a pulsed current. Fast sintering process, associated with minimum grain growth, results in excellent mechanical properties. Samples were sintered at temperatures ranging from 950 to 1100 °C. Microstructure of samples were studied using scanning electron microscope (SEM), energy-dispersive X-ray spectroscope (EDS), X-Ray diffraction (XRD), and optical microscope. Hardness, impact test, as well as room and high temperature compression tests were used to evaluate the effects of sintering temperature and duration on the mechanical properties of SPSed samples. Results show that optimum mechanical properties can be obtained after sintering at 1050 °C for 10 min. The correlation between sintering parameters, microstructure, and mechanical properties are discussed.

This paper investigates the effects of carbon nanotubes (CNT) addition on the structure and mechanical properties of Ni ₃ Al-xB (0.0 < x < 1.5 at%) intermetallic compound. Ni ₃ Al-xB-1wt%CNT nanocomposite powders were first synthesized by mechanical alloying. Effects of CNT addition on the lattice strain and crystallite size of synthesized powders were investigated by means of X-ray diffraction (XRD) analysis. Scanning electron microscope (SEM) was used to study powder morphologies. Powders, synthesized by mechanical alloying, were then consolidated using spark plasma sintering (SPS), conducted at 950 °C under pressure 50 MPa. Microhardness and shear punch tests were employed to study the mechanical properties of sintered samples. Results show that CNT addition is accompanied by a decrease in crystallite size and a significant improvement of mechanical properties of Ni ₃ Al-xB (0.0 < x < 1.5 at%) intermetallic compounds.

This paper investigates degradation and failure mechanisms of BPA-PC lenses in simulated harsh environment conditions. Exposure of secondary optics in Light Emitting Diode LED-based systems or any other similar applications to environmental stresses can adversely effect the performance and lifetime of products. This paper simulates a harsh environment condition, using a salt bath oven. Salt spray exposure/ageing tests at 45° C were carried out up to four months. Fourier transform infrared-attenuated total reflection FTIR-ATR spectrometer and Lambda 950 Ultraviolet-Visible (UV-VIS) spectrophotometer were used to study the optical and chemical characteristics of aged plates. Results showed that salt bath exposure test resulted in the severe deterioration of optical characteristics BPA-PC samples. Degradation of optical properties of BPA-PC plates is attributable to the oxidation of samples.

Isothermal ageing of Al–Mg–Si alloys, stored at room temperature for more than 5 months, is associated with an unexpected significant increase in the overall electrical resistivity. This unexpected anomalous increase is not observed in alloys with shorter storage (natural ageing) times. This phenomenon is explained with a scenario, based on the evolution of the size distribution of Guinier–Preston (GP) zones during natural ageing and during subsequent artificial ageing. The proposed scenario can explain the contribution of natural ageing atomic clusters to this anomalous increase in the electrical resistivity. A physically based combined precipitation–electrical resistivity model, with the former being based on simultaneous nucleation-growth-coarsening reactions and the latter based on the Bragg scattering of electrons from atomic clusters, has been used to explain the electrical resistivity evolution. It is shown that the proposed model is capable of reproducing the experimental data in both short natural ageing (less than 5 months) and long natural ageing (more than 5 months) regimes.