Chemical process industries are threatened by accidental and intentional major events that may lead to catastrophic consequences due to hazardous materials' production, operation, and storage. Remarkably, the digitalization of industrial facilities brings emerging cyber-physical attack risks, which calls for a holistic and integrated safety and security risk assessment and management. Considering the dynamic aspects of risks, the continuous monitoring and assessment of risk-related variations plays a vital role in making timely adaptions to risk treatment strategies and, therefore, accommodating increasing risks. To this end, this study proposes a comprehensive framework for risk-based safety and security barrier management, handling challenges in assessing integrated safety and security risks and deriving timely and cost-efficient barrier improvement strategies in case undesired risks are increasing to unacceptable levels. The fundamental ideas and applicable procedures are elaborated before a case study is demonstrated to offer insights into its feasibility. The case study shows that implementing this framework holds advantages in managing safety and security risks in a unified way, considering the interplays between safety and security and making continuous risk-treatment adaptions to sustain the safety and security of digitalized chemical process systems. Furthermore, the principles and precautionary considerations pertinent to this new framework are discussed to foster its application in real-world settings.

The rapid industrialization and urbanization in China require a high level of safety management and thus urge the development of safety risk assessment in China. In the past two decades, many safety risk assessment research findings have been published in international journals by Chinese scholars, while it is not clear the development progress and China's contributions to the world in this research field. Therefore, a systematic and thorough literature review is conducted to investigate risk assessment research in China. Firstly, the research publications authored by Chinese scholars are searched from the well-known literature database Web of Science to support the analysis of risk assessment research in China. Secondly, a bibliometric analysis is conducted for the obtained literature related to risk assessment research in China to find out publication trends, research organizations, research authors, research topics, and research methods. Then, a thorough analysis of research topics and research methods is carried out to present the research progress. Finally, possible future research issues in the risk assessment research domain are discussed based on this literature review. According to the discussion, more attention in China should be paid to the risk of digital or autonomous systems, the risk related to extreme events, and the risk in large cities.

Integrating process safety and process security risk management is increasingly essential for enhancing resilience in the chemical process industry. This study addresses how practitioners perceive the integration of these two domains, identifying key benefits, barriers, and strategies for effective implementation. A mixed-methods approach was applied, combining quantitative survey data from 47 industry professionals with qualitative insights from open-ended responses. The findings highlight significant advantages of integration, such as optimized resource use, reduced operational redundancies, and improved risk management. However, barriers such as knowledge gaps, resource constraints, and communication silos were identified. Respondents emphasized the importance of adopting a resilience-oriented approach involving proactive risk management, continuous improvement, and adaptability in both safety and security practices. Critical enablers for integration include strong leadership, alignment of societal values, cross-disciplinary training, and integrated risk assessment methodologies. Emerging technologies and regulatory alignment were also identified as critical factors in facilitating integration. The study contributes to the theoretical understanding of integrated risk management by supporting resilience engineering and systems theory. It offers actionable strategies for overcoming barriers and leveraging enablers, laying the groundwork for developing a resilience-oriented framework for process safety and process security risk management.

Explosion-induced domino accidents in the chemical industry, such as the 2005 Buncefield and 2019 Xiangshui accidents, can lead to catastrophic losses. Recent studies commonly use probit models (simplified linear regression models) to predict the probability of accident escalation caused by equipment failure due to overpressure conditions but necessitate distinct equations for different equipment types. In order to simplify the number of models and improve their accuracy, this study introduced three machine learning models (random forest model, convolutional neural network model, and deep neural network model), addressing complex nonlinear relationships that conventional regression models may not fully capture. By model training, the DNN model has the highest accuracy (99 %), followed by CNN (94 %) and random RF (95 %). The DNN model was selected as the optimal data-driven model for equipment vulnerability assessment due to their feedforward mechanism's capability to dynamically align parameters with evolving data distributions. The approach developed can not only predict the probability of equipment damage by integrating values related to peak overpressure and equipment type but also effectively address the accuracy validation issues associated with traditional regression models. Besides, this approach can be considered open source model and more explosion data may be used in the future to further improve the model.

In the process industry, hazardous chemical accidents can easily cause heavy loss, and emergency response is an important approach to reduce it. In the process of emergency response, many emergency tasks have different characteristics in their execution. This study analyzes the impact of the dynamic changes of emergency response personnel on the emergency tasks, and deduces the relationship between the execution time of an emergency task and the number of people with the time they join the task. Aiming to model the emergency response process under the possible dynamic change of the emergency task execution time, the dynamic timed Petri-net (DTPN) is proposed by improving the timed Petri-net (TPN) on the basis of the execution mechanism of transition, and the corresponding models are established according to several basic execution characteristics of the emergency tasks. The proposed approach is used to model the emergency response of on-site responders to a fire in a storage tank, and the time analysis is carried out. The results show that the approach can well solve the problem of modeling and analysis of emergency tasks with dynamic execution characteristics.

In the fire related domino effect analysis of storage tanks, time to failure is a very important issue, which helps to analyze the time characteristics of accident propagation in a certain area, and is also an important parameter for some methods to determine the failure probability of target tanks. This study carries out a numerical simulation to analyze the time to failure of tanks under fire with respect to domino effects, taking the time at which the tank wall stress exceeds the yield strength as the failure time of the corresponding tank. Two scenarios of fire escalation in domino effects are studied, and the time to failure under the synergistic effect of thermal radiations is analyzed. More importantly, this study performs the analysis of time to failure of the target tank considering heat radiation accumulation, that is, under the circumstance of successive multiple tank fires, the fire thermal radiations from multiple fires do not simultaneously influence the target storage tank, but they have an accumulation effect in the target tank, and this way influence the time to failure of the tank.

The evolving energy landscape in Europe is showing concrete signals that hydrogen will play a central role in the energy transition scenario. In this light, a report of the European Hydrogen Backbone pinpoints no less than forty existing projects focused on the commissioning of several kilometers of hydrogen pipelines in the following years. Hence, ensuring a safe operability of these systems represents a topic worthy of investigation and marked by significant challenges, especially given the unique properties that make hydrogen a potentially hazardous substance. Established techniques may prove helpful in supporting the development of dedicated prevention and mitigation strategies for hydrogen systems. Among these, Risk-Based Inspection (RBI) could represent an effective tool to design inspection programs aimed at the detection of hydrogen-induced damages, especially for components working in pressurized environments, including pipeline materials. However, the lack of operational experience associated with emerging technologies may lead to the adoption of over-conservative safety measures, which could impact the economic attractiveness of these systems. Therefore, this study proposes an evolution of conventional RBI planning by implementing concepts of safety economics and optimization modelling, thus building a novel approach named “Cost-Informed Risk-Based Inspection” (CIRBI). The proposed methodology is therefore applied to a case study of inspection techniques potentially suitable for pipeline materials (i.e., API X-series pipeline steels), showcasing its potential as a self-standing approach for inspection planning while also demonstrating the insight that it may provide to ensure a safe operability of hydrogen pipelines.

Introduction: Recent developments in a wide variety of cyber-physical system (CPS) designs have resulted in many safety and security concerns. These are caused by increasing complexity, connectivity to the outside world, and a variety of component types, all contributing to increased system vulnerability. Simultaneously, the use of digital models, big data analytics, remote computing, online services, and machine learning extends manufacturing systems far beyond their physical and visible boundaries. Focusing on industry and healthcare settings, this study explores the challenges faced by safety and security management originating from these developments.

Method: The scoping review method was used to gather literature on safety and security concerns. These are grouped and linked to the CPS components. Subsequently, their impact is reviewed from the perspective of safety and security management systems.

Results: The findings indicate that safety and security management become entangled, many new risks need to be considered, and the availability of online digital real-time system components and employee skills are critical factors. Some of the sensors and safety metrics software must now be classified as safety-critical because robots and people have started to share the same workspace. The rapid developments and many unresolved issues on design, ethics, data and software quality, external supervision, standards and guidance, legal frameworks, and online system components abroad urgently require attention. In the discussion, several recommendations are made regarding how safety and security management can address these challenges.

Conclusions: While robots and people increasingly mingle on shop floors and in care situations, safety management is lagging behind current CPS developments. New critical safety aspects require the attention of safety and security management. Practical applications: These findings in safety and security management systems will contribute to avoiding harm to people and the environment in companies operating CPS. One sentence summary: This study presents a structured way to deal with safety management of Cyber-Physical-Systems.

In recent years, the relationship between academia and the fossil fuel industry has become a focal point of intense debate. This concern arises from the fear that corporate funding might skew research activities. A significant development in this area is the adoption of policies by a Dutch university, and discussions in several others, prohibiting research funded by the fossil fuel industry. These policies aim to safeguard academic freedom and integrity. Despite this, there has been little discussion on the myriad challenges, implications, and possible unintended consequences, particularly in the realm of safety-and-security research. As such, this manuscript delves into the complex transition towards a fossil-fuel-free society, examining it through the lenses of safety science and sociotechnical systems. It emphasizes the vital importance of collective responsibility in ensuring systemic safety and security as we navigate towards achieving the sustainable development goals. This journey requires a delicate balance between the objectives of safety and sustainability, along with a deep understanding of the security implications of decreasing our dependence on the fossil fuel industry. The strategy of distancing academic research from fossil fuel industries, commonly seen as a positive step, also demands a nuanced consideration of its broader impacts, including the setting of precedents for addressing other existential and systemic risks. Instead, we argue for the establishment of robust governance structures rooted in restorative justice principles. Such frameworks can facilitate productive dialogue with underrepresented groups, motivate the fossil fuel industry towards sustainable practices, and safeguard the integrity of scholarly research. This approach not only addresses immediate concerns related to fossil fuels but also lays the groundwork for a more inclusive and equitable model of climate risk research, essential for tackling the multifaceted challenges of our era.

If a fire occurs in an area with multiple installations storing or handling flammable materials, it may escalate from one installation to another to form so-called domino effects. The propagation of fire-induced domino effects has temporal properties due to the heating effect of the thermal radiation of fires. Under the action of thermal radiation, the surrounding installations may be damaged, and the probability of damage can be estimated by Probit models. As a result, the propagation path exhibits characteristics of randomness. As new installations catch fire due to domino effects, the thermal radiation received by a target installation changes, so that the damage probability changes dynamically throughout the accident process. This study aims at further improve the previous study of the matrix modeling approach for fire-induced domino effects by considering the heating process of facilities under fire accidents. The analysis process incorporating the damage probability calculation algorithm is presented. The improved approach is illustrated by the study of two cases.

Domino effects are a complex phenomenon of accident escalation with high uncertainty, which could lead to catastrophic consequences. Predicting the probability of domino effects presents a great challenge in the field of process safety. In multi-level domino chains, synergistic effects of accidents would further raise the complexity of probability prediction since escalation vectors emitted from those accidents may be coupled. In this paper, four categories of synergistic effects are classified according to the type of accidents and their place on the domino accident sequence. Subsequently, specific models for estimating escalation probability under different synergistic accident scenarios are proposed based on the widely-used probit models, allowing the analysis of the coupling effects of escalation vectors. A probability prediction method for domino chains is further developed using Bayesian Network. The application of the developed method is demonstrated by a case study, and the domino probability is estimated accounting for the synergistic effects and all possible accident scenarios. The key units for promoting accident propagation are further identified through posterior probability analysis. The method would be helpful for domino risk assessment and management of any chemical industrial area.

Risk assessment can reveal the level of a safety situation which can be very important info for company safety management. Considering the multiple factors in risk assessment of a system and the vagueness nature of many factors, and using the benefits of the Petri-net in modeling and reasoning, a weighted fuzzy Petri-net (WFPN) based risk assessment approach which combines WFPN with the SPA-fuzzy method is proposed in this paper. The SPA-fuzzy method is utilized to establish the membership functions for fuzzy assessment, taking its advantage in comparing identity, contrary and discrepancy features of two different sets. In this study, the WFPN is redefined to model relationships between assessment factors, and the matrix-based fuzzy reasoning algorithm is provided to assess the factors in parallel. The application of the proposed risk assessment approach is illustrated by case studies: the risk assessment of a chemical storage tank area and the ignition accident assessment of hydrogen refueling stations.

Industrial production intensification greatly enhances resource utilization efficiency and production efficiency within the modern petrochemical industry (MPI). However, densely located hazardous installations pose significant threats to workers, society and environment. Under this impetus, an advanced pareto-based optimization methodology is proposed for chemical tank farm (CTF) design. The objectives of domino risk minimization and land resource utilization efficiency maximization can be achieved through optimizing the locations and dimensions of storage tanks. A simplified quantitative domino risk assessment procedure is developed within a grid-based Cartesian coordinate system, which links the design parameters and risk values. A bi-objective optimization model is developed for problem formulation and a well-designed simulated annealing-based multi-objective particle swarm optimization is proposed for model solving. A CTF with six floating roof diesel tanks is adopted for case study. The simulated annealing-based jumping mechanism can effectively avoid the local optimum, which makes the algorithm easier to obtain the trade-off with great convergence and diversity. The proposed methodology can provide safer and more cost-effective design solutions. Results indicate that the design parameters can significantly affect the regional domino risk distribution. The conflicting nature between safety and economy is discussed. This work is of great significance for the safety and reliability of MPI.

Earthquake-triggered fire domino scenarios (E-FDSs) arise frequently from the interaction between earthquakes and chemical installations, resulting in catastrophic multi-hazard coupling events. The complicated mutually amplified phenomena between natural disasters and chemical accidents significantly aggravates the escalation of domino accidents, which has posed great challenges for modeling and preventing E-FDSs. Under this impetus, this work proposes an advanced type-2 fuzzy probabilistic methodology to obtain the time-dependent failure probability of steel cylindrical tanks (SCTs) subjected to the earthquake-fire sequence. To cope with the limited prior knowledge on E-FDSs, a basic universal is established to describe the fire resistance attenuation caused by the seismic damage. The coupling failure criterion of SCTs is formulated by a type-2 fuzzy time-dependent limit state equation. A credibility-based stochastic simulation algorithm is developed for the hybrid uncertainty analysis (combining ambiguity and stochasticity). The proposed methodology is validated by case studies of a 5000 m³ fixed roof tank. Compared to the existing accident probability model, the proposed methodology can not only capture the fire resistance attenuation caused by the seismic damage but also provide a dynamic estimation of tank failure probability with respect to the fire exposure time. The proposed methodology can effectively and dynamically capture the accident evolution process, which in turn helps mitigate and prevent the spatiotemporal propagation of domino effects.

When a major chemical accident occurs, emergency response is an important measure to reduce accident losses. Some actions in an emergency response may be more important than others in reducing accident losses, so they need to be carried out as a matter of priority. The impact of the number of emergency personnel on the relationship between emergency response actions and time of emergency response process is analyzed in this paper in the circumstance that the number of responders is not enough to carry out emergency actions with priority at the same time, and a Petri-net based approach is proposed to model and analyze the actions. An emergency response action that needs to consider its priority is divided into two stages, one is to determine the personnel for executing the action, the other is the execution of the action. This division facilitates the handling of dynamic changes in the relationship between actions and differences in start time of the actions. The approach is illustrated by taking the emergency response of on-site emergency personnel of a chemical plant to a fire as an example. The efficiency of the emergency process is analyzed, and for the action of rescuing the wounded, which has the highest priority in the example, the time and the probability when considering the priority of emergency response actions are compared with those when not considering the priority.

Frequent unpredictable earthquake disasters such as the Turkey Earthquake in 2023 pose an increasing threat to oil tank farms since they may trigger major accidents and domino effects, resulting in casualties, economic losses, and environmental pollution. Unpredictable earthquakes are definitely difficult to prevent and thus resilience strategies such as emergency response should be applied to reduce losses. However, little attention has been paid to the quantitative resilience modeling of oil tank farms, resulting in difficulties in decision-making on resilience assessment and management. Therefore, this study proposes a quantitative seismic resilience model of oil storage tanks by using a dynamic agent-based modeling approach. This approach models the storage tank, active fault, and the environment as three independent agents with their attributes and behaviors. The interaction between agents can also be modeled through disaster evolution rules, and the consequences of interactions can be adjusted through adaptation and recovery strategies. The dynamic propagation of earthquake accidents and the evolution of potential domino effects can be quantified from a bottom-up perspective, thereby quantifying the seismic resilience of oil tank farms. A case study is carried out to illustrate the application of the developed model in oil tank farms and to analyze the sensitivity of different model parameters. The results show that the developed model can dynamically characterize the evolution of earthquake-induced domino effects as well as the emergency and restoration processes, supporting the decision-making on the allocation of resilience measures.

To maintain continuous production, chemical plant operators may ignore faults or handle faults online rather than shutting down process systems. However, interaction and interdependence links between components in a digitalized process system are substantial. Thus, faults will be propagated to downstream nodes, potentially leading to risk accumulation and major accidents. However, limited attention has been paid to this type of risk. To model the risk accumulation process, a dynamic risk assessment method is proposed by integrating the system-theoretic accident model and process approach (STAMP) and the cascading failure propagation model (CFPM). Firstly, STAMP is used to model and analyze the system safety of a process system. Two CFPMs are then proposed to measure risk accumulation under two different engineering situations. The proposed method is applied to the Chevron Richmond refinery crude unit and its associated upstream process. The results show that the proposed approach can effectively quantify the process of risk accumulation. This method can generate a real-time dynamic risk profile to support auxiliary decision-making.

Focusing on the effective configuration of emergency response systems in utility tunnels, this study proposes an innovative approach to optimize existing emergency response systems based on a consequence rapid prediction model and genetic algorithm. In the proposed approach, the interactions between different emergency response components are considered to perform a rapid gas dispersion prediction. Furthermore, the predicted gas concentration distribution is employed to estimate the quantitative explosion risks by combining the equivalent cloud method and the Baker-Strehlow model. Finally, the cumulative and cascading risk index are proposed and combined for systematic optimization by using a genetic algorithm. A case study is performed to demonstrate the feasibility of the proposed approach. The results indicate that the optimized emergency response systems effectively reduce both the cumulative and cascading risk level. This study provides technical support for emergency response system design and helps to improve the safety-risk-control capabilities of utility tunnels.

This paper presents a systematic literature review of risk assessment methods in the chemical process industry (CPI), focusing on process safety, process security, and resilience. We analyzed peer-reviewed articles from 2000 to 2022 using the PRISMA methodology and identified twelve predominant methods. Our findings reveal a shift towards dynamic, systemic-based assessments like the Functional Resonance Analysis Method (FRAM) and System-Theoretic Accident Model and Processes (STAMP). These methods are particularly effective at capturing the complexities of sociotechnical systems in the CPI. However, a significant observation from our review is the limited emphasis on the resilience paradigm within many existing methods when addressing both process safety and process security risks, which is crucial for preventing and recovering from disruptions. Given the evolving challenges in system safety and security threats, there is an urgent need for holistic methods that integrate process safety, process security, and resilience. Our review highlights the opportunity for further research to better prepare the industry for future challenges, ensuring safer, more secure, reliable, and resilient operations.

Domino effects are high-impact low-probability events that can have catastrophic consequences. To prevent and to reduce risks related to such events, safety barriers (SBs) are crucial. However, the initiation, propagation, and stopping processes of domino effects are characterized with complexity and uncertainties and hence they are unpredictable. This makes it challenging to allocate SBs based on predicted probabilities. In this study, a multi-objective optimization model which integrates graph theory with Non-dominated Sorting Genetic Algorithm II (NSGA-II) was proposed to allocate add-on SBs effectively. Graph metrics were used to quantify the escalation risks related to storage tanks and to optimize the allocation of add-on SBs, thereby minimizing the consequences of a domino effect under a budget constraint. The results of the case study demonstrate great efficiency in finding globally optimal strategies with a largest reduction of 94.3% in the out-closeness score due to the implementation of add-on SBs, allowing decision-makers to choose the most preferable investment strategy in face of domino effect risk. Our study therefore provides a novel approach to achieve an optimal allocation of add-on SBs globally and can be useful in preventing domino effects in large-scale chemical clusters equipped with a large number of storage tanks.