Mar Palmeros Parada
Please Note
20 records found
1
To Treat or Not to Treat
Comparing Health Impacts of PFAS Exposure to Health Impacts of PFAS Removal Technologies
We performed a life cycle assessment to quantify the health lost (in DALYs) due to an increased regeneration frequency of granular activated carbon (GAC), which is used at a local drinking water producer to meet recent PFAS guidelines. To quantify the health gained by lower PFAS exposure, we fir st used the existing physiologically based pharmacokinetic model by EFSA to relate ?EFSA4 concentrations in drinking water to those in blood serum. Serum concentrations were then used in exposure response relationships from literature to relate them to an increase in disease occurrence, which was subsequently related to DALYs.
For all endpoints considered, we found that the gain in human health by removing PFAS from drinking water was in the same range as the loss of human health from the increased GAC regeneration. While the high uncertainty in PFAS health effects limits our ability to make a reliable comparison, it is likely that other interventions that limit PFAS exposure have a higher net benefit than drinking water treatment. For example, phasing out all non-essential uses of PFAS will lead to a decreased exposure via multiple routes, including diet. Altogether, PFAS limits in drinking water may need to be determined on a case-by-case basis, that considers the current concentration levels in addition to the secondary impact of the required treatment technologies. This study mainly serves to start a dialogue about this complex issue, which is particularly important as increasingly many PFAS are added to drinking water guidelines, most of which are even more challenging to remove than those currently included. ...
We performed a life cycle assessment to quantify the health lost (in DALYs) due to an increased regeneration frequency of granular activated carbon (GAC), which is used at a local drinking water producer to meet recent PFAS guidelines. To quantify the health gained by lower PFAS exposure, we fir st used the existing physiologically based pharmacokinetic model by EFSA to relate ?EFSA4 concentrations in drinking water to those in blood serum. Serum concentrations were then used in exposure response relationships from literature to relate them to an increase in disease occurrence, which was subsequently related to DALYs.
For all endpoints considered, we found that the gain in human health by removing PFAS from drinking water was in the same range as the loss of human health from the increased GAC regeneration. While the high uncertainty in PFAS health effects limits our ability to make a reliable comparison, it is likely that other interventions that limit PFAS exposure have a higher net benefit than drinking water treatment. For example, phasing out all non-essential uses of PFAS will lead to a decreased exposure via multiple routes, including diet. Altogether, PFAS limits in drinking water may need to be determined on a case-by-case basis, that considers the current concentration levels in addition to the secondary impact of the required treatment technologies. This study mainly serves to start a dialogue about this complex issue, which is particularly important as increasingly many PFAS are added to drinking water guidelines, most of which are even more challenging to remove than those currently included.
Sustainability assessment framework for integrated seawater desalination and resource recovery
A participatory approach
PFAS drinking water treatment trade-offs
Comparing the health burden of GAC treatment to the health benefits of reduced PFAS exposure
Thermal seawater desalination for irrigation purposes in a water-stressed region
Emerging value tensions in full-scale implementation
Water scarcity in arid regions has driven the spread of desalination. These systems contribute to water access but come at an intensive energy cost, and lead to brine discharge and associated environmental impacts. This work aims to investigate emerging societal issues and tensions when developing and implementing a thermal desalination system to produce irrigation water in the South of Spain. This has been done in a demonstration system for solar desalination able to recover water and salts from desalination brine. For this purpose, a context-sensitive design exercise has been implemented. First, tensions between social values expressed by diverse stakeholders have been identified. Then, a set of technical scenarios for the full-scale implementation of the system were designed and evaluated, comparing them to conventional membrane desalination. The analysis indicates high economic and energy costs to avoid the environmental impacts of increasing water production.
This work explores resource recovery coupled to seawater desalination in small islands. As small islands depend on seawater desalination for water access, they make an excellent ground for exploring the trade-offs associated to resource recovery, like potential economic gains, energy use, and environmental impacts. Here, we investigated these tensions in the context of Lampedusa, in Italy. We then developed and evaluated scenarios for the recovery of additional water, Mg, and other resources from brines, to identify if and how resource recovery is an interesting approach for the island vis-à-vis these tensions. We have found that the potential to increase water production with water recovery from brine is an interesting alternative for small islands, especially when harnessing waste heat. However, while some technologies offer possibilities for recovering additional resources, in places like small islands the potential benefits from additional recovery do not seem to justify the costs to the local system.
The recovery of resources, including water reuse, has been presented as a solution to overcome scarcity, and improve the economic and environmental performance of water provision and treatment. However, its implementation faces non-technical challenges, including the need to collaborate with new stakeholders and face societal acceptance issues. Looking at the prominence of the circular economy in current policy developments and the challenges to resource recovery, exploring these issues is urgently needed. In this work, we reviewed a broad range of literature to identify societal values relevant to the recovery of water and other resources from wastewaters, particularly urban and industrial wastewater and desalination brines. We discuss tensions and uncertainties around these values, such as the tension between socio-economic expectations of resource recovery and potential long-term sustainability impacts, as well as uncertainties regarding safety and regulations. For addressing these tensions and uncertainties, we suggest aligning common methods in engineering and the natural sciences with Responsible Innovation approaches, such as Value Sensitive Design and Safe-by-Design. To complement Responsible Innovation, social learning with a Sustainability Transitions or Adaptive Governance perspective is suggested.
...
This paper investigates green hydrogen and bio-based sustainable aviation fuels, including their production technology and feedstock, in combination with Clean Sky 2 propulsion technologies and novel hydrogen-powered propulsion technologies. The impact that these alternative aviation fuels and propulsion technologies can have on greenhouse gas emissions is identified and the demand for alternative aviation fuels is compared with their expected availability, both until 2050.
OSiD
Opening the conceptual design of biobased processes to a context-sensitive sustainability analysis
Biobased production has been promoted as an alternative to fossil-based production to mitigate climate change. However, emerging concerns over the sustainability of biobased products have shown that tensions can emerge between different objectives and concerns, like emission reduction targets and food security, and that these are dependent on local contexts. Here we present the Open Sustainability-in-Design (OSiD) framework, the aim of which is to integrate a context-sensitive sustainability analysis in the conceptual design of biobased processes. The framework is illustrated, taking as an example the production of sustainable aviation fuel in southeast Brazil. The OSiD framework is a novel concept that brings the perspectives of stakeholders and considerations of the regional context to an ex ante sustainability analysis of biobased production. This work also illustrates a way to integrate methods from different scientific disciplines supporting the analysis of sustainability and the identification of tensions between different sustainability aspects. Making these tensions explicit early in the development of biobased production can make them more responsive to emerging sustainability concerns. Considering the global pressure to reduce carbon emissions, situating sustainability analyses in their socio-technical contexts as presented here can help to explain and improve the impacts of biobased production in the transition away from fossil resources.
The growth in biofuels’ investment brings with it concerns about the social and environmental impacts of the sector. Several tools and frameworks have been used to address these concerns, including the Responsible Research and Innovation (RRI) framework. This paper analyzes whether this framework can be applied in contexts where local culture and values shape differently the freedom of speech and engagement, such as in developing countries in which biofuel innovation projects are often implemented. A literature review focused on eight case studies of other authors was used to explore the role of “participation” as a structural element of the RRI framework and the impact of its absence where effective participation in the innovation development process is not possible. In conclusion, we highlight how this inspirational normative framework, designed to influence innovation, is misused to judge its impacts. More than that, the conclusions of such misused applications reflect more the difficulties involved in applying guidelines than the responsible character of the innovation, whose impacts are usually defined upfront materially and measurably.
Biobased production has been promoted as a sustainable alternative to fossil resources. However, controversies over its impact on sustainability highlight societal concerns, value tensions and uncertainties that have not been taken into account during its development. In this work, the consideration of stakeholders’ values in a biorefinery design project is investigated. Value sensitive design (VSD) is a promising approach to the design of technologies with consideration of stakeholders’ values, however, it is not directly applicable for complex systems like biorefineries. Therefore, some elements of VSD, such as the identification of relevant values and their connection to a technology’s features, are brought into biorefinery design practice. Midstream modulation (MM), an approach to promoting the consideration of societal aspects during research and development activities, is applied to promote reflection and value considerations during the design decision making. As result, it is shown that MM interventions during the design process led to new design alternatives in support of stakeholders' values, and allowed to recognize and respond to emerging value tensions within the scope of the project. In this way, the present work shows a novel approach for the technical investigation of VSD, especially for biorefineries. Also, based on this work it is argued that not only reflection, but also flexibility and openness are important for the application of VSD in the context of biorefinery design.
Biorefinery Design in Context
Integrating Stakeholder Considerations in the Design of Biorefineries
Sustainable development has become an outstanding aspiration in our society. However, the meaning of sustainability and how it should be operationalized is a complex issue that depends on subjective beliefs and values. To advance toward sustainable biobased production, we present an approach to delimit the design space of biorefineries by considering stakeholders’ values. Concepts from Design for Values were taken as the starting point for this approach, which was further developed with a biojet fuel production case in the Brazilian states of Minas Gerais and São Paulo. Design propositions that considered the interaction between stakeholders’ values, sustainability, and the production system were derived and used to suggest design space boundaries. These design boundaries are indicative, allowing for deliberation during future design activities. Through them, designers are prompted to actively reflect on the interaction between biorefinery systems and the socioeconomic and environmental context around them. By opening the design process to stakeholders’ values, we have developed a constructivist approach to incorporate sustainability in an inclusive and context-specific manner during the early stages of biorefinery design.
The incorporation of sustainability in the design of biorefineries is central for the development of the biobased economy. In this paper sustainability methods and metrics in current biorefinery design practices are analyzed to identify challenges and opportunities for future improvements in the field. Generally, there is a need for an integral analysis that includes societal impacts and goes beyond the automatic use of metrics for predefined issues. Although efforts have been made to develop more integral sustainability analyses for biorefinery design, they are often challenged by disciplinary boundaries that yield a narrow scope of analysis (e.g. conversion process, supply chain), and are blind to contextual settings or stakeholder perspectives. Multi and trans-disciplinary, inclusive and context aware approaches are identified as opportunities to overcome them in future developments.
OPBC PROJECT Mill Integrated Conversion of Palm Biomass to Commodity IntermediatesiiFurthermore, after a Life Cycle Assesment (LCA) it is found that the environmental impact of palm oil, as inEDIP 2003 methodology,is greatly reducedwhen the proposed process is included. The degree in which the impact is decreased depends on the considerations taken in the assessment, Bearing in mind the fermentable sugar productis a sugar replacement, the environmental impact of palm oil can be reducedat least39%. Although the assessment is based on rough considerations, given the scope of this design project this impact reductionis considered a good initial estimation of the benefits it can bring to the palm oil production.Overall, it is found that the proposed process can bring an economic benefit to palm oil mills, increasing the availability of renewable feedstocks for the chemical industryin Malaysia. It is found that larger scales result in highersugarproduction costs when transportation of biomass is considered. Thus, the profitability of the proposed process at lower scales is more robust to changes in fermentable sugar product price and transportation distance. Thus, it is considered that the processat a three-mill scale is a better alternative ...
OPBC PROJECT Mill Integrated Conversion of Palm Biomass to Commodity IntermediatesiiFurthermore, after a Life Cycle Assesment (LCA) it is found that the environmental impact of palm oil, as inEDIP 2003 methodology,is greatly reducedwhen the proposed process is included. The degree in which the impact is decreased depends on the considerations taken in the assessment, Bearing in mind the fermentable sugar productis a sugar replacement, the environmental impact of palm oil can be reducedat least39%. Although the assessment is based on rough considerations, given the scope of this design project this impact reductionis considered a good initial estimation of the benefits it can bring to the palm oil production.Overall, it is found that the proposed process can bring an economic benefit to palm oil mills, increasing the availability of renewable feedstocks for the chemical industryin Malaysia. It is found that larger scales result in highersugarproduction costs when transportation of biomass is considered. Thus, the profitability of the proposed process at lower scales is more robust to changes in fermentable sugar product price and transportation distance. Thus, it is considered that the processat a three-mill scale is a better alternative