Bifacial perovskite/silicon solar cells can combine the advantages of tandem technology (high efficiencies) and bifacial modules (additional received irradiance from the rear) to increase the energy yield of photovoltaic (PV) systems further. In literature, it has already been shown that for two-terminal tandems this would require a lower bandgap energy (E_g) for the perovskite cell, as the rear irradiance increases the current in the bottom cell creating a current mismatch, if this is not considered during optimization. This work expands on bifacial two-terminal tandem optimization by considering aspects not included before. Besides the E_g, the thickness (d) of the perovskite is also optimized, as this also affects the current matching. Additionally, this work studies the trends in different energy losses of the PV module to better understand what affects the optimal perovskite cell. Our simulations show that the optimal E_g is 1.61–1.65 eV and the optimal d is 650–750 nm, which agrees with the observations in literature. The optimal E_g and d are mostly a trade-off between mismatch and thermalization losses, meaning that the mismatch losses should not be fully minimized. Additionally, the irradiance from the rear side is converted less efficiently than the front side irradiance due to larger thermalization and reflection losses. Therefore, the energy yield of bifacial tandem modules, compared to monofacial tandem ones, only increases for large ground albedo. Finally, our results show that the bifacial tandems have over a 25% gain in energy yield compared to bifacial single junction modules and up to 5% gain compared to monofacial tandem modules.

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Research into the impact of innovative sustainable energy experiments and demonstrations is crucial to diversifying, scaling up, and accelerating the sustainable energy transition. Although there is vast research into sustainable energy experiments and demonstrations, research literature offers a fragmented collection of findings. A coherent overview of themes and insights regarding the transformative impact of innovative sustainable energy experiments and demonstrations on sustainable energy systems from the past, present, and near future is lacking and necessary to increase experiments and demonstrations' impact on the sustainable energy transition. The research in this study fills this knowledge gap by providing such an overview and yields novel insights into the organized function and impact of experiments and demonstrations. It spans a broad spectrum of sustainable energy technologies, the empirical domains where these are invented, developed and applied, and the stakeholders involved. The overview is the outcome of a Delphi study in which the insights of 47 international scientific research experts in sustainable energy experiments and demonstrations are bundled and explained. This study presents a thematic overview of the significant insights regarding past and current sustainable energy experiments and demonstrations and outlines a research agenda for the future. Policymakers, practitioners, and scientists can leverage this to inform their sustainable energy policies, business strategies, and research programs.@en

At standard test conditions (STC), the performance of photovoltaic modules is compared using efficiency. As irradiance and module temperature fluctuate over the year and STC efficiency does not assess the performance of the module accurately in real world conditions, the annual energy yield is used instead as performance metric. Perovskite/silicon tandem solar cells are being massively researched and sought after in PV industry for their efficiency well above 34% with further growth perspective. In this work, to evaluate and compare performance of different perovskite/silicon tandem photovoltaic (PV) modules based on different bottom cell technologies, we use a hybrid modelling approach. Such approach, combining experimentally obtained and simulated current-voltage curves, flexibly predicts the annual energy yield of novel tandem PV modules via our PVMD toolbox and enables their optimization in any location. In particular, considering (i) mono- and bi-facial architectures, (ii) 2-terminal and 4-terminal module configurations, and (iii) silicon heterojunction or novel poly-SiOx passivated c-Si solar bottom cells, we compare the annual energy yield of different perovskite/silicon tandem modules and we optimize their performance in different locations with respect to different perovskite thickness and bandgaps@en

Positive Energy Districts (PEDs) are integral to achieving sustainable urban development by enhancing energy self-sufficiency and reducing carbon emissions. This paper explores energy balance calculations in four diverse case study districts within different climatic conditions—Fiat Village in Settimo Torinese (Italy), Großschönau (Austria), Beursplain in Amsterdam (Netherlands), and Lunca Pomostului in Reşiţa (Romania)—as part of the SIMPLY Positive project. Each district faces unique challenges, such as outdated infrastructure or heritage protection, which we address through tailored strategies including building renovations and the integration of renewable energy systems. Additionally, we employ advanced simulation methodologies to assess energy performance. Simulation results highlight the significance of innovative technologies like photovoltaic-thermal (PVT) systems, application of demand-side actions, and flexible grid usage. Furthermore, mobility assessments and resident-driven initiatives demonstrate the critical role of community engagement in reducing carbon footprints. This study underscores the adaptability of PED frameworks across varied urban contexts and provides actionable insights for scaling similar strategies globally, supporting net-zero energy targets.@en

In the quest for advancing photovoltaic efficiency, the adoption of multijunction solar cell architectures has emerged as a promising approach. Perovskite/silicon double-junction solar cells have already achieved efficiencies surpassing 33%, exceeding the theoretical efficiency limit for single-junction devices. To enhance efficiency even further, exploring perovskite/perovskite/silicon (PPS) triple-junction solar cells seems a logical next step, as they offer the potential to further reduce thermalization losses and achieve even higher efficiencies. This study delves into the potential of various configurations of PPS modules, exploring different subcell interconnections. Initially, we present an optoelectrical model to simulate the performance of these devices, incorporating both luminescence coupling and cell-to-module losses. This enables us to optimize the bandgap energy of the top and middle perovskite subcells under both standard test conditions (STC) and outdoor conditions. Our analysis reveals that the addition of a perovskite subcell can improve the STC efficiency up to 9%–13%. This gain in STC performance also translates into a similar gain in energy yield, meaning that triple-junction devices produce 8%–14% more electricity than their double-junction reference devices.

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Two terminal (2T) perovskite/copper-indium-gallium-selenide (CIGS) tandem solar cells combine high conversion efficiency with lightweight flexible substrates which can decrease manufacturing and installation costs. In order to improve the power conversion efficiency of these tandem solar cells, the use of advanced simulation tools is crucial to estimate the loss mechanisms. In this regard, most of the available simulation works on tandem solar cells are oriented to minimize optical losses and assuming simplifications for the electrical simulations in particular in the top and bottom cell interconnection at the so-called tunnel recombination junction (TRJ) neglecting the inner physics of the complete tandem device. Therefore, the effect of charge exchange mechanism between top and bottom soler cells on the external parameters of a tandem devices is not fully understood yet. In this work, we present an experimentally validated opto-electrical model based on the fundamental semiconductor equations for the study of loss mechanisms of a reference perovskite/CIGS solar cell. Different from other numerical works, because our simulation platform includes the fundamental working mechanisms of the layers comprising the TRJ, we can properly calculate the losses related to it. We firstly present the calibration and validation of our opto-electrical model with respect to three fabricated reference solar cells: top cell only, bottom cell only and tandem device. Then, we use the calibrated model to evaluate main loss mechanisms affecting the baseline tandem device. Finally, we use the model to propose a roadmap for the optimization of monolithic perovskite/CIGS tandem solar cells.

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Our study focuses on the optimization of front contact design by exploring a novel bilayer configuration that employs transparent conductive oxides (TCOs) to enhance the efficiency of thin-film silicon solar cells. The TCOs investigated include sputtered hydrogenated indium oxide (IOH), cerium-doped indium oxide (ICO), cerium and hydrogen co-doped indium oxide (ICOH), and intrinsic zinc oxide (i-ZnO). We highlight the suitability of these TCOs in a bilayer design, first analyzing their opto-electrical properties as monolayers and subsequently in bilayer configurations. The IOH/i-ZnO bilayer architecture, in particular, demonstrates promising opto-electrical properties on both flat glass and micro-textured glass substrates. IOH/i-ZnO on flat glass substrate demonstrates remarkable mobility (143.44 cm²/Vs) and a carrier concentration in the order of 10¹⁹cm^-3. The mean of reflectance (R) trends consistently exceeds 80%, while the mean of transmittance (T) trends falls below 20% beyond 500 nm. The interference effects within the bilayers are minimized for designs on micro-textured glass, preserving values within a desirable range. These findings represent an innovative approach to front contact design for thin-film silicon solar cells, emphasizing the potential of bilayer configurations to advance solar cell technology.

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This paper presents dynamic air-based models of a hybrid photovoltaic-thermal (PVT) collector. The models are developed with the aim of estimating the temperature of the collector components and therefore of estimating the annual generation of electrical energy and thermal energy outputs, by using actual climate data of six different cities based on Köppen-Geiger-Photovoltaic (KGPV) climate zones. The results show that the unglazed type collector has the best PV cooling while the dual channel collector has the best air heating among air-based PVT collectors. The results also indicate that the use of additional fluid enhances both electrical and thermal performance. The dynamic models are validated by comparison with results found in the literature. The paper also discusses a novel bi-fluid PVT system combined with a storage tank and an H-infinity based robust controller that can handle uncertainties. The results of the bi-fluid system show that the fraction of energy demand covered by the system is highly dependent on climate conditions and the collector's surface area. It was found that for a small-scale house (standard for four people), the proposed system can cover more than 70% annual domestic hot water demand for cities with high solar irradiance and 32% for a city with low solar irradiance.

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The photovoltaic (PV) module energy rating standard series IEC 61853 does not cover bifacial PV modules. However, the market share of bifacial PV modules has dramatically increased in recent years and is projected to grow. This work demonstrates how Parts 3 and 4 of the IEC 61853 standard could be extended to bifacial modules. First, we develop an irradiance model that uses the data already given in the standard IEC 61853-4 to calculate the irradiance on the rear side of the module. Second, we propose a way to extend the energy yield calculation algorithm IEC 61853-3 to include bifacial modules and make it available to the PV community. This rear irradiance and bifacial energy yield calculation procedure is tested using real outdoor measurements for a nine-month period with a root mean square difference between measured and simulated energy yield of 4.65%. To conclude, we investigate the impact of different climates and normalization on the bifacial module energy rating results.

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Monolithic perovskite/c-Si tandem solar cells have attracted enormous research attention and have achieved efficiencies above 30%. This work describes the development of monolithic tandem solar cells based on silicon heterojunction (SHJ) bottom- and perovskite top-cells and highlights light management techniques assisted by optical simulation. We first engineered (i)a-Si:H passivating layers for (100)-oriented flat c-Si surfaces and combined them with various (n)a-Si:H, (n)nc-Si:H, and (n)nc-SiOx:H interfacial layers for SHJ bottom-cells. In a symmetrical configuration, a long minority carrier lifetime of 16.9 ms was achieved when combining (i)a-Si:H bilayers with (n)nc-Si:H (extracted at the minority carrier density of 1015 cm-3). The perovskite sub-cell uses a photostable mixed-halide composition and surface passivation strategies to minimize energetic losses at charge-transport interfaces. This allows tandem efficiencies above 23% (a maximum of 24.6%) to be achieved using all three types of (n)-layers. Observations from experimentally prepared devices and optical simulations indicate that both (n)nc-SiOx:H and (n)nc-Si:H are promising for use in high-efficiency tandem solar cells. This is possible due to minimized reflection at the interfaces between the perovskite and SHJ sub-cells by optimized interference effects, demonstrating the applicability of such light management techniques to various tandem structures.

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Transparent conductive oxides (TCOs) are used as front electrode of thin film silicon (TF-Si) solar cells to increase power conversion efficiency. Metal oxides doped with different materials can be deployed as TCO. The preferred TCO is usually selected using a trade-off between transparency and conductivity. This work proposes a bi-layer front contact to address the limitation of this trade-off. IOH and i-ZnO are chosen as the best candidates for such architecture due to their good opto-electrical properties. A thin layer of IOH ensures good lateral conductivity and high transparency in the visible part of the solar spectrum. An additional i-ZnO layer provides minimized parasitic absorption losses along with low transverse resistivity. The best opto-electrical properties are achieved when deposition temperature and power density are set at 25°C and 1.5 W/cm², 200°C and 2 W/cm² for IOH and i-ZnO respectively.

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Silicon heterojunction (SHJ) solar cells have achieved a record efficiency of 26.81% in a front/back-contacted (FBC) configuration. Moreover, thanks to their advantageous high V_OC and good infrared response, SHJ solar cells can be further combined with wide bandgap perovskite cells forming tandem devices to enable efficiencies well above 33%. In this study, we present strategies to realize high-efficiency SHJ solar cells through combined theoretical and experimental studies, starting from the optimization of Si-based thin-film layers to the implementation of electrodes with reduced indium and silver usage. Advanced opto-electrical simulations, which enable comprehensive theoretical understandings of the main physical mechanisms governing carriers’ collection and light management, provide clear pathways for device designs and experimental optimizations. We present the fabricated FBC-SHJ solar cells in both monofacial and bifacial configurations with the best efficiencies of 24.18% and 23.25%, respectively. We point out that to achieve optimum device performance, the compositional materials should be holistically optimized and evaluated as part of the contact stacks with adjacent layers. As an outlook beyond the classical FBC-SHJ solar cell architecture, we propose various novel SHJ-based solar cell architectures. Their potential performance was assessed and compared via rigorous opto-electrical simulations and a maximal efficiency of 27.60% was simulated for FBC-SHJ solar cells featuring localized contacts.

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The tandem PV technology can potentially increase the efficiency of PV modules over 30%. To design efficient modules, a quantification of the different losses is important. Herein, a model for quantifying the energy loss mechanisms in PV systems under real-world operating conditions with a level of detail back to the components and their fundamental properties is presented. Totally, 17 losses are defined and divided into four categories (fundamental, optical, electrical, and system losses). As example, a system based on a > 29% two-terminal perovskite/silicon tandem cell is considered. The loss distribution at standard test conditions is compared to four geographical locations. The results show that the thermalization, reflection, and inverter losses increase by 1.2%, 1.1%, and 1.4%, respectively, when operating outdoors. Additionally, it is quantified how fill factor gains partly compensate the current mismatch losses. For example, a mismatch of 7.0% in photocurrent leads to a power mismatch of 1.2%. Therefore, the power mismatch should be used as indicator for mismatch losses instead of a current mismatch. Finally, herein, it is shown that solar tracking increases not only the in-plane irradiance but also the efficiency of the tandem module.

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When integrated into urban environments, photovoltaic (PV) systems usually present operational temperatures that are significantly higher than those shown by rack-mounted systems. High operating temperatures are associated with reduced reliability of PV modules and significantly impact the electrical performance of solar cells. Utilizing the heat produced on PV modules or reducing operating temperatures can bolster their application within the building sector. We present the three main concepts studied to achieve these goals. First, a PV is a chimney concept that allows the use of the heat generated by the modules. Simulations for a PV chimney installed on a building in the Netherlands showed that although the heat quality produced inside its cavity was low, the potential use of the air mass flow for ventilation applications is promising. Additionally, we present two passive cooling solutions that can reduce the operating temperatures of PV modules: Optical filters and phase change materials. Experimental measurements in Delft showed that these solutions reduce the operating temperature of PV modules between 4 °C to 20 °C, particularly under high irradiance hours.

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Thin films of transition metal oxides such as molybdenum oxide (MoO_x) are attractive for application in silicon heterojunction solar cells for their potential to yield large short-circuit current density. However, full control of electrical properties of thin MoO_x layers must be mastered to obtain an efficient hole collector. Here, we show that the key to control the MoO_x layer quality is the interface between the MoO_x and the hydrogenated intrinsic amorphous silicon passivation layer underneath. By means of ab initio modelling, we demonstrate a dipole at such interface and study its minimization in terms of work function variation to enable high performance hole transport. We apply this knowledge to experimentally tailor the oxygen content in MoO_x by plasma treatments (PTs). PTs act as a barrier to oxygen diffusion/reaction and result in optimal electrical properties of the MoO_x hole collector. With this approach, we can thin down the MoO_x thickness to 1.7 nm and demonstrate short-circuit current density well above 40 mA/cm² and a champion device exhibiting 23.83% conversion efficiency.

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Reducing indium consumption, which is related to the transparent conductive oxide (TCO) use, is a key challenge for scaling up silicon heterojunction (SHJ) solar cell technology to terawatt level. In this work, we developed bifacial SHJ solar cells with reduced TCO thickness. We present three types of In₂O₃-based TCOs, tin-, fluorine-, and tungsten-doped In₂O₃ (ITO, IFO, and IWO), whose thickness has been optimally minimized. These are promising TCOs, respectively, from post-transition metal doping, anionic doping, and transition metal doping and exhibit different opto-electrical properties. We performed optical simulations and electrical investigations with varied TCO thicknesses. The results indicate that (i) reducing TCO thickness could yield larger current in both monofacial and bifacial SHJ devices; (ii) our IWO and IFO are favorable for n-contact and p-contact, respectively; and (iii) our ITO could serve well for both n-contact and p-contact. Interestingly, for the p-contact, with the ITO thickness reducing from 75 nm to 25 nm, the average contact resistivity values show a decreasing trend from 390 mΩ cm² to 114 mΩ cm². With applying 25-nm-thick front IWO in n-contact, and 25-nm-thick rear ITO use in p-contact, we obtained front side efficiencies above 22% in bifacial SHJ solar cells. This represents a 67% TCO reduction with respect to a reference bifacial solar cell with 75-nm-thick TCO on both sides.

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Organic-inorganic metal halide perovskites have attracted a considerable interest in the photovoltaic scientific community demonstrating a rapid and unprecedented increase in conversion efficiency in the last decade. Besides the stunning progress in performance, the understanding of the physical mechanisms and limitations that govern perovskite solar cells are far to be completely unravelled. In this work, we study the origin of their hysteretic behaviour from the standpoint of fundamental semiconductor physics by means of technology computer aided design electrical simulations. Our findings identify that the density of shallow interface defects at the interfaces between perovskite and transport layers plays a key role in hysteresis phenomena. Then, by comparing the defect distributions in both spatial and energetic domains for different bias conditions and using fundamental semiconductor equations, we can identify the driving force of hysteresis in terms of slow recombination processes and charge distributions.@en

We investigate gentle front side textures for perovskite/silicon tandem solar cells. These textures enhance the absorption of sunlight, yet are sufficiently gentle to allow deposition of an efficient perovskite top cell. We present a tandem solar cell with such gentle texture, fabricated by Kaneka corporation, with an efficiency as high as 28.6%. We perform an extensive ray-optics study, exploring non-conformal textures at the front and rear side of the perovskite layer. Our results reveal that a gentle texture with steepness of only 23° can be more optically efficient than conventional textures with more than double that steepness. We also show that the observed anti-reflective effect of such gentle textures is not based a double bounce, but on light trapping by total internal reflection. As a result, the optical effects of the encapsulation layers play an important role, and have to be accounted for when evaluating the texture design for perovskite/silicon tandems.

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We introduce a novel simulation tool capable of calculating the energy yield of a PV system based on its fundamental material properties and using self-consistent models. Thus, our simulation model can operate without measurements of a PV device. It combines wave and ray optics and a dedicated semiconductor simulation to model the optoelectronic PV device properties resulting in the IV-curve. The system surroundings are described via spectrally resolved ray tracing resulting in a cell resolved irradiance distribution, and via the fluid dynamics-based thermal model, in the individual cell temperatures. A lumped-element model is used to calculate the IV-curves of each solar cell for every hour of the year. These are combined factoring in the interconnection to obtain the PV module IV-curves, which connect to the inverter for calculating the AC energy yield. In our case study, we compare two types of 2 terminal perovskite/silicon tandem modules with STC PV module efficiencies of 27.7% and 28.6% with a reference c-Si module with STC PV module efficiency of 20.9%. In four different climates, we show that tandem PV modules operate at 1–1.9 °C lower yearly irradiance weighted average temperatures compared to c-Si. We find that the effect of current mismatch is significantly overestimated in pure optical studies, as they do not account for fill factor gains. The specific yields in kWh/kWp of the tandem PV systems are between −2.7% and +0.4% compared to the reference c-Si system in all four simulated climates. Thus, we find that the lab performance of the simulated tandem PV system translates from the laboratory to outdoors comparable to c-Si systems.

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