Formation cycling is a critical process aimed at improving the performance of lithium ion (Li-ion) batteries during subsequent use. Achieving highly reversible Li-metal anodes, which would boost battery energy density, is a formidable challenge. Here, formation cycling and its impact on the subsequent cycling are largely unexplored. Through solid-state nuclear magnetic resonance (ssNMR) spectroscopy experiments, we reveal the critical role of the Li-ion diffusion dynamics between the electrodeposited Li-metal (ED-Li) and the as-formed solid electrolyte interphase (SEI). The most stable cycling performance is realized after formation cycling at a relatively high current density, causing an optimum in Li-ion diffusion over the Li-metal-SEI interface. We can relate this to a specific balance in the SEI chemistry, explaining the lasting impact of formation cycling. Thereby, this work highlights the importance and opportunities of regulating initial electrochemical conditions for improving the stability and life cycle of lithium metal batteries.

More and more printed circuit boards (PCBs) will be used in electric aircraft to achieve higher power density of the on-board electric system, while PCBs in aircraft are more likely to generate partial discharges (PDs) due to external factors such as compact structure and low air pressure. Therefore, this article proposes a fluorescent fiber-based method for detecting and evaluating PDs on PCBs. The detection method is effectively immune against the presence of the electromagnetic, acoustic, and vibration interference. Based on the optical detection, the evolution regularities of PCB surface appearance changes, optical PRPD patterns, and optical pulses during the aging process of PCB under different air pressure are analyzed in this article. Then, 12 assessment features are extracted for the PD aging process, and the contribution of these 12 features to the severity assessment at different air pressures is obtained using the minimal-redundancy-maximal-relevance (mRMR) algorithm. Finally, different numbers of PD features are tested for PD severity assessment by the support vector machine (SVM) algorithm. The evaluation results show that the severity assessment method proposed in this article can achieve an assessment accuracy of at least 91.1% and up to 94.4% under all three air pressures, which has good application and guidance value.

New 7xxx aluminum alloys with high alloying contents are being designed, which could induce serious hot tearing defects during direct-chill (DC) casting. Among all factors affecting hot tearing of 7xxx alloys, undoubtedly alloying elements play a significant role. In this study, the effect of main alloying elements (Zn, Mg, and Cu) on hot tearing of grain-refined Al-xZn-yMg-zCu alloys was investigated by a dedicated hot tearing rating apparatus simulating the DC-casting process. It was found that the minimum and maximum hot tearing susceptibilities occur for 4 to 6 and 9 wt pct Zn, respectively, indicating the complicated effect of Zn content. The hot tearing resistance of grain-refined Al-9Zn-yMg-zCu alloys is enhanced with increasing Mg content but is deteriorated with increasing Cu content. This can be attributed to the interaction of the thermal stresses, melt feeding, and final eutectics. The observed tendencies of the main alloying elements on hot tearing were also confirmed for four commercial 7xxx alloys. In addition, both the load value at non-equilibrium solidus and the SKK criterion proposed by Suyitno et al. using measured load developments were found to be good indicators in predicting hot tearing susceptibility. This study can provide a beneficial guide in designing 7xxx alloys considering the potential occurrence of hot cracks beforehand.

The 2015/16 ENSO event increased the temperature of waters surrounding northeast Australia to above 30 °C, with large patches of water reaching 32 °C, for over two months, which led to severe bleaching of corals of the Northern Great Barrier Reef (NGBR). This study provides evidence gained from remote-sensing data, oceanographic data and oceanographic modeling, that three factors caused this excessive heating, namely: 1) the shutdown of the North Queensland Coastal Current, which would otherwise have flushed and cooled the Northern Coral Sea and the NGBR through tidal mixing 2) the advection of warm (>30 °C) water from the Gulf of Carpentaria eastward through Torres Strait and then southward over the NGBR continental shelf, and 3) presumably local solar heating. The eastward flux of this warm water through Torres Strait was driven by a mean sea level difference on either side of the strait that in turn was controlled by the wind, which also generated the southward advection of this warm water onto the NGBR shelf. On the NGBR shelf, the residence time of this warm water was longer inshore than offshore, and this may explain the observed cross-shelf gradient of coral bleaching intensity. The fate of the Great Barrier Reef is thus controlled by the oceanography of surrounding seas.

The effect of Zn addition on the hot tearing susceptibilities of non-refined Al-xZn-2Mg-2Cu (x = 2-12 wt pct) alloys was investigated via direct crack observations and load response measurements. The obtained experimental results were compared with the predictions made using a modified Rappaz–Drezet–Gremaud (RDG) hot tearing model. Both the minimum crack width and load at the non-equilibrium solidus (NES) temperature (which served as a good indicator of hot tearing response) were observed at a Zn concentration of approximately 4 wt pct, and the formation of cracks was highly correlated with the predictions made via the modified RDG hot tearing model (although the obtained relationship critically depended on the magnitude of fraction solid at which solid coalescence was expected to occur). Furthermore, it was confirmed from the load development pattern that the addition of Zn into the matrix of Al-xZn-2Mg-2Cu alloys promoted the formation of coalesced networks, which decreased their corresponding coalescence fraction solids.

Cold cracking is a severe challenge during the direct-chill casting of high-strength 7××× series aluminum alloys. A finite element method (FEM) simulation combined with a cold cracking criterion has been demonstrated to possess obvious technical advantages in cold cracking prediction. However, the current absence of mechanical properties and effective criteria for 7××× series aluminum alloys inhibits the progress of the technique. In this study, the corresponding mechanical properties of four typical 7××× series aluminum alloys are investigated. The cold cracking tendencies of the alloys are evaluated by a new cold cracking index (CCI) developed by the authors. It is shown that AA7055 has the highest cold cracking propensity among the four alloys, followed by AA7050, AA7085, and AA7022, respectively. The cold cracking tendency is basically consistent with the amount of nonequilibrium eutectics of the alloys under the same casting process. It is also shown that the application of water wiper can effectively decrease the occurrence of cold cracking.